Mechanochemical Activation of Zinc and Application to Negishi Cross-Coupling
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[1] Cover Picture: (Isr. J. Chem. 11/2018) , 2018, Israel Journal of Chemistry.
[2] Y. Monguchi,et al. Stainless Steel-Mediated Hydrogen Generation from Alkanes and Diethyl Ether and Its Application for Arene Reduction. , 2018, Organic letters.
[3] Manuela A. Gîlea,et al. Mechanochemistry of nucleosides, nucleotides and related materials , 2018, Beilstein journal of organic chemistry.
[4] Phil S. Baran,et al. Natural Product Total Synthesis: As Exciting as Ever and Here To Stay. , 2018, Journal of the American Chemical Society.
[5] James Mack,et al. Mechanochemistry and organic synthesis: from mystical to practical , 2018 .
[6] D. Browne,et al. Mechanochemistry as an emerging tool for molecular synthesis: what can it offer? , 2018, Chemical science.
[7] O. Baudoin,et al. Barbier-Negishi Coupling of Secondary Alkyl Bromides with Aryl and Alkenyl Triflates and Nonaflates. , 2018, Angewandte Chemie.
[8] Kecheng Zhang,et al. Barbier-Negishi Coupling of Secondary Alkyl Bromides with Triflates and Nonaflates , 2018 .
[9] Jean Martínez,et al. 1,1′-Carbonyldiimidazole and Mechanochemistry: A Shining Green Combination , 2017 .
[10] D. Browne,et al. One-pot multistep mechanochemical synthesis of fluorinated pyrazolones , 2017, Beilstein journal of organic chemistry.
[11] Carsten Bolm,et al. Altering Product Selectivity by Mechanochemistry. , 2017, The Journal of organic chemistry.
[12] Tomislav Friščić,et al. Mechanochemistry: A Force of Synthesis , 2016, ACS central science.
[13] Mario Ellwart,et al. Solid Organozinc Pivalates: A New Class of Zinc Organometallics with Greatly Enhanced Air- and Moisture-Stability , 2017, Synthesis.
[14] P. Knochel,et al. Directed Zincation with TMPZnCl·LiCl and Further Functionalization of the Tropolone Scaffold. , 2016, Organic letters.
[15] T. Swager,et al. Mechanochemical Synthesis of Extended Iptycenes. , 2016, Journal of the American Chemical Society.
[16] Jean Martínez,et al. Poly(ethylene) glycols and mechanochemistry for the preparation of bioactive 3,5-disubstituted hydantoins , 2016 .
[17] Tim Cernak,et al. The medicinal chemist's toolbox for late stage functionalization of drug-like molecules. , 2016, Chemical Society reviews.
[18] Mario Ellwart,et al. Air-stable solid aryl and heteroaryl organozinc pivalates: syntheses and applications in organic synthesis. , 2014, Chemistry.
[19] T. Friščić,et al. Multi-step and multi-component organometallic synthesis in one pot using orthogonal mechanochemical reactions , 2014 .
[20] M. Organ,et al. On the remarkably different role of salt in the cross-coupling of arylzincs from that seen with alkylzincs. , 2014, Angewandte Chemie.
[21] P. Knochel,et al. Organozinc pivalate reagents: segregation, solubility, stabilization, and structural insights. , 2014, Angewandte Chemie.
[22] M. Tyagi,et al. Solvent-free mechanochemical glycosylation in ball mill. , 2013, Carbohydrate research.
[23] P. Knochel,et al. TMPZnOPiv•LiCl: a new base for the preparation of air-stable solid zinc pivalates of sensitive aromatics and heteroaromatics. , 2013, Organic letters.
[24] P. Knochel,et al. Improved air-stable solid aromatic and heterocyclic zinc reagents by highly selective metalations for Negishi cross-couplings. , 2012, Angewandte Chemie.
[25] J. Clyburne,et al. Higher-order zincates as transmetalators in alkyl-alkyl negishi cross-coupling. , 2012, Angewandte Chemie.
[26] Ka Hou Hoi,et al. The development of bulky palladium NHC complexes for the most-challenging cross-coupling reactions. , 2012, Angewandte Chemie.
[27] James Mack,et al. Mechanochemistry: opportunities for new and cleaner synthesis. , 2012, Chemical Society reviews.
[28] D. Bohme,et al. Identification of a higher-order organozincate intermediate involved in Negishi cross-coupling reactions by mass spectrometry and NMR spectroscopy. , 2011, Chemistry.
[29] Cory Valente,et al. On the role of additives in alkyl-alkyl Negishi cross-couplings. , 2010, Chemical communications.
[30] M. Organ,et al. Pd-PEPPSI-IPent: low-temperature negishi cross-coupling for the preparation of highly functionalized, tetra-ortho-substituted biaryls. , 2010, Angewandte Chemie.
[31] A. Kennedy,et al. Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions by elucidation of Mg-Zn hybrids , 2010, Proceedings of the National Academy of Sciences.
