Morphology and defect structure of the CeO2(111) films grown on Ru(0001) as studied by scanning tunneling microscopy

The morphology of ceria films grown on a Ru(0 0 0 1) substrate was studied by scanning tunneling microscopy in combination with low-energy electron diffraction and Auger electron spectroscopy. The preparation conditions were determined for the growth of nmthick, well-ordered CeO2(1 1 1) films covering the entire surface. The recipe has been adopted from the one suggested by Mullins et al. [D.R. Mullins, P.V. Radulovic, S.H. Overbury, Surf. Sci. 429 (1999) 186] and modified in that significantly higher oxidation tem

[1]  K. Fukui,et al.  Atom-resolved noncontact atomic force microscopic and scanning tunneling microscopic observations of the structure and dynamic behavior of CeO2(1 1 1) surfaces , 2003 .

[2]  Paolo Fornasiero,et al.  Catalysis by Ceria and Related Materials , 2002 .

[3]  E. Wang,et al.  Transformation of CeO 2(1 1 1) to Ce 2O 3(0 0 0 1) films , 2003 .

[4]  P. Sautet,et al.  Au atoms and dimers on the MgO(100) surface: a DFT study of nucleation at defects. , 2005, The journal of physical chemistry. B.

[5]  S. C. Parker,et al.  The electronic structure of oxygen vacancy defects at the low index surfaces of ceria , 2005 .

[6]  G. Briggs,et al.  Defect formation on CeO2(111) surfaces after annealing studied by STM , 1999 .

[7]  Stefano de Gironcoli,et al.  Reply to “Comment on ‘Taming multiple valency with density functionals: A case study of defective ceria' ” , 2005 .

[8]  K. Schierbaum,et al.  Ultrathin ordered CeO2 overlayers on Pt(111): interaction with NO2, NO, H2O and CO , 2000 .

[9]  Raymond J. Gorte,et al.  Direct oxidation of hydrocarbons in a solid-oxide fuel cell , 2000, Nature.

[10]  S. C. Parker,et al.  Density functional theory studies of the structure and electronic structure of pure and defective low index surfaces of ceria , 2005 .

[11]  T. Risse,et al.  Interaction of gold clusters with color centers on MgO(001) films. , 2006, Angewandte Chemie.

[12]  Avelino Corma,et al.  Spectroscopic evidence for the supply of reactive oxygen during CO oxidation catalyzed by gold supported on nanocrystalline CeO2. , 2005, Journal of the American Chemical Society.

[13]  G. Wong,et al.  Comparison of the reactivity of high-surface area, monolayer vanadia/ceria catalysts with vanadia/CeO2(1 1 1) model systems , 2003 .

[14]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[15]  X. Verykios,et al.  Renewable Hydrogen from Ethanol by Autothermal Reforming , 2004, Science.

[16]  Ling Zhou,et al.  Electron Localization Determines Defect Formation on Ceria Substrates , 2005, Science.

[17]  A. Siokou,et al.  Interaction of Methanol with Well-Defined Ceria Surfaces: Reflection/Absorption Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Temperature-Programmed Desorption Study , 1999 .

[18]  S. Overbury,et al.  The Interaction between NO and CO on Rh-Loaded CeOx(111) , 2000 .

[19]  H. Freund,et al.  Oxygen storage at the metal/oxide interface of catalyst nanoparticles. , 2005, Angewandte Chemie.

[20]  G. Briggs,et al.  Defect Structure of Nonstoichiometric CeO{sub 2}(111) Surfaces Studied by Scanning Tunneling Microscopy , 1997 .

[21]  Andrew G. Glen,et al.  APPL , 2001 .

[22]  J. Harding,et al.  The surface structure of CeO2(001) single crystals studied by elevated temperature STM , 2001 .

[23]  M. Bowker,et al.  Pd nanoparticle enhanced re-oxidation of non-stoichiometric TiO2: STM imaging of spillover and a new form of SMSI , 1999 .

[24]  M. Flytzani-Stephanopoulos,et al.  Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts , 2003, Science.

[25]  W. A. Brown,et al.  RAIRS studies of CO adsorption on Pd/CeO2-x(111)/Pt(111) , 2006 .

[26]  K. Schierbaum Ordered ultra-thin cerium oxide overlayers on Pt(111) single crystal surfaces studied by LEED and XPS , 1998 .

[27]  K. Schierbaum,et al.  Cerium oxides and cerium-platinum surface alloys on Pt(111) single-crystal surfaces studied by scanning tunneling microscopy , 2002 .

[28]  S. Overbury,et al.  Ordered cerium oxide thin films grown on Ru(0001) and Ni(111) , 1999 .

[29]  Diebold,et al.  Imaging cluster surfaces with atomic resolution: the strong metal-support interaction state of Pt supported on TiO2(110) , 2000, Physical review letters.

[30]  Avelino Corma,et al.  Nanocrystalline CeO2 increases the activity of Au for CO oxidation by two orders of magnitude. , 2004, Angewandte Chemie.

[31]  F. Netzer,et al.  Strain-induced formation of arrays of catalytically active sites at the metal-oxide interface [rapid communication] , 2004 .

[32]  S. Overbury,et al.  Chemisorption and reaction of NO and N2O on oxidized and reduced ceria surfaces studied by soft X-ray photoemission spectroscopy and desorption spectroscopy , 1999 .

[33]  L. Giordano,et al.  Characteristics of Pd adsorption on the MgO(100) surface: Role of oxygen vacancies , 2001 .

[34]  Hannu Häkkinen,et al.  Charging Effects on Bonding and Catalyzed Oxidation of CO on Au8 Clusters on MgO , 2005, Science.

[35]  U. R. Pillai,et al.  Highly active gold-ceria catalyst for the room temperature oxidation of carbon monoxide , 2006 .

[36]  R. M. Lambert,et al.  Structure, composition and thermal properties of cerium oxide films on platinum {111} , 1995 .

[37]  Stefano de Gironcoli,et al.  Taming multiple valency with density functionals: A case study of defective ceria , 2005 .

[38]  H. Freund,et al.  Surface chemistry of catalysis by gold , 2004 .

[39]  F. Netzer,et al.  Growth and thermal properties of ultrathin cerium oxide layers on Rh( 1 1 1 ) , 2002 .

[40]  R. Nix,et al.  The growth, structure and stability of ceria overlayers on Pd(111) , 1994 .

[41]  D. Thompson Perspective on industrial and scientific aspects of gold catalysis , 2003 .

[42]  K. Hermansson,et al.  Surface properties of CeO2 from first principles , 2004 .