Pyridine Vapors Detection by an Optical Fibre Sensor

An optical fibre sensor has been implemented towards pyridine vapors detection; to achieve this, a novel vapochromic material has been used, which, in solid state, suffers a change in colour from blue to pink-white in presence of pyridine vapours. This complex is added to a solution of PVC (Poly Vinyl Chloride), TBP (Tributylphosphate) and tetrahydrofuran (THF), forming a plasticized matrix; by dip coating technique, the sensing material is fixed onto a cleaved ended optical fibre. The fabrication process was optimized in terms of number of dips and dipping speed, evaluating the final devices by dynamic range. Employing a reflection set up, the absorbance spectra and changes in the reflected optical power of the sensors were registered to determine their response. A linear relation between optical power versus vapor concentration was obtained, with a detection limit of 1 ppm (v/v).

[1]  Carlos Fernández-Valdivielso,et al.  Optical fiber sensor based on lutetium bisphthalocyanine for the detection of gases using standard telecommunication wavelengths , 2003 .

[2]  Andreas Mandelis,et al.  Pd/PVDF thin film hydrogen sensor based on laser-amplitude-modulated optical-transmittance: dependence on H2 concentration and device physics , 1998 .

[3]  Francisco J. Arregui,et al.  Volatile alcoholic compounds fibre optic nanosensor , 2006 .

[4]  Ignacio R. Matias,et al.  Detection of volatile organic compound vapors by using a vapochromic material on a tapered optical fiber , 2000 .

[5]  L B Fay,et al.  Heterocyclic aromatic amine formation in grilled bacon, beef and fish and in grill scrapings. , 1993, Carcinogenesis.

[6]  Yasuhiko Arai,et al.  Sensitivity of fiber-optic carbon dioxide sensors utilizing indicator dye , 2003 .

[7]  H. Steiner,et al.  Online sensing of volatile organic compounds in groundwater using mid-infrared fibre optic evanescent wave spectroscopy: a pilot scale test. , 2003, Water science and technology : a journal of the International Association on Water Pollution Research.

[8]  Pascal Boilot,et al.  Electronic noses inter-comparison, data fusion and sensor selection in discrimination of standard fruit solutions , 2003 .

[9]  Andrea Cusano,et al.  An high sensitivity optical sensor for chloroform vapours detection based on nanometric film of δ-form syndiotactic polystyrene , 2005 .

[10]  A. Strasheim,et al.  NOMENCLATURE, SYMBOLS, UNITS AND THEIR USAGE IN , 1985 .

[11]  Brian D. MacCraith,et al.  Fibre optic ammonia sensing employing novel near infrared dyes , 1998 .

[12]  Francisco J. Arregui,et al.  Development of an In-Fiber Nanocavity Towards Detection of Volatile Organic Gases , 2006, Sensors (Basel, Switzerland).

[13]  Tomasz Markiewicz,et al.  Classification of milk by means of an electronic nose and SVM neural network , 2004 .

[14]  R. Claus,et al.  Optical fiber humidity sensor using a nano Fabry–Perot cavity formed by the ionic self-assembly method , 1999 .

[15]  P. Kubelka Ein Beitrag zur Optik der Farban striche , 1931 .

[16]  J. Goschnick,et al.  Water pollution recognition with the electronic nose KAMINA , 2005 .

[17]  Francisco J. Arregui,et al.  Volatile Organic Compound Optical Fiber Sensors: A Review , 2006, Sensors (Basel, Switzerland).

[18]  Cesar Elosua,et al.  Optical fibre sensors based on vapochromic gold complexes for environmental applications , 2005 .

[19]  H. S. Wolff,et al.  iRun: Horizontal and Vertical Shape of a Region-Based Graph Compression , 2022, Sensors.

[20]  E. Akkaya,et al.  Fiber optic sodium and potassium sensing by using a newly synthesized squaraine dye in PVC matrix. , 2002, Talanta.

[21]  Krishna C. Persaud,et al.  Remote detection of gaseous ammonia using the near infrared transmission properties of polyaniline , 2003 .

[22]  Candido Bariain,et al.  Volatile-organic-compound optic fiber sensor using a gold-silver vapochromic complex , 2006 .

[23]  P. K. Clifford,et al.  Characteristics of semiconductor gas sensors I. Steady state gas response , 1982 .

[24]  Cesar Jauregui,et al.  Wavelength-division-multiplexed distributed fiber Raman amplifier bus network for sensors , 2005, International Conference on Optical Fibre Sensors.

[25]  Carlos Fernández-Valdivielso,et al.  An experimental study about the utilization of Liquicoat® solutions for the fabrication of pH optical fiber sensors , 2002 .