Temperature dependence of trap creation in silicon dioxide

The controversy over whether the rate of trap creation in silicon dioxide or at its interfaces with contacting electrodes increases or decreases at low temperature in metal‐oxide‐semiconductor structures is resolved. This is done experimentally by separating the strongly temperature‐dependent background trapping in the interfacial regions from trap creation by hot electrons. As will be demonstrated here, the trap‐generation rate is reduced at low temperatures regardless of the injection mode into the oxide conduction band, but the buildup of the created sites shows no saturation. Tunnel injection through or hot electron emission over the interfacial energy barrier are compared and discussed in detail. Also, our data are compared to radiation damage studies of others and their models using the motion of a hydrogen‐related species to the cathodic interface where it interacts with defect sites to produce the observed interface states.

[1]  M. Aslam,et al.  Common origin for electron and hole traps in MOS devices , 1987, IEEE Transactions on Electron Devices.

[2]  Seiji Horiguchi,et al.  Interface‐trap generation modeling of Fowler–Nordheim tunnel injection into ultrathin gate oxide , 1985 .

[3]  Patrick M. Lenahan,et al.  Hole traps and trivalent silicon centers in metal/oxide/silicon devices , 1984 .

[4]  Max J. Schulz,et al.  Insulating Films on Semiconductors , 1981 .

[5]  G.J. Dunn Effect of an Al overlayer on interface states in poly-Si gate MOS capacitors , 1989, IEEE Electron Device Letters.

[6]  Tak H. Ning,et al.  Thermal reemission of trapped electrons in SiO2 , 1978 .

[7]  Temperature effects on electron trap generation and occupation in SiO2 , 1988 .

[8]  Massimo V. Fischetti,et al.  Electron heating studies in silicon dioxide: Low fields and thick films , 1986 .

[9]  Bruce E. Deal,et al.  Interface states and electron spin resonance centers in thermally oxidized (111) and (100) silicon wafers , 1981 .

[10]  M. Fischetti,et al.  The effect of gate metal and SiO2 thickness on the generation of donor states at the Si‐SiO2 interface , 1985 .

[11]  Toshikazu Nishida,et al.  Observation of threshold oxide electric field for trap generation in oxide films on silicon , 1988 .

[12]  D. R. Young,et al.  Identification of electron traps in thermal silicon dioxide films , 1981 .

[13]  S. Lai,et al.  Interface trap generation in silicon dioxide when electrons are captured by trapped holes , 1983 .

[14]  Donald R. Young,et al.  Reduction of electron trapping in silicon dioxide by high‐temperature nitrogen anneal , 1981 .

[15]  P. Balk,et al.  Elimination and Generation of Si ‐ SiO2 Interface Traps by Low Temperature Hydrogen Annealing , 1988 .

[16]  Brower Kl,et al.  Kinetics of H2 passivation of Pb centers at the (111) Si-SiO2 interface. , 1988 .

[17]  S. Bardy,et al.  Degradation of metal/oxide/semiconductor structures by Fowler-Nordheim tunnelling injection , 1987 .

[18]  Tierney,et al.  Direct observation of the threshold for electron heating in silicon dioxide. , 1986, Physical review letters.

[19]  Y. Nissan-Cohen,et al.  The effect of hydrogen on trap generation, positive charge trapping, and time-dependent dielectric breakdown of gate oxides , 1988, IEEE Electron Device Letters.

[20]  S. A. Grot,et al.  Temperature dependence of electron trapping in metal‐oxide‐semiconductor devices as a function of the injection mode , 1988 .

[21]  J. Moret,et al.  Charge trapping and breakdown in thin SiO2 polysilicon-gate MOS capacitors☆ , 1987 .

[22]  James Stasiak,et al.  Trap creation in silicon dioxide produced by hot electrons , 1989 .

[23]  P. S. Winokur,et al.  The Role of Hydrogen in Radiation-Induced Defect Formation in Polysilicon Gate MOS Devices , 1987, IEEE Transactions on Nuclear Science.

