Closing the Loop on Cadmium - An Assessment of the Material Cycle of Cadmium in the U.S. (11 pp)

Goal, Scope and Background In this study, the major flows of cadmium in the U.S. economy are quantified and the primary sinks are identified to gauge the need for additional policy to minimize the potential human health and ecosystem risks associated with these flows. Because of the concurrent occurrence of cadmium and zinc in ore, we also consider the relevant portions of the material cycle of zinc.Methods We estimated the flows of cadmium through U.S. manufacturing using a mass balance approach with data provided by the U.S. Geological Survey's Minerals Yearbook. Cadmium emissions factors were created using facility specific information found in the U.S. Toxics Release Inventory and were used to model future losses. Data gaps were filled through review of relevant literature. We modeled the import and sales of nickel-cadmium batteries with rechargeable battery usage trends and estimates of market share by battery chemistry.Results and Conclusion Primary cadmium in the U.S. is almost exclusively produced as a co-product of zinc. Almost all zinc and cadmium mined in the U.S. is exported to foreign smelters as ore concentrate. We estimate that the bulk of cadmium consumed in the U.S. economy (~90%) is imported in the form of nickel-cadmium rechargeable batteries. These batteries can be divided into the larger wet-cells and portable rechargeable batteries (PRB). The collection rate for the recycling of large wet cells was found to be high (80%) while the collection rate for PRBs is low (5-20%). The Rechargeable Battery Recycling Corporation (RBRC) is responsible for the collection of these batteries which are recycled exclusively by the International Materials Reclamation Company (INMETCO). The remaining PRBs are generally disposed of in municipal solid waste (MSW) landfills. This study provides a detailed substance flow analysis of U.S. stocks and flows of cadmium in products, however additional research is needed to better quantify the associated exposures and risks. Recommendation and Perspective Based on our analysis, we make four recommendations. First we suggest that if cadmium is to be used, it should be used in long-lived products that can be easily collected and recycled with minimal losses. Second, continued cadmium use should be coupled with renewed efforts on the part of policy-makers to encourage the collection and recycling of cadmium-bearing products. At present, consumers do not see the environmental cost associated with the proper disposal of the cadmium content of NiCd batteries. Policy options for improving recycling rates include collecting deposits and providing rewards for the return of spent batteries, taxing or otherwise discouraging discarding PRBs in municipal solid waste, and providing incentives for extended producer responsibility. Third, we highlight the importance of the connection between zinc mining and the supply of cadmium in designing an effective policy to manage the risks associated with cadmium. Fourth, we recommend that policy measures be taken to provide the necessary data required to improve our understanding of the flow of cadmium into the U.S. in the form of product imports and the amount of cadmium lost or disposed of by recycling processes.

[1]  Rebecca L. Lankey,et al.  Life-Cycle Methods for Comparing Primary and Rechargeable Batteries , 2000 .

[2]  A. Ledin,et al.  Present and Long-Term Composition of MSW Landfill Leachate: A Review , 2002 .

[3]  Reid Lifset,et al.  The characterization of technological zinc cycles , 2003 .

[4]  F. Goodarzi,et al.  Environmental aspects of trace elements in coal , 1995 .

[5]  J. A. Carter,et al.  Pathways of thirty-seven trace elements through coal-fired power plant , 1975 .

[6]  Stefan Anderberg,et al.  Industrial Metabolism at the Regional Level: The Rhine Basin , 1992 .

[7]  Yong-Chul Jang,et al.  Leaching of lead from computer printed wire boards and cathode ray tubes by municipal solid waste landfill leachates. , 2003, Environmental science & technology.

[8]  Vasilis Fthenakis,et al.  Life cycle impact analysis of cadmium in CdTe PV production , 2004 .

[9]  A. Bradshaw,et al.  Toxic Metals in Soil-Plant Systems. , 1995 .

[10]  Stefan Anderberg,et al.  Heavy metal pollution in the Rhine Basin , 1993 .

[11]  Robert U. Ayres,et al.  Industrial Metabolism: Restructuring for Sustainable Development , 1994 .

[12]  Linda Gaines,et al.  Energy and Environmental Impacts of Electric Vehicle Battery Production and Recycling , 1995 .

[13]  G. Klepper,et al.  Industrial Metabolism: A Case Study of the Economics of Cadmium Control , 1995 .

[14]  Carl Johan Rydh,et al.  Impact on global metal flows arising from the use of portable rechargeable batteries. , 2003, The Science of the total environment.

[15]  John Holmberg,et al.  Socio-ecological Indicators for Sustainability. , 1996 .

[16]  Björn A. Andersson Materials availability for large-scale thin-film photovoltaics , 2000 .

[17]  Future Redistribution of Cadmium to Arable Swedish Soils: A Substance Stock Analysis , 2004 .

[18]  Stefan Anderberg,et al.  Old Sins: Industrial Metabolism, Heavy Metal Pollution, and Environmental Transition in Central Europe , 2000 .

[19]  Hsien H. Khoo Zinc Casting and Recycling , 2004 .

[20]  E. Landa,et al.  Tire-wear particles as a source of zinc to the environment. , 2004, Environmental science & technology.

[21]  J R Gronow,et al.  Household hazardous waste in municipal landfills: contaminants in leachate. , 2005, The Science of the total environment.

[22]  Francis C. McMichael,et al.  Recycling batteries , 1998 .

[23]  Carl Johan Rydh Material Flows of Household Batteries in Sweden , 1999 .

[24]  S. Anderberg,et al.  Industrial Ecology and Global Change: Metals Loading of the Environment: Cadmium in the Rhine Basin , 1994 .

[25]  P. G. Reeves,et al.  An improved understanding of soil Cd risk to humans and low cost methods to phytoextract Cd from contaminated soils to prevent soil Cd risks , 2004, Biometals.

[26]  P. G. Reeves,et al.  Marginal nutritional status of zinc, iron, and calcium increases cadmium retention in the duodenum and other organs of rats fed rice-based diets. , 2004, Environmental research.

[27]  Wulf-Peter Schmidt,et al.  Environmental considerations on battery-housing recovery , 1999 .

[28]  J. Pacyna,et al.  An assessment of global and regional emissions of trace metals to the atmosphere from anthropogenic sources worldwide , 2001 .

[29]  William R. Moomaw,et al.  Industrial Ecology and Global Change: Contents , 1994 .

[30]  Vasilis Fthenakis,et al.  End-of-life management and recycling of PV modules , 2000 .

[31]  Carl Johan Rydh,et al.  Life Cycle Inventory of Recycling Portable Nickel-Cadmium Batteries , 2002 .

[32]  Christophe Pécheyran,et al.  Volatile metal species in coal combustion flue gas. , 2002, Environmental science & technology.

[33]  H. Ehrig Quality and Quantity of Sanitary Landfill Leachate , 1983 .