Bio-inspired slanted polymer nanohairs for anisotropic wetting and directional dry adhesion

Slanted polymer nanohairs possess a number of attractive properties in terms of anisotropic wetting and directional adhesion. This highlight provides an overview of the recent progress in the development of bio-inspired slanted polymer nanohairs and their applications towards anisotropic wetting and directional dry adhesion properties. With the advanced nano-fabrication techniques, it is possible to fabricate angled, directionally bent polymer nanohairs in a highly reproducible and geometry-controllable manner. The fabrication methods can be categorized into two streams: direct replica molding from a master with slanted structure or nanofabrication (photolithography or molding) with post treatment such as e-beam exposure, thermal annealing and mechanical compression. In this highlight, the fabrication methods for angled, high aspect ratio polymer nanohairs are briefly described along with their potential applications in anisotropic wetting and directional adhesion. Particular emphasis is given to recent achievements and future directions in biomimetic functional surfaces.

[1]  Sang Heup Moon,et al.  Effect of leaning angle of gecko-inspired slanted polymer nanohairs on dry adhesion , 2010 .

[2]  M. Kwak,et al.  Wettability of nanoengineered dual-roughness surfaces fabricated by UV-assisted capillary force lithography. , 2009, Journal of colloid and interface science.

[3]  K. Suh,et al.  Unidirectional wetting and spreading on stooped polymer nanohairs , 2009 .

[4]  Kahp Y. Suh,et al.  Adhesion hysteresis of Janus nanopillars fabricated by nanomolding and oblique metal deposition , 2009 .

[5]  F. Mugele Fundamental challenges in electrowetting: from equilibrium shapes to contact angle saturation and drop dynamics , 2009 .

[6]  Kahp Y Suh,et al.  Wetting transition and optimal design for microstructured surfaces with hydrophobic and hydrophilic materials. , 2009, Journal of colloid and interface science.

[7]  Kahp Y Suh,et al.  Shape-tunable polymer nanofibrillar structures by oblique electron beam irradiation. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[8]  Kahp Y. Suh,et al.  Stooped Nanohairs: Geometry‐Controllable, Unidirectional, Reversible, and Robust Gecko‐like Dry Adhesive , 2009 .

[9]  K. Suh,et al.  A nontransferring dry adhesive with hierarchical polymer nanohairs , 2009, Proceedings of the National Academy of Sciences.

[10]  M. Sitti,et al.  Gecko-inspired directional and controllable adhesion. , 2008, Small.

[11]  R. Fearing,et al.  Directional adhesion of gecko-inspired angled microfiber arrays , 2008 .

[12]  Rui Zhang,et al.  Biomimetic nanofiber patterns with controlled wettability , 2008 .

[13]  Rhokyun Kwak,et al.  Generation and self-replication of monolithic, dual-scale polymer structures by two-step capillary-force lithography. , 2008, Small.

[14]  W. Lu,et al.  A biomimetic hierarchical scaffold: natural growth of nanotitanates on three-dimensional microporous Ti-based metals. , 2008, Nano letters.

[15]  Liangti Qu,et al.  Carbon Nanotube Arrays with Strong Shear Binding-On and Easy Normal Lifting-Off , 2008, Science.

[16]  S. Brueck,et al.  Strongly anisotropic wetting on one-dimensional nanopatterned surfaces. , 2008, Nano letters.

[17]  Lan Dang,et al.  Drop retention force as a function of resting time. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[18]  Wen Li,et al.  Anisotropic wetting behavior arising from superhydrophobic surfaces: parallel grooved structure. , 2008, Journal of Physical Chemistry B.

[19]  A. Jagota,et al.  Strongly enhanced static friction using a film-terminated fibrillar interface. , 2008, Soft matter.

[20]  Shravanthi T. Reddy,et al.  Bioinspired Surfaces with Switchable Adhesion , 2007 .

[21]  R. Ho,et al.  Fabrication of Double‐Length‐Scale Patterns via Lithography, Block Copolymer Templating, and Electrodeposition , 2007 .

[22]  S. Soper,et al.  Integration of large-area polymer nanopillar arrays into microfluidic devices using in situ polymerization cast molding. , 2007, Lab on a chip.

[23]  Lingbo Zhu,et al.  Hierarchical silicon etched structures for controlled hydrophobicity/superhydrophobicity. , 2007, Nano letters.

[24]  Teri W Odom,et al.  Multiscale patterning of plasmonic metamaterials. , 2007, Nature nanotechnology.

[25]  C. Stafford,et al.  Anisotropic wetting on tunable micro-wrinkled surfaces. , 2007, Soft matter.

[26]  Eduard Arzt,et al.  Patterned Surfaces with Pillars with Controlled 3D Tip Geometry Mimicking Bioattachment Devices , 2007 .

