ELECTROCHEMICAL SERIES

There are three tables for this electrochemical series. Each table lists standard reduction potentials, E° values, at 298.15 K (25 °C), and at a pressure of 101.325 kPa (1 atm). Table 1 is an alphabetical listing of the elements, according to the symbol of the elements. Thus, data for silver (Ag) precede those for aluminum (Al). Table 2 lists only those reduction reactions that have E° values positive in respect to the standard hydrogen electrode. In Table 2, the reactions are listed in the order of increasing positive potential, and they range from 0.0000 V to + 3.4 V. Table 3 lists only those reduction potentials which have E° negative with respect to the standard hydrogen electrode. In Table 3, the reactions are listed in the order of decreasing potential and range from 0.0000 V to –4.10 V. The reliability of the potentials is not the same for all the data. Typically, the values with fewer significant figures have lower reliability. The values of reduction potentials, in particular those of less common reactions, are not definite; they are subject to occasional revisions. Abbreviations: ac = acetate; bipy = 2,2 ́-dipyridine, or bipyridine; en = ethylenediamine; phen = 1,10-phenanthroline.