Review on Conductive Polymer/CNTs Nanocomposites Based Flexible and Stretchable Strain and Pressure Sensors

In the last decade, significant developments of flexible and stretchable force sensors have been witnessed in order to satisfy the demand of several applications in robotic, prosthetics, wearables and structural health monitoring bringing decisive advantages due to their manifold customizability, easy integration and outstanding performance in terms of sensor properties and low-cost realization. In this paper, we review current advances in this field with a special focus on polymer/carbon nanotubes (CNTs) based sensors. Based on the electrical properties of polymer/CNTs nanocomposite, we explain underlying principles for pressure and strain sensors. We highlight the influence of the manufacturing processes on the achieved sensing properties and the manifold possibilities to realize sensors using different shapes, dimensions and measurement procedures. After an intensive review of the realized sensor performances in terms of sensitivity, stretchability, stability and durability, we describe perspectives and provide novel trends for future developments in this intriguing field.

[1]  Petra Pötschke,et al.  The influence of matrix viscosity on MWCNT dispersion and electrical properties in different thermoplastic nanocomposites , 2012 .

[2]  Homayoun Najjaran,et al.  Low-cost ultra-stretchable strain sensors for monitoring human motion and bio-signals , 2018 .

[3]  P. Verma,et al.  Electrical conductivity of CNT/polymer composites: 3D printing, measurements and modeling , 2020 .

[4]  Dimitris C. Lagoudas,et al.  Characterization of electrical and thermal properties of carbon nanotube/epoxy composites , 2014 .

[5]  Hang Zhao,et al.  Highly sensitive piezo-resistive graphite nanoplatelet-carbon nanotube hybrids/polydimethylsilicone composites with improved conductive network construction. , 2015, ACS applied materials & interfaces.

[6]  O. Kanoun,et al.  Flexible strain sensing filaments based on styrene-butadiene-styrene co-polymer mixed with carbon particle filled thermoplastic polyurethane , 2018, International Conference Nanotechnology for Instrumentation and Measurement.

[7]  Hyosang Lee,et al.  Soft Nanocomposite Based Multi-point, Multi-directional Strain Mapping Sensor Using Anisotropic Electrical Impedance Tomography , 2017, Scientific Reports.

[8]  Michael C. McAlpine,et al.  Flexible piezoelectric PMN-PT nanowire-based nanocomposite and device. , 2013, Nano letters.

[9]  Pei Huang,et al.  Multifunctional Wearable Device Based on Flexible and Conductive Carbon Sponge/Polydimethylsiloxane Composite. , 2016, ACS applied materials & interfaces.

[10]  T. Pichler,et al.  Functionalization of carbon nanotubes , 2004 .

[11]  Shaohong Shi,et al.  Preparation and 3D-printing of highly conductive polylactic acid/carbon nanotube nanocomposites via local enrichment strategy , 2019, RSC advances.

[12]  Mohammad Reza Khosravani,et al.  3D-printed sensors: Current progress and future challenges , 2020, Sensors and Actuators A: Physical.

[13]  Olfa Kanoun,et al.  Processing and characterization of MWCNTs/epoxy nanocomposites thin films for strain sensing applications , 2017 .

[14]  Olfa Kanoun,et al.  Flexible Carbon Nanotube Films for High Performance Strain Sensors , 2014, Sensors.

[15]  Olfa Kanoun,et al.  Electronic Motion Capture Glove based on Highly Sensitive Nanocomposite Sensors , 2019, 2019 16th International Multi-Conference on Systems, Signals & Devices (SSD).

[16]  Inkyu Park,et al.  Transparent, Flexible Strain Sensor Based on a Solution-Processed Carbon Nanotube Network. , 2017, ACS applied materials & interfaces.

[17]  Sida Luo,et al.  SWCNT/Graphite Nanoplatelet Hybrid Thin Films for Self‐Temperature‐Compensated, Highly Sensitive, and Extensible Piezoresistive Sensors , 2013, Advanced materials.

[18]  W. Blau,et al.  Electrical and rheological percolation of PMMA/MWCNT nanocomposites as a function of CNT geometry and functionality , 2010 .

