Defect center luminescence spectroscopy in Yb Co-doped silica fibers

Spectroscopic studies of intrinsic defect centers in Yb doped silica fibers are presented. The relationship between the defect centers and photodarkening in Yb doped silica fibers is investigated. Photoluminescence from nonbridging oxygen hole center (NBOHC) and oxygen deficiency center (ODC) defects in several ytterbium-doped silica fibers are presented and analyzed. The photoluminescence spectra and temporal decays are given to determine if the Yb dopant and associated co-dopants which serve as network modifiers in the silica matrix could provide pathways whereby infrared photons could be upconverted into the UV, leading to damage in the fiber.

[1]  L. Norin,et al.  Preventing photodarkening in ytterbium-doped high power fiber lasers; correlation to the UV-transparency of the core glass. , 2008, Optics express.

[2]  David L. Griscom,et al.  Defect structure of glasses: Some outstanding questions in regard to vitreous silica , 1985 .

[3]  K. Kojima,et al.  Local structure around Er3+ ions in sol-gel derived GeO2 glasses studied by vibrational and XAFS spectroscopy , 2004 .

[4]  A. A. Frolov,et al.  UV argon laser induced luminescence changes in germanosilicate fibre preforms , 1996 .

[5]  A. Amossov,et al.  Oxygen-deficient centers in silica glasses: a review of their properties and structure , 1994 .

[6]  D. Payne,et al.  Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation , 2007 .

[7]  Evgenii M Dianov,et al.  Cooperative luminescence and absorption in Ytterbium-doped silica fiber and the fiber nonlinear transmission coefficient at lambda=980 nm with a regard to the Ytterbium ion-pairs' effect. , 2006, Optics express.

[8]  L. Skuja Optically active oxygen-deficiency-related centers in amorphous silicon dioxide , 1998 .

[9]  Joe Wong,et al.  Distribution of defects induced in fused silica by ultraviolet laser pulses before and after treatment with a CO2 laser , 2005 .

[10]  André Croteau,et al.  Characterization of defect luminescence in Yb doped silica fibers: part I NBOHC. , 2008, Optics express.

[11]  D. Åberg,et al.  Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation. , 2007, Optics letters.

[12]  Arai,et al.  Evidence for pair generation of an E' center and a nonbridging oxygen-hole center in gamma -ray-irradiated fluorine-doped low-OH synthetic silica glasses. , 1992, Physical review. B, Condensed matter.

[13]  André Croteau,et al.  Photoexcitation of Yb-doped aluminosilicate fibers at 250 nm: evidence for excitation transfer from oxygen deficiency centers to Yb 3+ , 2010 .

[14]  Linards Skuja,et al.  Direct singlet-to-triplet optical absorption and luminescence excitation band of the twofold-coordinated silicon center in oxygen-deficient glassy SiO 2 , 1994 .

[15]  Yuki Okuda,et al.  Formation of Drawing- or Radiation-Induced Defects in Germanium-Doped Silica Core Optical Fiber , 1994 .

[16]  Linards Skuja,et al.  The origin of the intrinsic 1.9 eV luminescence band in glassy SiO2 , 1994 .

[17]  G. H. Sigel,et al.  Photoluminescence in as-drawn and irradiated silica optical fibers: an assessment of the role of non-bridging oxygen defect centers , 1981 .

[18]  U. Röpke,et al.  Power-law dependence of the photodarkening rate constant on the inversion in Yb doped fibers. , 2009, Optics letters.

[19]  Andre Stesmans,et al.  Defects induced in fused silica by high fluence ultraviolet laser pulses at 355 nm , 2002 .

[20]  S. Unger,et al.  Efficient Yb laser fibers with low photodarkening by optimization of the core composition. , 2008, Optics express.