Large electrostrictive actuation of barium titanate single crystals

An experimental investigation of the electromechanical behavior of single crystals of the ferroelectric perovskite barium titanate is presented. An experimental setup has been designed to investigate large strain actuation in single crystal ferroelectrics subjected to combined electrical and mechanical loading. Experiments have been performed on initially single domain crystals of barium titanate with (1 0 0) and (0 0 1) orientation at compressive stresses between 0 and 5 MPa. Global strain and polarization histories have been recorded. The electrostrictive response is shown to be highly dependent on the level of applied stress with a maximum strain of 0.9% measured at a compressive stress of about 2 MPa and electric 8eld of about 10 kV/cm. This level of strain is about 5 times higher than in typical commercial piezoelectric PZT. Polarized light microscopy has been used to observe the evolution of the domain pattern simultaneously with the strain and polarization measurement. The observations reveal that the observed large strain behavior is the result of 90° domain switching.

[1]  Z. Li,et al.  Piezoelectrically‐induced switching of 90° domains in tetragonal BaTiO3 and PbTiO3 investigated by micro‐Raman spectroscopy , 1992 .

[2]  David Kinderlehrer,et al.  Theory of magnetostriction with applications to TbxDy1-xFe2 , 1993 .

[3]  H. Schmid Polarized Light Microscopy (PLM) of Ferroelectric and Ferroelastic Domains in Transmitted and Reflected Light , 1993 .

[4]  T. Shrout,et al.  Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals , 1997 .

[5]  Christopher S. Lynch,et al.  The effect of uniaxial stress on the electro-mechanical response of 8/65/35 PLZT , 1996 .

[6]  D. R. Young,et al.  Triple Hysteresis Loops and the Free-Energy Function in the Vicinity of the 5°C Transition in BaTiO 3 , 1956 .

[7]  Antonio DeSimone,et al.  A constrained theory of magnetoelasticity , 2002 .

[8]  A. F. Devonshire XCVI. Theory of barium titanate , 1949 .

[9]  Boris A. Strukov,et al.  Ferroelectric Phenomena in Crystals , 1998 .

[10]  A. Bhalla,et al.  90°-Domain reversal in Pb(Zrx, Ti1-x)O3 ceramics , 1993 .

[11]  C. B. Sawyer,et al.  Rochelle Salt as a Dielectric , 1930 .

[12]  M. A. Northrup,et al.  Thin Film Shape Memory Alloy Microactuators , 1996, Microelectromechanical Systems (MEMS).

[13]  Nava Setter,et al.  Ferroelectric ceramics : tutorial reviews, theory, processing, and applications , 1993 .

[14]  K. Bhattacharya,et al.  Domain patterns and macroscopic behaviour of ferroelectric materials , 2001 .

[15]  R. C. Miller,et al.  Motion of 180° Domain Walls in Metal Electroded Barium Titanate Crystals as a Function of Electric Field and Sample Thickness , 1960 .

[16]  Wei Chen,et al.  A micro-electro-mechanical model for polarization switching of ferroelectric materials , 1998 .

[17]  R. Newnham,et al.  90‡ domain reversal in Pb(ZrxTi1−x)O3 ceramics , 1994 .

[18]  L. E. Cross,et al.  Ferroelectric Materials for Electromechanical Transducer Applications , 1995 .

[19]  E. Burcsu Investigation of large strain actuation in barium titanate , 2001 .

[20]  E. A. Little The dynamic behavior of domain walls in barium titanate , 1954 .

[21]  Dragan Damjanovic,et al.  FERROELECTRIC, DIELECTRIC AND PIEZOELECTRIC PROPERTIES OF FERROELECTRIC THIN FILMS AND CERAMICS , 1998 .

[22]  A. F. Devonshire Theory of ferroelectrics , 1954 .

[23]  A. F. Devonshire CIX. Theory of barium titanate—Part II , 1951 .

[24]  G. Ravichandran,et al.  Large strain electrostrictive actuation in barium titanate , 2000 .