Selective Olefin Hydroformylation on Carbon-supported Ru and Ru–Co Carbonyl Cluster-derived Catalysts

High activities and selectivities toward normal-alcohols were achieved in the vapor-phase hydroformylation of ethylene and propylene on the carbon-supported Ru–Co bimetallic carbonyl cluster-derived catalysts under an atmospheric pressure.

[1]  A. Fukuoka,et al.  Homogeneous multimetallic catalysts: Part 6. Hydroformylation and hydroesterification of olefins by homogeneous cobalt-ruthenium bimetallic catalysts , 1986 .

[2]  M. Vannice,et al.  Carbon-supported Fe-Ru catalysts prepared from stoichiometric mixed-metal carbonyl clusters , 1985 .

[3]  M. Leconte,et al.  Bimetallic catalysts starting from heteropolymetallic clusters: Surface organometallic chemistry and Fischer-Tropsch activity of an Fe—Os system , 1983 .

[4]  M. Ue,et al.  Synthesis and characterization of [RuCo3(CO)12]- clusters. Effective catalyst precursors for the homologation of methanol , 1983 .

[5]  V. Kuznetsov,et al.  CO hydration over catalysts prepared via supporting Fe3(CO)12 and (NEt4)2[Fe2Mn(CO)12] on oxide supports , 1982 .

[6]  G. Geoffroy,et al.  Synthesis and Spectroscopic Characterization of H3CoRu3(CO)12. Crystal and Molecular Structure of the C3v Isomer , 1980 .

[7]  E. M. Holt,et al.  Activation of coordinated carbon monoxide toward alkyl and aryl migration (carbon monoxide insertion) by molecular Lewis acids and x-ray structure of the reactive intermediate , 1980 .

[8]  G. Geoffroy,et al.  Synthesis of Tetranuclear Mixed-Metal Clusters via the Reaction of Co(CO)4- with Closed Metal Carbonyl Trimers. Crystal and Molecular Structure of (Ph3P)2NCoRu3(CO)13. , 1980 .

[9]  M. Ichikawa.  Catalytic hydroformylation of olefins over the rhodium, bimetallic RhCo, and cobalt carbonyl clusters supported with some metal oxides , 1979 .

[10]  M. Ichikawa.  Catalysis by supported metal crystallites prepared from metal carbonyl clusters: III. Catalytic vapor-phase hydroformylation of olefins over Rh, bimetallic RhCo, and Co crystallites prepared from the carbonyl cluster compounds dispersed on zinc oxide , 1979 .