Hazards assessment and technical actions due to the production of pressured hydrogen within a pilot photovoltaic-electrolyser-fuel cell power system for agricultural equipment

A pilot power system formed by photovoltaic panels, alkaline electrolyser and fuel cell stacks was designed and set up to supply the heating system of an experimental greenhouse. The aim of this paper is to analyse the main safety aspects of this power system connected to the management of the pressured hydrogen, such as the explosion limits of the mixture hydrogen-oxygen, the extension of the danger zone, the protection pressure vessels and the system to make unreactive the plant. The electrolyser unit is the core of this plant and from the safety point of view has been equipped with devices able to highlight the malfunctions before they cause damages. Alarm situations are highlighted and the production process is cut off in safe conditions in the event that the operational parameters have an abnormal deviation from the design values. Also the entire power system has been designed so that any failure to its components does not compromise the workers’ safety even if the risk analysis is in progress because technical operations are being carried out for enhancing the plant functionality, making it more suitable to the designed task of supplying electrically the greenhouse heating system during cold periods. Some experimental data pertinent to the solar radiation and the corresponding hydrogen production rate are also reported. At present it does not exist a well-established safety reference protocol to design the reliability of these types of power plants and then the assumed safety measures even if related to the achieved pilot installation, can represent an original base of reference to set up guidelines for designing the safety of power plants in the future available for agricultural purposes.

[1]  E. David An overview of advanced materials for hydrogen storage , 2005 .

[2]  Simone Pascuzzi,et al.  Hydrogen and renewable energy sources integrated system for greenhouse heating , 2013 .

[3]  P. Mizsey,et al.  Flammability of gas mixtures. Part 2: influence of inert gases. , 2005, Journal of hazardous materials.

[4]  A. Ganguly,et al.  Modeling and analysis of solar photovoltaic-electrolyzer-fuel cell hybrid power system integrated with a floriculture greenhouse , 2010 .

[5]  Lynne E. Macaskie,et al.  Integrating dark and light bio-hydrogen production strategies: towards the hydrogen economy , 2009 .

[6]  Hüseyin Benli,et al.  A performance comparison between a horizontal source and a vertical source heat pump systems for a greenhouse heating in the mild climate Elaziğ, Turkey , 2013 .

[7]  R. Valdés,et al.  Procedure for optimal design of hydrogen production plants with reserve storage and a stand-alone photovoltaic power system , 2012 .

[8]  John H.S. Lee,et al.  Comments on explosion problems for hydrogen safety , 2008 .

[9]  Alberto Pardossi,et al.  Chapter 1: Sustainable Greenhouse Systems. in “Sustainable Agriculture: Technology, Planning and Management”, Augusto Salazar e Ismael Rios Editors, Nova Science Publishers, Inc. NY USA , 2010 .

[10]  F. Mueller-Langer,et al.  Techno-economic assessment of hydrogen production processes for the hydrogen economy for the short and medium term , 2007 .

[11]  J. O. Voogt,et al.  Greenhouse production systems for people , 2012 .

[12]  Volkmar Schröder,et al.  Comparison of calculated data for the flammability and the oxidation potential according to ISO 10156 with experimentally determined values , 2011 .

[13]  C. Rivkin,et al.  An overview of hydrogen safety sensors and requirements , 2011 .

[14]  E. Cerruto,et al.  Improvement in pesticide application on greenhouse crops: results of a survey about greenhouse structures in Italy , 2008 .

[15]  Maria Molnarne,et al.  Sicherheitstechnische Kenngrößen, Band 2: Explosionsbereiche von Gasgemischen , 2003 .

[16]  Simone Pascuzzi,et al.  Study of a pilot photovoltaic-electrolyser-fuel cell power system for a geothermal heat pump heated greenhouse and evaluation of the electrolyser efficiency and operational mode , 2014 .

[17]  John K. Kaldellis,et al.  Optimal design of geothermal–solar greenhouses for the minimisation of fossil fuel consumption , 2006 .

[18]  J. Ni,et al.  Performance evaluation of ground source heat pump system for greenhouse heating in northern China , 2012 .

[19]  B. Huyghebaert,et al.  Photovoltaic and geothermal integration system for greenhouse heating: an experimental study. , 2011 .

[20]  Rihab Jallouli,et al.  Sizing, techno-economic and generation management analysis of a stand alone photovoltaic power unit including storage devices , 2012 .

[21]  Jacob Brouwer,et al.  Experimental results for hybrid energy storage systems coupled to photovoltaic generation in residen , 2011 .