[32] J. Howard,et al. Revelation of the difference between arylzinc reagents prepared from aryl Grignard and aryllithium reagents respectively: kinetic and structural features. , 2009, Journal of the American Chemical Society.
[33] B. Lipshutz,et al. Zn-mediated, Pd-catalyzed cross-couplings in water at room temperature without prior formation of organozinc reagents. , 2009, Journal of the American Chemical Society.
[34] P. Knochel,et al. Preparation of polyfunctional arylmagnesium, arylzinc, and benzylic zinc reagents by using magnesium in the presence of LiCl. , 2009, Chemistry.
[35] P. Knochel,et al. LiCl-mediated preparation of highly functionalized benzylic zinc chlorides. , 2008, Organic letters.
[36] P. Knochel,et al. (tmp)(2)Zn x 2 MgCl(2) x 2 LiCl: a chemoselective base for the directed zincation of sensitive arenes and heteroarenes. , 2007, Angewandte Chemie.
[37] M. Organ,et al. Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective. , 2007, Angewandte Chemie.
[38] G. Dunet,et al. Highly diastereoselective synthesis of homoallylic alcohols bearing adjacent quaternary centers using substituted allylic zinc reagents. , 2007, Journal of the American Chemical Society.
[39] P. Knochel,et al. Effiziente Synthese funktionalisierter zinkorganischer Verbindungen durch direkte Insertion von Zink in organische Bromide und Iodide , 2006 .
[40] P. Knochel,et al. Efficient synthesis of functionalized organozinc compounds by the direct insertion of zinc into organic iodides and bromides. , 2006, Angewandte Chemie.
[41] Cheng-yi Chen,et al. Enantioselective, Palladium-Catalyzed α-Arylation of N-Boc-pyrrolidine , 2006 .
[42] Mayumi Kimura,et al. A novel procedure for the preparation of zinc reagents: a practical synthesis of (+)-biotin , 2004 .
[43] K. Takagi,et al. Functionalized arylzinc compounds in ethereal solvent: direct synthesis from aryl iodides and zinc powder and application to Pd-catalyzed reaction with allylic halides. , 2003, The Journal of organic chemistry.
[44] Shouquan Huo. Highly efficient, general procedure for the preparation of alkylzinc reagents from unactivated alkyl bromides and chlorides. , 2003, Organic letters.
[45] R. Rieke,et al. The Reaction of Active Zinc with Organic Bromides , 1999 .
[46] R. Rieke,et al. Direct Formation of Secondary and Tertiary Alkylzinc Bromides and Subsequent Cu(I)-Mediated Couplings. , 1996, The Journal of organic chemistry.
[47] R. Rieke,et al. 1,4-Addition of secondary and tertiary alkylzinc bromides to .alpha.,.beta.-unsaturated ketones without a copper catalyst. , 1995 .
[48] P. Knochel,et al. Preparation of new classes of aliphatic, allylic, and benzylic zinc and copper reagents by the insertion of zinc dust into organic halides, phosphates, and sulfonates , 1992 .
[49] P. Knochel,et al. Preparation of highly functionalized magnesium, zinc, and copper aryl and alkenyl organometallics via the corresponding organolithiums , 1992 .
[50] Koichi Tanaka,et al. Reformatsky and Luche reaction in the absence of solvent , 1991 .
[51] R. Rieke,et al. The direct formation of functionalized alkyl(aryl)zinc halides by oxidative addition of highly reactive zinc with organic halides and their reactions with acid chlorides, .alpha.,.beta.-unsaturated ketones, and allylic, aryl, and vinyl halides , 1991 .
[52] M. P. Yeh,et al. General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper , 1988 .
[53] M. P. Yeh,et al. Synthesis and reactivity toward acyl chlorides and enones of the new highly functionalized copper reagents RCu(CN)ZnI , 1988 .
[54] P. Miginiac,et al. Activation of zinc by trimethylchlorosilane. An improved procedure for the preparation of .beta.-hydroxy esters from ethyl bromoacetate and aldehydes or ketones (Reformatsky reaction) , 1987 .
[55] R. Sauvêtre,et al. Preparation et reactivite de fluorovinylzincs , 1985 .
[56] P. Knochel,et al. Addition of functionalized allylic bromides to terminal alkynes , 1984 .
[57] J. Gawroński. Tandem reformatsky reactions of 2-bromopropionates in the presence of chlorotrimethylsilane , 1984 .
[58] K. Gupta,et al. β-Lactam formation by ultrasound-promoted reformatsky type reaction , 1984 .
[59] R. Rieke,et al. Preparation of highly reactive metal powders. New procedure for the preparation of highly reactive zinc and magnesium metal powders , 1981 .
[60] R. Rieke,et al. Activated metals. Preparation of highly reactive zinc , 1973 .
[61] M. Newman. Enolization in the Reformatsky Reaction , 1942 .