Fundamentals of high-energy spark ignition with lasers

Abstract An experimental study of laser-induced spark ignition of flammable, gaseous premixtures is reported, with theoretical interpretations. Ignition was in an explosion bomb, equipped with four variable-speed fans that facilitated the study of quiescent and isotropic turbulent conditions. Good optical access enabled the progress of plasma fronts, shock waves, igniting kernels, and propagating flames to be recorded with high-speed schlieren photography. A focused beam from a Q-switched Nd:YAG laser initiated electrical breakdown, with plasma energies between 85 and 200 mJ. Probabilities of breakdown were found for air and isooctane–air mixtures over ranges of pressures and temperatures. Blast-wave theory applied to shock-wave trajectories enabled initial plasma conditions to be inferred. This suggested electron temperatures of over 105 K and very high pressures. Calculated values of the absorption coefficient for the laser beam energy show these plasma properties to be commensurate with the observed energy and size. The ensuing rarefaction wave creates toroidal rings at the leading and trailing edges of the plasma. The former decays more rapidly and a third lobe of the kernel is generated that moves towards the laser. In flammable mixtures this enhances the flame spread. Laminar flame speeds are overdriven by this gasdynamic effect, as well as by the high energy of the plasma, to such an extent that the flame speed decays from elevated values as the flame stretch decreases, contrary to the increases that occur with normal flames with positive Markstein numbers. The extent to which turbulence narrows the ignition limits is found experimentally. For mixtures close to the lean flammability limit, strong gasdynamic flows induced by laser ignition can stretch the flames to extinction and narrow the ignition limits. If a flame becomes established, eventually the third lobe disappears as the initial gas dynamic effects decay and are overwhelmed by the imposed flow fields. Nevertheless, the overdrive effects persist for some time and overdriven flames were observed in regimes where normal flames would have quenched.

[1]  Andrzej W. Miziolek,et al.  Laser-based ignition of H2O2 and D2O2 premixed gases through resonant multiphoton excitation of H and D atoms near 243 nm , 1991 .

[2]  J. Daiber,et al.  Laser‐Driven Detonation Waves in Gases , 1967 .

[3]  D. Bradley How fast can we burn , 1992 .

[4]  W. Steen Laser Material Processing , 1991 .

[5]  G. Bach,et al.  Direct initiation of spherical detonations in gaseous explosives , 1969 .

[6]  Felix Jiri Weinberg,et al.  A preliminary investigation of the use of focused laser beams for minimum ignition energy studies , 1971, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[7]  Felix Jiri Weinberg,et al.  The effect of plasma constitution on laser ignition energies , 1977 .

[8]  Iu. P. Raizer Laser-induced discharge phenomena , 1977 .

[9]  Leon J. Radziemski,et al.  Lasers-Induced Plasmas and Applications , 1989 .

[10]  Paul D. Ronney Laser versus conventional ignition of flames , 1994 .

[11]  Myung Taeck Lim,et al.  Spark kernel development in constant volume combustion , 2003 .

[12]  D. Bradley,et al.  Evaluation of novel igniters in a turbulent bomb facility and a turbo-annular gas turbine combustor , 1989 .

[13]  P. Gaskell,et al.  Burning Velocities, Markstein Lengths, and Flame Quenching for Spherical Methane-Air Flames: A Computational Study , 1996 .

[14]  Tatsuro Tsukamoto,et al.  Mechanism of flame kernel formation produced by short duration sparks , 1988 .

[15]  Derek Bradley,et al.  Spark ignition and the early stages of turbulent flame propagation , 1987 .

[16]  R. Knystautas,et al.  Laser Spark Ignition of Chemically Reactive Gases , 1968 .

[17]  Jack A. Syage,et al.  Dynamics of flame propagation using laser‐induced spark initiation: Ignition energy measurements , 1988 .

[18]  G. Taylor The formation of a blast wave by a very intense explosion I. Theoretical discussion , 1950, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[19]  D. Bradley,et al.  The measurement of laminar burning velocities and Markstein numbers for iso-octane-air and iso-octane-n-heptane-air mixtures at elevated temperatures and pressures in an explosion bomb , 1998 .

[20]  P. Ashmore,et al.  Photochemistry and reaction kinetics , 1967 .

[21]  Derek Bradley,et al.  Turbulent burning velocities: a general correlation in terms of straining rates , 1987, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[22]  R. B. Edmonson,et al.  Microchronometric Schlieren Study of Gaseous Expansion from an Electric Spark , 1952 .

[23]  D. Bradley,et al.  Criteria for turbulent propagation limits of premixed flames , 1985 .

[24]  Eran Sher,et al.  Numerical modeling of spark ignition and flame initiation in a quiescent methane-air mixture , 1994 .

[25]  S. H. Chung,et al.  Numerical simulation of front lobe formation in laser-induced spark ignition of CH4/air mixtures , 2002 .

[26]  Derek Bradley,et al.  Spark ignition of turbulent gases , 1982 .

[27]  R. Hanson,et al.  Digital imaging of laser-ignited combustion , 1988 .

[28]  Philip H. Gaskell,et al.  The modeling of aerodynamic strain rate and flame curvature effects in premixed turbulent combustion , 1998 .

[29]  Dennis R. Alexander,et al.  Laser spark ignition and combustion characteristics of methane-air mixtures , 1998 .

[30]  G. Taylor The instability of liquid surfaces when accelerated in a direction perpendicular to their planes. I , 1950, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[31]  M. Metghalchi,et al.  Burning Velocities of Mixtures of Air with Methanol, Isooctane, and Indolene at High Pressure and Temperature , 1982 .

[32]  J. Kerr Asymptotic parameter realms and scintillation scales for extended sources in turbulence. , 1976, Applied optics.

[33]  S. Ramsden,et al.  A Radiative Detonation Model for the Development of a Laser-Induced Spark in Air , 1964, Nature.

[34]  M. Akram Two-Dimensional Model for Spark Discharge Simulation in Air , 1996 .

[35]  S. Ramsden,et al.  RADIATION SCATTERED FROM THE PLASMA PRODUCED BY A FOCUSED RUBY LASER BEAM , 1964 .

[36]  V. Srivastava,et al.  Pressure dependence of the laser-induced breakdown thresholds of gases and droplets. , 1990, Applied optics.

[37]  Derek Bradley,et al.  Turbulent burning velocities and flame straining in explosions , 1984, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[38]  Jack A. Syage,et al.  Time-resolved imaging of flame kernels: Laser spark ignition of H2/O2/Ar mixtures , 1995 .

[39]  T. Phuoc,et al.  An optical and spectroscopic study of laser-induced sparks to determine available ignition energy , 2002 .

[40]  D. Bradley,et al.  Turbulent flame propagation in premixed gases: Theory and experiment , 1979 .

[41]  Ronald G. Pinnick,et al.  Aerosol-induced laser breakdown thresholds: wavelength dependence. , 1988, Applied optics.

[42]  Tran X. Phuoc,et al.  Laser-induced spark ignition of CH4/air mixtures , 1999 .

[43]  M. Kono,et al.  Investigation of ignition by composite sparks under high turbulence intensity conditions , 1992 .

[44]  J. Warnatz,et al.  Numerical simulation of spark ignition including ionization , 2000 .

[45]  D. Bradley,et al.  Electron-gas energy exchanges in a.c. fields and their relevance in lasers , 1976 .