Finite-size effects in fine particles: magnetic and transport properties

Some of the most relevant finite-size and surface effects in the magnetic and transport properties of magnetic fine particles and granular solids are reviewed. The stability of the particle magnetization, superparamagnetic regime and the magnetic relaxation are discussed. New phenomena appearing due to interparticle interactions, such as the collective state and non-equilibrium dynamics, are presented. Surface anisotropy and disorder, spin-wave excitations, as well as the enhancements of the coercive field and particle magnetization are also reviewed. The competition of surface and finite-size effects to settle the magnetic behaviour is addressed. Finally, two of the most relevant phenomena in the transport properties of granular solids are summarized namely, giant magnetoresistance in granular heterogeneous alloys and Coulomb gap in insulating granular solids.

[1]  Slonczewski Jc,et al.  Conductance and exchange coupling of two ferromagnets separated by a tunneling barrier. , 1989 .

[2]  Albert Fert,et al.  Electrical resistivity of ferromagnetic nickel and iron based alloys , 1976 .

[3]  Dimitrov,et al.  Magnetic properties of spherical fcc clusters with radial surface anisotropy. , 1995, Physical review. B, Condensed matter.

[4]  Zhang,et al.  Enhanced temperature-dependent magnetoresistivity of Fe/Cr superlattices. , 1991, Physical review. B, Condensed matter.

[5]  Dimitrov,et al.  Effects of surface anisotropy on hysteresis in fine magnetic particles. , 1994, Physical review. B, Condensed matter.

[6]  P. Levy,et al.  Conductivity and magnetoresistance in magnetic granular films (invited) , 1993 .

[7]  L. Néel Anisotropie magnétique superficielle et surstructures d'orientation , 1954 .

[8]  M. Stearns Simple explanation of tunneling spin-polarization of Fe, Co, Ni and its alloys , 1977 .

[9]  P. Sheng Theory for the Dielectric Function of Granular Composite Media , 1980 .

[10]  C. Chien,et al.  Giant negative magnetoresistance in granular ferromagnetic systems (invited) , 1993 .

[11]  B. Abeles,et al.  Tunneling of Spin-Polarized Electrons and Magnetoresistance in Granular Ni Films , 1976 .

[12]  M. Stearns,et al.  Determination of para‐ and ferromagnetic components of magnetization and magnetoresistance of granular Co/Ag films (invited) , 1994 .

[13]  J. Rivas,et al.  Magnetoresistance in manganite/alumina nanocrystalline composites , 2001 .

[14]  J. Coey Noncollinear Spin Arrangement in Ultrafine Ferrimagnetic Crystallites , 1971 .

[15]  K. O’Grady,et al.  Remanence breakdown in granular alloys at magnetic percolation , 2000 .

[16]  S. Kaul Static critical phenomena in ferromagnets with quenched disorder , 1985 .

[17]  R. Chantrell,et al.  The effect of interactions on GMR in granular solids , 1994 .

[18]  R. Victora,et al.  Predicted time dependence of the switching field for magnetic materials. , 1989, Physical review letters.

[19]  R. Kodama,et al.  Atomic-scale magnetic modeling of oxide nanoparticles , 1999 .

[20]  N. García Conducting ballistic magnetoresistance and tunneling magnetoresistance: Pinholes and tunnel barriers , 2000 .

[21]  P. M. Tedrow,et al.  Spin-polarized electron tunneling , 1994 .

[22]  Jianping Wang,et al.  Ultrahigh coercivity of granular CoCrPt–SiO2 thin films , 2000 .

[23]  H. Rohrer Magnetoresistance of Dilute Alloys , 1968 .

[24]  R. Landauer Electrical resistance of disordered one-dimensional lattices , 1970 .

[25]  A. Morrish,et al.  Noncollinear magnetic structure of CoFe2O4 small particles , 1988 .

[26]  K. O’Grady,et al.  The nature of magnetic interactions in CoFe-Ag(Cu) granular thin films , 2000 .

[27]  J. M. Daughton,et al.  Magnetic Tunneling Applied to Memory (Invited) , 1997 .

