Tracking and quantification of gaseous chemical plumes from anthropogenic emission sources within the Los Angeles Basin

Abstract This paper describes the sensor technology, measurement methodology and data analysis algorithms that are used to characterize gaseous emissions observed with a large-area coverage longwave-infrared (LWIR) hyperspectral imaging (HSI) sensor. In so doing the demonstrated capability is expanded well beyond the small number of gas species that have typically been reported and also sets these observations within a definitive, comprehensive framework that documents in detail the procedures used for detection, identification, and quantification of atmospheric trace gases using LWIR HSI systems, along with the methodology for determining their respective detection limits. Examples are provided for a 530 km 2 region of the Los Angeles Basin collected on July 22, 2014.

[1]  S. Hook,et al.  The ASTER spectral library version 2.0 , 2009 .

[2]  James K. Crowley,et al.  Identification of plant species by using high spatial and spectral resolution thermal infrared (8.0–13.5 μm) imagery , 2010 .

[3]  N. Draper,et al.  Applied Regression Analysis. , 1967 .

[4]  D. Cobb,et al.  Application of selective catalytic reduction (SCR) technology for NOx reduction from refinery combustion sources , 1991 .

[5]  David W. Warren,et al.  First flights of a new airborne thermal infrared imaging spectrometer with high area coverage , 2011, Defense + Commercial Sensing.

[6]  Craig R. Schwartz,et al.  Comparison of infrared imaging hyperspectral sensors for military target detection applications , 1996, Optics & Photonics.

[7]  Robert A. Schowengerdt,et al.  Image reconstruction by parametric cubic convolution , 1982, Comput. Graph. Image Process..

[8]  Ayana R. Anderson,et al.  Top five industries resulting in injuries from acute chemical incidents—Hazardous Substance Emergency Events Surveillance, nine states, 1999-2008. , 2015, MMWR supplements.

[9]  David W. Warren,et al.  LWIR/MWIR imaging hyperspectral sensor for airborne and ground-based remote sensing , 1996, Optics & Photonics.

[10]  Airborne Emission Spectrometer: a testbed for the EOS TES , 1996, Optics & Photonics.

[11]  Barbara Barletta,et al.  Increase in HFC‐134a emissions in response to the success of the Montreal Protocol , 2015 .

[12]  Martin Chamberland,et al.  Standoff identification and quantification of flare emissions using infrared hyperspectral imaging , 2011, Defense + Commercial Sensing.

[13]  J. Horel,et al.  MESOWEST: COOPERATIVE MESONETS IN THE WESTERN UNITED STATES , 2002 .

[14]  J. Peischl,et al.  Increasing atmospheric burden of ethanol in the United States , 2012 .

[15]  A. Stohl,et al.  Extraordinary halocarbon emissions initiated by the 2011 Tohoku earthquake , 2015 .

[16]  C. Rosenzweig,et al.  Cities lead the way in climate–change action , 2010, Nature.

[17]  Terrence S. Lomheim,et al.  Infrared hyperspectral imaging Fourier transform and dispersive spectrometers: comparison of signal-to-noise-based performance , 2002, SPIE Optics + Photonics.

[18]  Ira Leifer,et al.  Airborne visualization and quantification of discrete methane sources in the environment , 2014 .

[19]  Kevin C. Gross,et al.  Remote identification and quantification of industrial smokestack effluents via imaging Fourier-transform spectroscopy. , 2010, Environmental science & technology.

[20]  S. Reimann,et al.  Evidence for under‐reported western European emissions of the potent greenhouse gas HFC‐23 , 2011 .

[21]  David W. Warren,et al.  Dyson spectrometers for high-performance infrared applications , 2008 .

[22]  H. Bovensmann,et al.  Real-time remote detection and measurement for airborne imaging spectroscopy: a case study with methane , 2015 .

[23]  D. A. Howard,et al.  A thermal emission spectral library of rock-forming minerals , 2000 .

[24]  Simon J. Hook,et al.  Characterization of anthropogenic methane plumes with the HyperspectralThermal Emission Spectrometer (HyTES): a retrieval method and error analysis , 2016 .

[25]  Stephen J. Young,et al.  Remotely sensed ammonia emission from fumarolic vents associated with a hydrothermally active fault in the Salton Sea Geothermal Field, California , 2011 .

[26]  M. Eismann Hyperspectral Remote Sensing , 2012 .

[27]  Alain P. Kattnig,et al.  SIELETERS, an airborne infrared dual-band spectro-imaging system for measurement of scene spectral signatures. , 2015, Optics express.

[28]  Timothy J. Johnson,et al.  The PNNL quantitative infrared database for gas-phase sensing: a spectral library for environmental, hazmat, and public safety standoff detection , 2004, SPIE Optics East.

[29]  Bruce C. Walker,et al.  A Greenhouse-Gas Information System: Monitoring and Validating Emissions Reporting and Mitigation , 2011 .

[30]  David W. Warren,et al.  MAHI: An Airborne Mid-Infrared Imaging Spectrometer for Industrial Emissions Monitoring , 2017, IEEE Transactions on Geoscience and Remote Sensing.

[31]  David W. Warren,et al.  MAKO: a high-performance, airborne imaging spectrometer for the long-wave infrared , 2010, Optical Engineering + Applications.

[32]  Johannes Orphal,et al.  Instrument concept of the imaging Fourier transform spectrometer GLORIA , 2014 .

[33]  Paul E. Lewis,et al.  Airborne mapping of chemical plumes in the aftermath of Hurricanes Katrina and Rita , 2006, SPIE Defense + Commercial Sensing.

[34]  Gang Li,et al.  The HITRAN 2008 molecular spectroscopic database , 2005 .

[35]  S. J. Young,et al.  An in‐scene method for atmospheric compensation of thermal hyperspectral data , 2002 .

[36]  Xiaoli Yu,et al.  Adaptive multiple-band CFAR detection of an optical pattern with unknown spectral distribution , 1990, IEEE Trans. Acoust. Speech Signal Process..

[37]  Scot M. Miller,et al.  Anthropogenic emissions of methane in the United States , 2013, Proceedings of the National Academy of Sciences.

[38]  Gabrielle Pétron,et al.  A new look at methane and nonmethane hydrocarbon emissions from oil and natural gas operations in the Colorado Denver‐Julesburg Basin , 2014 .

[39]  E. Kort,et al.  Methane Leaks from North American Natural Gas Systems , 2014, Science.