论文信息 - Photolabilisation of phosphine ligands bound to iron : photofragmentation voltammetry analysis

Photolabilisation of phosphine ligands bound to iron : photofragmentation voltammetry analysis

Photofragmentation volammetry is used to demonstrate directly the primary loss of P(Ar)3 from [(η5C5H5) Fe(CO)(PAr3)C(NHMe)Me]+BF4–(Ar = phenyl 1 and p-tolyl 2) on irradiation with visible light. In contrast, no loss of carbon monoxide is observed.

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