[27]  Andrew R. Parker,et al.  Biomimetics of photonic nanostructures. , 2007, Nature nanotechnology.

[28]  H. Low,et al.  Anisotropic wettability on imprinted hierarchical structures. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[29]  Eduard Arzt,et al.  Adhesion of bioinspired micropatterned surfaces: effects of pillar radius, aspect ratio, and preload. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[30]  Metin Sitti,et al.  Adhesion of biologically inspired vertical and angled polymer microfiber arrays. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[31]  J. Aizenberg,et al.  Reversible Switching of Hydrogel-Actuated Nanostructures into Complex Micropatterns , 2007, Science.

[32]  Lei Jiang,et al.  Application of superhydrophobic edge effects in solving the liquid outflow phenomena. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[33]  C. Extrand,et al.  Retention forces of a liquid slug in a rough capillary tube with symmetric or asymmetric features. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[34]  Metin Sitti,et al.  Biologically inspired polymer microfibers with spatulate tips as repeatable fibrillar adhesives , 2006 .

[35]  Han Gao,et al.  Combinational template-assisted fabrication of hierarchically ordered nanowire arrays on substrates for device applications , 2006 .

[36]  C Majidi,et al.  Effective elastic modulus of isolated gecko setal arrays , 2006, Journal of Experimental Biology.

[37]  M. Cutkosky,et al.  Frictional adhesion: a new angle on gecko attachment , 2006, Journal of Experimental Biology.

[38]  Kahp Y. Suh,et al.  Stretched polymer nanohairs by nanodrawing. , 2006 .

[39]  Huajian Gao,et al.  Mechanics of robust and releasable adhesion in biology: bottom-up designed hierarchical structures of gecko. , 2006 .

[40]  Bertram Schwarzchild Drops of liquid exhibit surprising self-propulsion on ratcheted surfaces , 2006 .

[41]  Kahp Y Suh,et al.  Nanoengineered multiscale hierarchical structures with tailored wetting properties. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[42]  Bharat Bhushan,et al.  Adhesion analysis of two-level hierarchical morphology in natural attachment systems for 'smart adhesion' , 2006 .

[43]  K. Leong,et al.  Effects of nanoimprinted patterns in tissue-culture polystyrene on cell behavior. , 2005, Journal of vacuum science & technology. A, Vacuum, surfaces, and films : an official journal of the American Vacuum Society.

[44]  Ronald S. Fearing,et al.  Attachment of fiber array adhesive through side contact , 2005 .

[45]  Se-Jin Choi,et al.  Unconventional Patterning with A Modulus-Tunable Mold: From Imprinting to Microcontact Printing , 2004 .

[46]  X. Fang,et al.  Hierarchical Structure: Silicon Nanowires Standing on Silica Microwires , 2004 .

[47]  J. Sturm,et al.  Micro- and nanofluidics for DNA analysis , 2004, Analytical and bioanalytical chemistry.

[48]  Hideaki Abe,et al.  Mechanism of ArF resist-pattern shrinkage in critical-dimension scanning electron microscopy measurement , 2004 .

[49]  S. Gorb,et al.  From micro to nano contacts in biological attachment devices , 2003, Proceedings of the National Academy of Sciences of the United States of America.

[50]  Jin Zhai,et al.  Super‐Hydrophobic Surfaces: From Natural to Artificial , 2002 .

[51]  Zhifeng Ren,et al.  Hierarchical ZnO Nanostructures , 2002 .

[52]  H. H. Lee,et al.  Capillary Force Lithography , 2001 .

[53]  D. Leckband,et al.  Intermolecular forces in biology , 2001, Quarterly Reviews of Biophysics.

[54]  I. Hsing,et al.  An improved anodic bonding process using pulsed voltage technique , 2000, Journal of Microelectromechanical Systems.

[55]  H. Craighead,et al.  Separation of long DNA molecules in a microfabricated entropic trap array. , 2000, Science.

[56]  A. M. Higgins,et al.  Anisotropic spinodal dewetting as a route to self-assembly of patterned surfaces , 2000, Nature.

[57]  A. Ajdari,et al.  Moving droplets on asymmetrically structured surfaces. , 1999, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics.

[58]  J. Rogers,et al.  Distributed feedback ridge waveguide lasers fabricated by nanoscale printing and molding on nonplanar substrates , 1999 .

[59]  Pascal Silberzan,et al.  Rectified motion of a mercury drop in an asymmetric structure , 1996 .

[60]  C. Furmidge,et al.  Studies at phase interfaces. I. The sliding of liquid drops on solid surfaces and a theory for spray retention , 1962 .

[61]  K. Kawasaki Study of wettability of polymers by sliding of water drop , 1960 .

[62]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .