Theoretical performance limits of a syngas–diesel fueled compression ignition engine from second law analysis

The present study is an attempt to investigate a syngas–diesel dual fueled diesel engine operation under varying load conditions from the second law point of view. The fuel type in dual fuel operation is achieved by varying the volumetric fractions of hydrogen (H2) and carbon monoxide (CO) content in syngas. It is revealed that increasing the hydrogen quantity of syngas increases the cumulative work availability and reduces the destroyed availability. This enhancement is due to a better combustion process and increased work output when a high amount of H2 quantity is employed. At lower loads, the in-cylinder combustion temperatures are reduced in case of the dual fuel combustion. Hence, the destruction availability is increased due to poor combustion and reduced heat transfer availability losses. When the engine is operated beyond 40% load, the destroyed availability reduced due to higher combustion temperature and pressure. The increase in the both exhaust gas and cooling water availabilities are reflected in an increase in second law efficiency with increasing load. The dual fuel cumulative work availability is increased at higher loads and thus, the exergy efficiency is increased.

[1]  N. M. Al-Najem,et al.  Energy-exergy analysis of a diesel engine , 1992 .

[2]  Toshio Shudo,et al.  An HCCI combustion engine system using on-board reformed gases of methanol with waste heat recovery: ignition control by hydrogen , 2006 .

[3]  O. Le Corre,et al.  Characterisation of a Syngas-Diesel Fuelled CI Engine , 2005 .

[4]  Ujjwal K. Saha,et al.  Effect of engine parameters and type of gaseous fuel on the performance of dual-fuel gas diesel engines—A critical review , 2009 .

[5]  R. J. Moffat,et al.  Contributions to the Theory of Single-Sample Uncertainty Analysis , 1982 .

[6]  Dimitrios C. Kyritsis,et al.  Comparative second-law analysis of internal combustion engine operation for methane, methanol, and dodecane fuels , 2001 .

[7]  Roy J. Primus A Second Law Approach to Exhaust System Optimization , 1984 .

[8]  Ghazi A. Karim,et al.  Exhaust emissions from an SI engine operating on gaseous fuel mixtures containing hydrogen , 2005 .

[9]  K. Hoag,et al.  An appraisal of advanced engine concepts using second law analysis techniques , 1984 .

[10]  T. A. Brzustowski,et al.  Second-Law Analysis of Energy Processes Part I: Exergy — An Introduction* , 1976 .

[11]  T. L. McKinley,et al.  An Assessment of Turbocharging Systems for Diesel Engines from First and Second Law Perspectives , 1988 .

[12]  Jerald A. Caton The Effects of Compression Ratio and Expansion Ratio on Engine Performance Including the Second Law of Thermodynamics: Results From a Cycle Simulation , 2007 .

[13]  Evangelos G. Giakoumis,et al.  Speed and load effects on the availability balances and irreversibilities production in a multi-cylinder turbocharged diesel engine , 1997 .

[14]  Howard N. Shapiro,et al.  Second law analysis of the Ames solid waste recovery system , 1980 .

[15]  Mehmet Kopac,et al.  Determination of optimum speed of an internal combustion engine by exergy analysis , 2005 .

[16]  T. J. Kotas,et al.  The Exergy Method of Thermal Plant Analysis , 2012 .

[17]  Jerald A. Caton Results From an Engine Cycle Simulation of Compression Ratio and Expansion Ratio Effects on Engine Performance , 2008 .

[18]  J. H. Van Gerpen,et al.  Second-law analysis of diesel engine combustion , 1990 .

[19]  P. Spath,et al.  Preliminary screening: Technical and economic assessment of synthesis gas to fuels and chemicals with emphasis on the potential for biomass-derived syngas , 2003 .

[20]  Jerald A. Caton,et al.  Destruction of availability (exergy) due to combustion processes: A parametric study , 2006 .

[21]  Noam Lior,et al.  Sources of Combustion Irreversibility , 1994 .

[22]  Edward A. Bruges,et al.  Available energy and the second law analysis , 1959 .

[23]  Ujjwal K. Saha,et al.  Analysis of Throttle Opening Variation Impact on a Diesel Engine Performance Using Second Law of Thermodynamics , 2009 .

[24]  Jerald A. Caton,et al.  Operating Characteristics of a Spark-Ignition Engine Using the Second Law of Thermodynamics: Effects of Speed and Load , 2000 .

[25]  John B. Heywood,et al.  Internal combustion engine fundamentals , 1988 .

[26]  Evangelos G. Giakoumis,et al.  Second-law analyses applied to internal combustion engines operation , 2006 .

[27]  Toshio Shudo,et al.  Influence of Reformed Gas Composition on HCCI Combustion Engine System fueled with DME and H2-CO-CO2 which are Onboard-reformed from Methanol Utilizing Engine Exhaust Heat , 2004 .

[28]  R. J. Primus,et al.  A NEW PERSPECTIVE ON DIESEL ENGINE EVALUATION BASED ON SECOND LAW ANALYSIS , 1984 .

[29]  C. D. Rakopoulos,et al.  Generation of combustion irreversibilities in a spark ignition engine under biogas–hydrogen mixtures fueling , 2009 .

[30]  S. J. Kline,et al.  Describing Uncertainties in Single-Sample Experiments , 1953 .

[31]  C. D. Rakopoulos,et al.  Development and validation of a multi-zone combustion model for performance and nitric oxide formation in syngas fueled spark ignition engine , 2008 .

[32]  Michael J. Moran,et al.  Availability analysis: A guide to efficient energy use , 1982 .

[33]  Ujjwal K. Saha,et al.  Assessment of a Syngas-Diesel Dual Fuelled Compression Ignition Engine , 2010 .

[34]  C. N. Michos,et al.  Availability analysis of a syngas fueled spark ignition engine using a multi-zone combustion model , 2008 .

[35]  A. C. Alkidas,et al.  The Application of Availability and Energy Balances to a Diesel Engine , 1988 .

[36]  C. Rakopoulos,et al.  Hydrogen enrichment effects on the second law analysis of natural and landfill gas combustion in engine cylinders , 2006 .

[37]  Olivier Le Corre,et al.  Combustion of Syngas in Internal Combustion Engines , 2008 .

[38]  Jerald A. Caton,et al.  On the destruction of availability (exergy) due to combustion processes — with specific application to internal-combustion engines , 2000 .