[19]  Hidenori Mimura,et al.  Rapid-Response, Widely Stretchable Sensor of Aligned MWCNT/Elastomer Composites for Human Motion Detection , 2016 .

[20]  Yong Lin,et al.  A highly stretchable strain sensor based on a graphene/silver nanoparticle synergic conductive network and a sandwich structure , 2016 .

[21]  Xing Yang,et al.  Flexible capacitive pressure sensor based on multi-walled carbon nanotube electrodes , 2017 .

[22]  Wei Jiang,et al.  A stretchable and transparent strain sensor based on sandwich-like PDMS/CNTs/PDMS composite containing an ultrathin conductive CNT layer , 2020 .

[23]  G. Boiteux,et al.  New melt mixing polyethylene multiwalled carbon nanotube nanocomposites with very low electrical percolation threshold , 2013 .

[24]  T. Paixão,et al.  3D-printed flexible device combining sampling and detection of explosives , 2019, Sensors and Actuators B: Chemical.

[25]  S. Lanceros‐Méndez,et al.  Effect of carbon nanotube type and functionalization on the electrical, thermal, mechanical and electromechanical properties of carbon nanotube/styrene–butadiene–styrene composites for large strain sensor applications , 2014 .

[26]  M. Endo,et al.  Shear-induced preferential alignment of carbon nanotubes resulted in anisotropic electrical conductivity of polymer composites , 2006 .

[27]  I. Alig,et al.  Electrical conductivity recovery in carbon nanotube–polymer composites after transient shear , 2007 .

[28]  N. Lee,et al.  Stretchable, Transparent, Ultrasensitive, and Patchable Strain Sensor for Human-Machine Interfaces Comprising a Nanohybrid of Carbon Nanotubes and Conductive Elastomers. , 2015, ACS nano.

[29]  Paolo Lugli,et al.  Flexible Capacitive Tactile Sensors Based on Carbon Nanotube Thin Films , 2015, IEEE Sensors Journal.

[30]  Myounggu Park,et al.  Strain-dependent electrical resistance of multi-walled carbon nanotube/polymer composite films , 2008, Nanotechnology.

[31]  Gerard Cummins,et al.  Nanocomposite-Based Microstructured Piezoresistive Pressure Sensors for Low-Pressure Measurement Range , 2018, Micromachines.

[32]  Bowen Ji,et al.  Flexible Capacitive Hydrogel Tactile Sensor With Adjustable Measurement Range Using Liquid Crystal and Carbon Nanotubes Composites , 2017, IEEE Transactions on Electron Devices.

[33]  T. Gupta,et al.  Strong, stretchable and ultrasensitive MWCNT/TPU nanocomposites for piezoresistive strain sensing , 2019, Composites Part B: Engineering.

[34]  Olfa Kanoun,et al.  Evaluation of the piezoresistive behavior of multifunctional nanocomposites thin films , 2014, 2014 IEEE 11th International Multi-Conference on Systems, Signals & Devices (SSD14).

[35]  Amin Khajeh,et al.  Fabrication of piezoresistive based pressure sensor via purified and functionalized CNTs/PDMS nanocomposite: Toward development of haptic sensors , 2017 .

[36]  Sang-Gook Kim,et al.  Extremely Elastic Wearable Carbon Nanotube Fiber Strain Sensor for Monitoring of Human Motion. , 2015, ACS nano.

[37]  O. Kanoun,et al.  Temperature Self-Compensated Strain Sensors based on MWCNT-Graphene Hybrid Nanocomposite , 2019, Journal of Composites Science.

[38]  Xiangli Liu,et al.  Integrated Resistive-Capacitive Strain Sensors Based on Polymer–Nanoparticle Composites , 2020 .

[39]  M. Lima,et al.  Elastomeric Conductive Composites Based on Carbon Nanotube Forests , 2010, Advanced materials.

[40]  Hesheng Xia,et al.  Polymer-encapsulated carbon nanotubes prepared through ultrasonically initiated in situ emulsion polymerization , 2003 .