[28]  Berkowitz,et al.  Surface Spin Disorder in NiFe2O4 Nanoparticles. , 1996, Physical review letters.

[29]  Inoue,et al.  Theory of tunneling magnetoresistance in granular magnetic films. , 1996, Physical review. B, Condensed matter.

[30]  Tronc,et al.  Superparamagnetic relaxation of weakly interacting particles. , 1994, Physical review letters.

[31]  H. Bertram,et al.  The effect of interactions on the saturation remanence of particulate assemblies , 1973 .

[32]  C. Kittel Introduction to solid state physics , 1954 .

[33]  Garg,et al.  Escape-field distribution for escape from a metastable potential well subject to a steadily increasing bias field. , 1995, Physical review. B, Condensed matter.

[34]  M. Julliere Tunneling between ferromagnetic films , 1975 .

[35]  A. Johnston,et al.  Magnetotransport properties of NiFe–Ag granular alloys: Origin of the thermal behavior , 1997 .

[36]  Jian-Gang Zhu,et al.  Micromagnetic studies of thin metallic films (invited) , 1988 .

[37]  U. Gafvert,et al.  Electron tunneling between ferromagnetic films , 1982 .

[38]  Gerber,et al.  Spin-dependent electronic transport in granular ferromagnets. , 1996, Physical review letters.

[39]  M. Satou,et al.  Magnetic Properties of Iron Oxide Powder treated with Sodium Metaphosphate , 1975 .

[40]  Young,et al.  Giant magnetoresistance in heterogeneous Cu-Co alloys. , 1992, Physical review letters.

[41]  Xiong,et al.  Investigation of giant magnetoresistance in magnetic, concentrated, nanostructured alloys. , 1993, Physical Review B (Condensed Matter).

[42]  C. Chien,et al.  Temperature dependence of spontaneous magnetization of ultrafine Fe particles in Fe‐SiO2 granular solids , 1987 .

[43]  H. Pfeiffer Influence of thermal fluctuations on the magnetic properties of particle assemblies , 1990 .

[44]  G. Tatara,et al.  DOMAIN WALL SCATTERING EXPLAINS 300% BALLISTIC MAGNETOCONDUCTANCE OF NANOCONTACTS , 1999 .

[45]  J. Smit,et al.  Magnetoresistance of ferromagnetic metals and alloys at low temperatures , 1951 .

[46]  S. Ohnuma,et al.  Spin-dependent tunneling phenomena in insulating granular systems , 1997 .

[47]  G. A. Prinz,et al.  Science and Technology of Nanostructured Magnetic Materials , 1991 .

[48]  Xiao,et al.  Origin of the temperature dependence of the giant magnetoresistance in magnetic granular solids. , 1994, Physical review. B, Condensed matter.

[49]  A. Morrish,et al.  Noncollinearity as a size effect of CrO2 small particles , 1982 .

[50]  S. Maekawa,et al.  Effect of Coulomb Blockade on Magnetoresistance in Ferromagnetic Tunnel Junctions , 1998 .

[51]  R. Kodama,et al.  Surface spin disorder in ferrite nanoparticles (invited) , 1997 .

[52]  J. Zhu,et al.  Angular dependence measurement of individual barium ferrite recording particles near the single domain size , 1994 .

[53]  Milani,et al.  Spin relaxation in small free iron clusters. , 1990, Physical review letters.

[54]  A. Aharoni Magnetization buckling in elongated particles of coated iron oxides , 1988 .

[55]  Javier Tejada,et al.  Macroscopic Quantum Tunneling of the Magnetic Moment: Introduction , 1998 .

[56]  P. Gaunt,et al.  Magnetic viscosity in ferromagnets , 1976 .

[57]  V. Wildpaner Monte Carlo study of small magnetic particles , 1974 .

[58]  Finite-size and surface effects in maghemite nanoparticles: Monte Carlo simulations , 2001, cond-mat/0101348.

[59]  Peter M. Levy,et al.  Resistivity due to Domain Wall Scattering , 1997 .

