Geographical origin of polished rice based on multiple element and stable isotope analyses.

We determined carbon and nitrogen contents (C and N contents) and stable carbon, nitrogen, and oxygen isotopic compositions (δ(13)C, δ(15)N, and δ(18)O) of polished rice in order to develop a simple method to discriminate its geographical origin. As a first attempt, we examined a single cultivar, Koshihikari rice, from 14 different cultivation areas including Australia (n=1), Japan (n=12), and USA (n=1). For all rice samples, C and N contents and the isotopic compositions are consistent with those of general plant materials, being 37.2-40.0% (C content), 0.8-1.4% (N content), -27.1 to -25.4% (δ(13)C), +0.4 to +9.0% (δ(15)N), and +18.8 to +22.9% (δ(18)O). However, its cultivated area is clearly distinguished by a pentagonal radar plot based on the elemental and isotopic compositions. Thus, the comparison of C and N contents and δ(13)C, δ(15)N, and δ(18)O values would potentially be useful for rapid and routine discrimination of geographical origin of the polished rice.

[1]  S. Epstein,et al.  Two Categories of 13C/12C Ratios for Higher Plants , 1971 .

[2]  S. Ambrose,et al.  Reconstruction of African human diet using bone collagen carbon and nitrogen isotope ratios , 1986, Nature.

[3]  Ian Goodall,et al.  The determination of the authenticity of wine from its trace element composition , 1997 .

[4]  K. Różański,et al.  Relation Between Long-Term Trends of Oxygen-18 Isotope Composition of Precipitation and Climate , 1992, Science.

[5]  J. Gray,et al.  Climatic information from 18O/16O ratios of cellulose in tree rings , 1976, Nature.

[6]  G. Shearer,et al.  A COMPARISON OF UNENRICHED VERSUS 15N‐ENRICHED FERTILIZER AS A TRACER FOR N FERTILIZER UPTAKE , 1975 .

[7]  Akemi Yasui,et al.  Analytical Chemistry for Environmental and Human Health. Determination of the geographic origin of brown-rice with trace-element composition. , 2000 .

[8]  G. Shearer,et al.  Variations in the Natural Abundance of 15N of Wheat Plants in Relation to Fertilizer Nitrogen Applications1 , 1975 .

[9]  G. Shearer,et al.  Variation of 15N in Corn and Soil Following Application of Fertilizer Nitrogen 1 , 1973 .

[10]  T. Hirata,et al.  Determination of strontium isotope ratio of brown rice for estimating its provenance , 2002 .

[11]  S. Kawamoto,et al.  Variations in lipid content and fatty acid composition of major non-glutinous rice cultivars in Japan , 2005 .

[12]  S. Kelly,et al.  The application of isotopic and elemental analysis to determine the geographical origin of premium long grain rice , 2002 .

[13]  J. Hayes,et al.  Compound-specific isotopic analyses: a novel tool for reconstruction of ancient biogeochemical processes. , 1990, Organic geochemistry.

[14]  H. Craig Isotopic Variations in Meteoric Waters , 1961, Science.

[15]  P. Ritz,et al.  Milk characterization: effect of the breed , 2005 .

[16]  G. Haberhauer,et al.  The potential of multielement stable isotope analysis for regional origin assignment of butter , 2000 .

[17]  H. Kitazato,et al.  Biogeochemical processes in the saline meromictic Lake Kaiike, Japan: implications from molecular isotopic evidences of photosynthetic pigments. , 2005, Environmental microbiology.

[18]  D. Goldberg,et al.  Stable carbon isotope ratio analysis of Australian orange juices , 2000 .

[19]  T. Hirata,et al.  Determination of the Geographic Origin of Brown-Rice with Isotope Ratios of 11B/10B and 87Sr/86Sr , 2002 .

[20]  Simon D. Kelly,et al.  Tracing the geographical origin of food: The application of multi-element and multi-isotope analysis , 2005 .

[21]  David De Jong,et al.  Detection of adulteration of commercial honey samples by the 13C/12C isotopic ratio , 2003 .

[22]  F. Reniero,et al.  Stable oxygen isotope content of water of EU data-bank wines from Italy, France and Germany , 1999 .

[23]  Olaf Schmidt,et al.  Inferring the origin and dietary history of beef from C, N and S stable isotope ratio analysis , 2005 .