[41]  L. Lorenzelli,et al.  Stretchable resistive pressure sensor based on CNT-PDMS nanocomposites , 2015, 2015 11th Conference on Ph.D. Research in Microelectronics and Electronics (PRIME).

[42]  B. B. Narakathu,et al.  Development of a novel carbon nanotube based printed and flexible pressure sensor , 2017, 2017 IEEE Sensors Applications Symposium (SAS).

[43]  Feng Xu,et al.  3D Printing Technologies for Flexible Tactile Sensors toward Wearable Electronics and Electronic Skin , 2018, Polymers.

[44]  Wei Yang,et al.  A comparison of melt and solution mixing on the dispersion of carbon nanotubes in a poly(vinylidene fluoride) matrix , 2012 .

[45]  Apostolos Avgeropoulos,et al.  Non-covalent functionalization of carbon nanotubes with polymers , 2014 .

[46]  Zhiqiang Lin,et al.  Ultra-stretchable and highly sensitive strain sensor based on gradient structure carbon nanotubes. , 2018, Nanoscale.

[47]  Jian Zhou,et al.  Coaxial Thermoplastic Elastomer‐Wrapped Carbon Nanotube Fibers for Deformable and Wearable Strain Sensors , 2018 .

[48]  L. Tong,et al.  A multifunctional skin-like wearable optical sensor based on an optical micro-/nanofibre. , 2020, Nanoscale.

[49]  Olfa Kanoun,et al.  Flexible piezoresistive sensor matrix based on a carbon nanotube PDMS composite for dynamic pressure distribution measurement , 2019, Journal of Sensors and Sensor Systems.

[50]  R. Ruoff,et al.  Stretchable and highly sensitive graphene-on-polymer strain sensors , 2012, Scientific Reports.

[51]  T. Chou,et al.  Highly stretchable multi-walled carbon nanotube/thermoplastic polyurethane composite fibers for ultrasensitive, wearable strain sensors. , 2019, Nanoscale.

[52]  Changyu Shen,et al.  Electrically conductive strain sensing polyurethane nanocomposites with synergistic carbon nanotubes and graphene bifillers. , 2016, Nanoscale.

[53]  B. Lee,et al.  Effect of carbon nanotube alignment on nanocomposite sensing performance , 2020, Materials Research Express.

[54]  F. K. Hansen,et al.  The Optimum Dispersion of Carbon Nanotubes for Epoxy Nanocomposites: Evolution of the Particle Size Distribution by Ultrasonic Treatment , 2012 .

[55]  Bo Li,et al.  Highly Stretchable Core-Sheath Fibers via Wet-Spinning for Wearable Strain Sensors. , 2018, ACS applied materials & interfaces.

[56]  I. Kinloch,et al.  Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites , 2003 .

[57]  S. Chang,et al.  Highly Sensitive Piezocapacitive Sensor for Detecting Static and Dynamic Pressure Using Ion-Gel Thin Films and Conductive Elastomeric Composites. , 2017, ACS applied materials & interfaces.

[58]  W. Kaminsky Polyolefin-nanocomposites with special properties by in-situ polymerization , 2018, Frontiers of Chemical Science and Engineering.

[59]  Chuck Zhang,et al.  Processing and modeling of conductive thermoplastic/carbon nanotube films for strain sensing , 2008 .

[60]  Lai-fei Cheng,et al.  A 3D-printed stretchable structural supercapacitor with active stretchability/flexibility and remarkable volumetric capacitance , 2020, Journal of Materials Chemistry A.

[61]  Olfa Kanoun,et al.  Assessing the electrical behaviour of MWCNTs/epoxy nanocomposite for strain sensing , 2017 .

[62]  W. Khan,et al.  Carbon Nanotube-Based Polymer Composites: Synthesis, Properties and Applications , 2016 .

[63]  Chen Zhu,et al.  Stretchable, Highly Durable Ternary Nanocomposite Strain Sensor for Structural Health Monitoring of Flexible Aircraft , 2017, Sensors.

[64]  Satish Nagarajaiah,et al.  The strain sensing and thermal–mechanical behavior of flexible multi-walled carbon nanotube/polystyrene composite films , 2011 .