[60]  K. Trohidou,et al.  Magnetic properties of dipolar interacting single-domain particles , 1998 .

[61]  A. Labarta,et al.  Magnetic relaxation of a one‐dimensional model for small particle systems with dipolar interaction: Monte Carlo simulation , 1996 .

[62]  S. Mørup Superparamagnetism and Spin Glass Ordering in Magnetic Nanocomposites , 1994 .

[63]  T. Miyazaki,et al.  Giant magnetic tunneling e ect in Fe/Al2O3/Fe junction , 1995 .

[64]  H. Mamiya,et al.  Effects of cooling field on magnetic relaxation on an iron-nitride fine particle system , 1997 .

[65]  Magnetoresistance of Magnetically Uncoupled Multilayered Structures , 1991 .

[66]  P. Xiong,et al.  Giant magnetoresistance and its evolution in the granular FexAg100−x system (0≤x≤100) , 1993 .

[67]  Taylor,et al.  Exchange-induced spin polarization of conduction electrons in paramagnetic metals. , 1989, Physical review. B, Condensed matter.

[68]  C. Serna,et al.  Coercivity enhancement in γ-Fe2O3 particles dispersed at low-volume fraction , 1998 .

[69]  V. Franco,et al.  CoFe-Cu granular alloys: From noninteracting particles to magnetic percolation , 1999 .

[70]  P. Sheng,et al.  Hopping Conductivity in Granular Metals , 1973 .

[71]  A. K. Jonscher,et al.  The ‘universal’ dielectric response , 1977, Nature.

[72]  V. Franco,et al.  Evidence of domain wall scattering in thin films of granular CoFe-AgCu , 2000 .

[73]  A. Aharoni The remanent state of fine particles , 1993 .

[74]  Q. Pankhurst,et al.  Origin of the spin-canting anomaly in small ferrimagnetic particles. , 1991, Physical review letters.

[75]  Gu,et al.  Electronic-structure calculations of cobalt clusters. , 1993, Physical review. B, Condensed matter.

[76]  R. Kodama,et al.  Finite Size Effects in Antiferromagnetic NiO Nanoparticles , 1997 .

[77]  L. Berger,et al.  Low‐field magnetoresistance and domain drag in ferromagnets , 1978 .

[78]  B. Barbara,et al.  the barrier plot as a tool in magnetic relaxation studies , 1993 .

[79]  J. Kurkijaervi,et al.  INTRINSIC FLUCTUATIONS IN A SUPERCONDUCTING RING CLOSED WITH A JOSEPHSON JUNCTION. , 1972 .

[80]  Boyd,et al.  Two Mechanisms and a Scaling Relation for Dynamics in Ferrofluids. , 1996, Physical review letters.

[81]  Zhang,et al.  Conductivity and magnetoresistance of magnetic multilayered structures. , 1992, Physical review. B, Condensed matter.

[82]  C. Chien,et al.  Magnetization and its temperature dependence in compositionally modulated amorphous Fe70B30‐Ag films , 1987 .

[83]  Lindgård,et al.  Estimation of electronic and structural influence on the thermal magnetic properties of clusters. , 1994, Physical review. B, Condensed matter.

[84]  C. Chien Granular magnetic solids (invited) , 1991 .

[85]  J. Coey,et al.  Magnetoresistance of chromium dioxide powder compacts , 1998 .

[86]  J. Gregg,et al.  Jitterbug spin channel mixing in heterogeneous giant magnetoresistive material , 1996 .

[87]  Henry,et al.  Spin accumulation and domain wall magnetoresistance in 35 nm Co wires , 2000, Physical review letters.

[88]  Shufeng Zhang Theory of giant magnetoresistance in magnetic granular films , 1992 .

[89]  K. O’Grady,et al.  The effect of the microstructure on the magnetic interactions in CoFe–AgCu granular films: From demagnetizing to magnetizing interactions , 1997 .

[90]  J. S. Rowlinson,et al.  Phase Transitions and Critical Phenomena , 1972 .

[91]  Jiang,et al.  Giant magnetoresistance in nonmultilayer magnetic systems. , 1992, Physical review letters.