Chemical-Looping Combustion of Solid Fuels — Operational Experiences in 100 kW Dual Circulating Fluidized Bed System☆

Results from the first year of operation of a 100 kW chemical-looping combustor for solid fuels are presented. Gas measurements showed the presence of unconverted gas from the fuel reactor. With bituminous coal the gas conversion was up to 84%, and significantly higher with low-volatile fuel and char. The gas conversion was strongly dependent on solids inventory in the fuel reactor. A CO2 capture up to 98-99% was reached. The unit worked well and operation was stable. The operation shows the viability of this technology, which has unique potential for breakthrough in cost and energy penalty of CO2 capture.

[1]  A. Lyngfelt Oxygen Carriers for Chemical Looping Combustion-4000 h of Operational Experience , 2011 .

[2]  Petter E. Røkke,et al.  Techno-Economic Evaluations and Benchmarking of Pre-combustion CO2 Capture and Oxy-fuel Processes Developed in the European ENCAP Project , 2009 .

[3]  Jun Xiao,et al.  Experiments on chemical looping combustion of coal with a NiO based oxygen carrier , 2009 .

[4]  A. Abad,et al.  The use of ilmenite as oxygen-carrier in a 500Wth Chemical-Looping Coal Combustion unit , 2011 .

[5]  A. Lyngfelt,et al.  A fluidized-bed combustion process with inherent CO2 separation; Application of chemical-looping combustion , 2001 .

[6]  Juan Adánez,et al.  Progress in chemical-looping combustion and reforming technologies , 2012 .

[7]  Anders Lyngfelt,et al.  The use of petroleum coke as fuel in a 10 kWth chemical-looping combustor , 2008 .

[8]  Laihong Shen,et al.  Characterization of chemical looping combustion of coal in a 1 kWth reactor with a nickel-based oxygen carrier , 2010 .

[9]  A. Lyngfelt,et al.  Chemical‐Looping Combustion of Solid Fuels ‐ Design and Operation of a 100 KW Unit with Bituminous Coal , 2014 .

[10]  Stefan Heinrich,et al.  Operational experience with a system of coupled fluidized beds for chemical looping combustion of solid fuels using ilmenite as oxygen carrier , 2014 .

[11]  Mohammad. M. Hossain,et al.  Chemical-looping combustion (CLC) for inherent CO2 separations—a review , 2008 .

[12]  Anders Lyngfelt,et al.  Chemical-looping with oxygen uncoupling using CuO/ZrO2 with petroleum coke , 2009 .

[13]  A. Lyngfelt,et al.  Chemical-looping combustion of solid fuels – Operation in a 10 kW unit with two fuels, above-bed and in-bed fuel feed and two oxygen carriers, manganese ore and ilmenite , 2012 .

[14]  Anders Lyngfelt,et al.  Design and Operation of a 10 kWth Chemical-Looping Combustor for Solid Fuels - Testing with South African Coal , 2008 .

[15]  Pontus Markström,et al.  Designing and operating a cold-flow model of a 100 kW chemical-looping combustor , 2012 .

[16]  Anders Lyngfelt,et al.  CHEMICAL-LOOPING COMBUSTION IN A 100 KW UNIT FOR SOLID FUELS , 2012 .

[17]  Liang-Shih Fan,et al.  Iron-based syngas chemical looping process and coal-direct chemical looping process development at Ohio State University , 2014 .

[18]  Anders Lyngfelt,et al.  Operation of a 100kW chemical-looping combustor with Mexican petroleum coke and Cerrejón coal , 2014 .

[19]  Anders Lyngfelt,et al.  Materials for chemical-looping combustion , 2011 .