[65]  Xiaodong He,et al.  Directional sensing based on flexible aligned carbon nanotube film nanocomposites. , 2018, Nanoscale.

[66]  Olfa Kanoun,et al.  Piezoresistive performance characterization of strain sensitive multi-walled carbon nanotube-epoxy nanocomposites , 2017 .

[67]  M. Sitti,et al.  Self‐Sensing Paper Actuators Based on Graphite–Carbon Nanotube Hybrid Films , 2018, Advanced science.

[68]  Khalil Arshak,et al.  Development of new capacitive strain sensors based on thick film polymer and cermet technologies , 2000 .

[69]  Qingting Liu,et al.  Highly flexible strain sensors based on polydimethylsiloxane/carbon nanotubes (CNTs) prepared by a swelling/permeating method and enhanced sensitivity by CNTs surface modification , 2019, Composites Science and Technology.

[70]  Mohamed R. Berber,et al.  CARBON NANOTUBES CURRENT PROGRESS OF THEIR POLYMER COMPOSITES , 2016 .

[71]  Zhanhu Guo,et al.  2D end-to-end carbon nanotube conductive networks in polymer nanocomposites: a conceptual design to dramatically enhance the sensitivities of strain sensors. , 2018, Nanoscale.

[72]  S. Tjong,et al.  Electrical behavior of polypropylene/multiwalled carbon nanotube nanocomposites with low percolation threshold , 2007 .

[73]  Peng Chen,et al.  Flexible Strain Sensor Based on Carbon Black/Silver Nanoparticles Composite for Human Motion Detection , 2018, Materials.

[74]  Vithyasaahar Sethumadhavan,et al.  Development of printable electronic materials for low cost flexible sensor fabrication , 2017, 2017 IEEE International Conference on Electrical, Instrumentation and Communication Engineering (ICEICE).

[75]  Dong-Wook Jeong,et al.  Highly stretchable conductors and piezocapacitive strain gauges based on simple contact-transfer patterning of carbon nanotube forests , 2014 .

[76]  J. Pekárek,et al.  Carbon nanostructures used in capacitive sensors as the surface increase element , 2009, International Symposium for Design and Technology in Electronic Packaging.

[77]  Jing Li,et al.  Effects of surfactant treatment on mechanical and electrical properties of CNT/epoxy nanocomposites , 2008 .

[78]  Petra Pötschke,et al.  Influence of material and processing parameters on carbon nanotube dispersion in polymer melts , 2011 .

[79]  David Harrison,et al.  3D printing of highly flexible supercapacitor designed for wearable energy storage , 2017 .

[80]  Y. Sakka,et al.  Alignment of carbon nanotubes by magnetic fields and aqueous dispersion , 2009 .

[81]  H. Brünig,et al.  Orientation of multiwalled carbon nanotubes in composites with polycarbonate by melt spinning , 2005 .

[82]  Johannes K. Sell,et al.  Hysteresis and Material Effects of Printed Strain Gauges Embedded in Organic Coatings , 2017 .

[83]  M. Yang,et al.  Dispersion of carbon nanotubes in polymer matrix by in-situ emulsion polymerization , 2004 .

[84]  O. Kanoun,et al.  Highly sensitive capacitive pressure sensors for robotic applications based on carbon nanotubes and PDMS polymer nanocomposite , 2019, Journal of Sensors and Sensor Systems.

[85]  H. Friedrich,et al.  3D printing of CNT- and graphene-based conductive polymer nanocomposites by fused deposition modeling , 2017 .

[86]  H. Tanabi,et al.  Effect of CNTs dispersion on electrical, mechanical and strain sensing properties of CNT/epoxy nanocomposites , 2019, Results in Physics.

[87]  Olfa Kanoun,et al.  Electrical Characterization of Elongation Sensors Based on SBS-CTPU Filaments , 2018, 2018 15th International Multi-Conference on Systems, Signals & Devices (SSD).

[88]  Tao Liu,et al.  A Review: Carbon Nanotube-Based Piezoresistive Strain Sensors , 2012, J. Sensors.