[24]  D. Dimaria,et al.  Correlation of trap creation with electron heating in silicon dioxide , 1987 .

[25]  D. Dimaria,et al.  An electron paramagnetic resonance study of electron injected oxides in metal‐oxide‐semiconductor capacitors , 1988 .

[26]  Douglas A. Buchanan,et al.  Interface and bulk trap generation in metal‐oxide‐semiconductor capacitors , 1990 .

[27]  M. Heyns,et al.  Comparison of high-field stress effects in metal-oxide-semiconductor structures with aluminum and polycrystalline silicon gates using internal photoemission measurements , 1985 .

[28]  P. Kenkare,et al.  Relationship between trapped holes, positive ions, and interface states in irradiated Si‐SiO2 structures , 1989 .

[29]  Donald R. Young,et al.  The effects of water on oxide and interface trapped charge generation in thermal SiO2 films , 1981 .

[30]  Paul M. Solomon,et al.  Direct measurement of the energy distribution of hot electrons in silicon dioxide , 1985 .

[31]  J. M. Andrews,et al.  Electrochemical Charging of Thermal SiO2 Films by Injected Electron Currents , 1971 .

[32]  D. Dimaria,et al.  Parameter Dependence of RIE Induced Radiation Damage in Silicon Dioxide , 1981 .

[33]  Kirtley,et al.  Theory of high-field electron transport in silicon dioxide. , 1985, Physical review. B, Condensed matter.

[34]  Patrick M. Lenahan,et al.  Electron spin resonance study of high field stressing in metal‐oxide‐silicon device oxides , 1986 .

[35]  Thomas N. Theis,et al.  Electron heating in silicon dioxide and off‐stoichiometric silicon dioxide films , 1985 .

[36]  Hisham Z. Massoud,et al.  Electron trapping in SiO2 at 295 and 77 °K , 1979 .

[37]  E. Harari Dielectric breakdown in electrically stressed thin films of thermal SiO2 , 1978 .

[38]  Y. Nissan-Cohen,et al.  Trap generation and occupation dynamics in SiO2 under charge injection stress , 1986 .

[39]  K. L. Brower,et al.  Chemical kinetics of hydrogen and (111)Si-SiO2 interface defects , 1990 .

[40]  Dennis B. Brown,et al.  Time dependence of interface trap formation in MOSFETs following pulsed irradiation , 1988 .

[41]  B. Eitan,et al.  Current induced trap generation in SiO2 , 1982 .

[42]  D. Dimaria,et al.  Determination of insulator bulk trapped charge densities and centroids from photocurrent‐voltage charactersitcs of MOS structures , 1976 .

[43]  P. Lenahan,et al.  Nature of the E’ deep hole trap in metal‐oxide‐semiconductor oxides , 1987 .

[44]  R. F. De Keersmaecker,et al.  Oxide field dependence of SiSiO2 interface state generation and charge trapping during electron injection , 1989 .

[45]  M. Heyns,et al.  Trap generation and electron detrapping in SiO2 during high‐field stressing of metal‐oxide‐semiconductor structures , 1984 .

[46]  S. Lai Effects of gate metals on interface effects in metal oxide semiconductor systems after electron trapping , 1982 .

[47]  M. Fischetti,et al.  Vacuum emission of hot electrons from silicon dioxide at low temperatures , 1988 .

[48]  David L. Griscom,et al.  Formation of interface traps in MOSFETs during annealing following low temperature irradiation , 1988 .

[49]  Donald R. Young,et al.  Hydrogen migration under avalanche injection of electrons in Si metal‐oxide‐semiconductor capacitors , 1983 .

[50]  D. Dimaria,et al.  Strong electric field heating of conduction-band electrons in SiO2 , 1984 .

[51]  F. B. McLean,et al.  Temperature- and Field-Dependent Charge Relaxation in SiO2 Gate Insulators , 1978, IEEE Transactions on Nuclear Science.

[52]  Patrick M. Lenahan,et al.  Fundamental differences between thick and thin oxides subjected to high electric fields , 1987 .