Optical Fiber LSPR Biosensor Prepared by Gold Nanoparticle Assembly on Polyelectrolyte Multilayer

This article provides a novel method of constructing an optical fiber localized surface plasmon resonance (LSPR) biosensor. A gold nanoparticle (NP) assembled film as the sensing layer was built on the polyelectrolyte (PE) multilayer modified sidewall of an unclad optical fiber. By using a trilayer PE structure, we obtained a monodisperse gold NP assembled film. The preparation procedure for this LSPR sensor is simple and time saving. The optical fiber LSPR sensor has higher sensitivity and outstanding reproducibility. The higher anti-interference ability for response to an antibody makes it a promising method in application as a portable immuno-sensor.

[1]  H. S. Wolff,et al.  iRun: Horizontal and Vertical Shape of a Region-Based Graph Compression , 2022, Sensors.

[2]  G. Frens Controlled Nucleation for the Regulation of the Particle Size in Monodisperse Gold Suspensions , 1973 .

[3]  Yu-Quan Chen,et al.  Organic vapour sensing using localized surface plasmon resonance spectrum of metallic nanoparticles self assemble monolayer. , 2007, Talanta.

[4]  Giuseppe Zerbi,et al.  Use of a Geometry Optimized Fiber-Optic Surface-Enhanced Raman Scattering Sensor in Trace Detection , 2007, Applied spectroscopy.

[5]  Giuseppe Zerbi,et al.  Fiber-optic SERS sensor with optimized geometry , 2007 .

[6]  Jaw-Luen Tang,et al.  Fiber-optic biochemical sensing with a colloidal gold-modified long period fiber grating , 2006 .

[7]  W. A. Murray,et al.  Overlayers on silver nanotriangles: Field confinement and spectral position of localized surface plasmon resonances. , 2006, Nano letters.

[8]  D. Astruc,et al.  Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. , 2004, Chemical reviews.

[9]  Kotaro Kajikawa,et al.  Optical fiber affinity biosensor based on localized surface plasmon resonance , 2004 .

[10]  Yi-Fang Lin,et al.  Fiber-optic chemical and biochemical probes based on localized surface plasmon resonance , 2006 .

[11]  Guangzhao Zhang,et al.  Roles of chain conformation and interpenetration in the growth of a polyelectrolyte multilayer. , 2008, The journal of physical chemistry. B.

[12]  Bu Feng Preparation of Localized Surface Plasmon Resonance Sensing Film with Gold Colloid by Electrostatic Assembly , 2008 .

[13]  Yuan Wang,et al.  Electrodeposition of large size gold nanoparticles on indium tin oxide glass and application as refractive index sensor , 2009 .

[14]  Ashutosh Chilkoti,et al.  A colorimetric gold nanoparticle sensor to interrogate biomolecular interactions in real time on a surface. , 2002, Analytical chemistry.

[15]  C. Mirkin,et al.  Controlling anisotropic nanoparticle growth through plasmon excitation , 2003, Nature.

[16]  G. Frens Controlled nucleation for the regulation of the particle size in monodisperse gold solutions , 1973 .

[17]  K. Leosson,et al.  Evanescent-wave fluorescence microscopy using symmetric planar waveguides. , 2009, Optics express.

[18]  Tsao-Jen Lin,et al.  Reflection-based localized surface plasmon resonance fiber-optic probe for chemical and biochemical sensing at high-pressure conditions , 2007 .

[19]  K. Lance Kelly,et al.  Chain Length Dependence and Sensing Capabilities of the Localized Surface Plasmon Resonance of Silver Nanoparticles Chemically Modified with Alkanethiol Self-Assembled Monolayers , 2001 .

[20]  L. Chau,et al.  Colloidal gold-modified optical fiber for chemical and biochemical sensing. , 2003, Analytical chemistry.