[89]  P. Slobodian,et al.  Multifunctional flexible and stretchable polyurethane/carbon nanotube strain sensor for human breath monitoring , 2019, Polymers for Advanced Technologies.

[90]  B. D. Boruah,et al.  Capacitive behavior of carbon nanotube thin film induced by deformed ZnO microspheres , 2017, Nanotechnology.

[91]  A. Oueriagli,et al.  Electrical conductivity of multiwalled carbon nanotubes/polyester polymer nanocomposites , 2016 .

[92]  Ning Hu,et al.  Effect of fabrication process on electrical properties of polymer/multi-wall carbon nanotube nanocomposites , 2008 .

[93]  Huamin Zhou,et al.  Highly flexible and stretchable MWCNT/HEPCP nanocomposites with integrated near-IR, temperature and stress sensitivity for electronic skin , 2018 .

[94]  Simon S. Park,et al.  Effect of CNT alignment on the strain sensing capability of carbon nanotube composites , 2013 .

[95]  S. Mitra,et al.  Controlled synthesis of reduced graphene oxide-carbon nanotube hybrids and their aqueous behavior , 2020, Journal of Nanoparticle Research.

[96]  Craig E. Banks,et al.  Future of additive manufacturing: Overview of 4D and 3D printed smart and advanced materials and their applications , 2021 .

[97]  Panayiotis Georgiopoulos,et al.  Strain sensing in polymer/carbon nanotube composites by electrical resistance measurement , 2015 .

[98]  O. Kanoun,et al.  Customizing hydrothermal properties of inkjet printed sensitive films by functionalization of carbon nanotubes , 2020, Nanotechnology.

[99]  Sunwoo Woo,et al.  A thin all-elastomeric capacitive pressure sensor array based on micro-contact printed elastic conductors , 2014 .

[100]  L. Fambri,et al.  Fused Filament Fabrication of Piezoresistive Carbon Nanotubes Nanocomposites for Strain Monitoring , 2020, Frontiers in Materials.

[101]  Clifford R. Pollock,et al.  Stretchable distributed fiber-optic sensors , 2020, Science.

[102]  Prasad K. Yarlagadda,et al.  Sandwiched carbon nanotube film as strain sensor , 2012 .

[103]  W. Bauhofer,et al.  A review and analysis of electrical percolation in carbon nanotube polymer composites , 2009 .

[104]  D. Xiang,et al.  Enhanced performance of 3D printed highly elastic strain sensors of carbon nanotube/thermoplastic polyurethane nanocomposites via non-covalent interactions , 2019, Composites Part B: Engineering.

[105]  Wei Wang,et al.  Recent Developments for Flexible Pressure Sensors: A Review , 2018, Micromachines.

[106]  Yirong Lin,et al.  Electrical and mechanical tuning of 3D printed photopolymer–MWCNT nanocomposites through in situ dispersion , 2019, Journal of Applied Polymer Science.

[107]  O. Kanoun,et al.  Investigation on the Influence of Solvents on MWCNT-PDMS Nanocomposite Pressure Sensitive Films , 2017 .

[108]  A Highly Sensitive Flexible Piezoresistive Sensor Based on Wrinkled CNT-PDMS , 2018, 2018 IEEE 13th Annual International Conference on Nano/Micro Engineered and Molecular Systems (NEMS).

[109]  S. Orrego,et al.  Ultrasensitive, flexible, and low-cost nanoporous piezoresistive composites for tactile pressure sensing. , 2019, Nanoscale.

[110]  Pooi See Lee,et al.  Highly Stretchable Piezoresistive Graphene–Nanocellulose Nanopaper for Strain Sensors , 2014, Advanced materials.

[111]  Yei Hwan Jung,et al.  Stretchable silicon nanoribbon electronics for skin prosthesis , 2014, Nature Communications.

[112]  Jae-Doo Huh,et al.  Simple CNT nanocomposite piezoresistive press sensor , 2017, 2017 International Conference on Information and Communication Technology Convergence (ICTC).

[113]  J. Fischer,et al.  Effect of nanotube alignment on percolation conductivity in carbon nanotube/polymer composites , 2005 .