Ineducable us: the applications and contexts of microscopy used for the characterisation of historic building materials

The analysis by microscopy of the compositions and microstructures of geomaterials found in historic structures and buildings is integral to archaeological, art-historical, conservation and restoration-related investigations, and supports decision making for material replacement and repair. In archaeology there is a need to elucidate past social, economic and technological processes, and to understand the environmental impacts of past human activities related to materials use. Standard light and electron microscopy are most commonly employed, but high resolution methods such as transmission electron and three-dimensional tomography such as µ-CT are also being used. Experimental and novel developments, where they overlap with advanced materials science, are uncommon. The application of scientific characterisation frames cultural heritage value, reinforcing our understanding of authenticity and integrity. Characterisation is constrained, in turn, by the values system that operates in cultural heritage. International charters and conservation philosophy necessitate the application of science to contextualising conservation. However, the appearance of science in heritage work has also led to the performance of science for its own sake (‘endoscience’, sensu Munoz Vinas, Contemporary Theory of Conservation, Routledge, 2011). This moves some to suggest that there is a disconnect between scientific work and its practical value. Apparent communication problems between scientists applying microscopy and other stakeholders require changes to management of material characterisation in heritage projects.

[1]  M. Gómez-Heras,et al.  The benefit of a tough skin: bullet holes, weathering and the preservation of heritage , 2017, Royal Society Open Science.

[2]  Ewan Hyslop,et al.  Safeguarding Glasgow's stone built heritage skills and materials requirements : facade surveys and building stone analysis , 2006 .

[3]  Jennifer Leigh Murgatroyd Ancient mortar production in Ostia, Italy : builders and their choices , 2016 .

[4]  Thomas Yarrow,et al.  Science, value and material decay in the conservation of historic environments , 2016 .

[5]  Dario Ambrosini,et al.  Preventive thermographic diagnosis of historical buildings for consolidation , 2012 .

[6]  A. Magnani,et al.  Thermal and Petrographic Characterization of Herculaneum Wall Plasters , 2017 .

[7]  Mónika Hajpál,et al.  Changes in Sandstones of Historical Monuments Exposed to Fire or High Temperature , 2002 .

[8]  T. Schmid,et al.  Determination and imaging of binder remnants and aggregates in historic cement stone by Raman microscopy , 2013 .

[9]  John Hughes Heritage tea-breaks: petrographic characterisation of old masonry materials from Serbia and Slovenia , 2013 .

[10]  V. Cnudde,et al.  Salt weathering of sandstone during drying : effect of primary and secondary crystallisation , 2016 .

[11]  I. Simpson,et al.  Shieling Areas: Historical Grazing Pressures and Landscape Responses in Northern Iceland , 2012 .

[12]  S. Bracci,et al.  The Greek and Asiatic marbles of the Florentine Niobids , 2016 .

[13]  Federico Lenzerini,et al.  The Destruction of the Buddhas of Bamiyan and International Law , 2003 .

[14]  C. Kennedy The Role of Heritage Science in Conservation Philosophy and Practice , 2015 .

[15]  Johannes Weber,et al.  Nineteenth Century “Novel” Building Materials: Examples of Various Historic Mortars Under the Microscope , 2012 .

[16]  Gilles Mertens,et al.  Quantitative composition of ancient mortars from the Notre Dame Cathedral in Tournai (Belgium) , 2009 .

[17]  Anja Diekamp,et al.  Lime Mortar with Natural Hydraulic Components: Characterisation of Reaction Rims with FTIR Imaging in ATR-Mode , 2012 .

[18]  S. Kazarian,et al.  Revealing the Nature and Distribution of Metal Carboxylates in Jackson Pollock's Alchemy (1947) by Micro-Attenuated Total Reflection FT-IR Spectroscopic Imaging. , 2017, Analytical chemistry.

[19]  Silvana Fais,et al.  Integrated ultrasonic, laser scanning and petrographical characterisation of carbonate building materials on an architectural structure of a historic building , 2017, Bulletin of Engineering Geology and the Environment.

[20]  Narayan Khandekar,et al.  Preparation of cross-sections from easel paintings , 2003 .

[21]  Jeremy P. Ingham,et al.  Geomaterials Under the Microscope , 2010 .

[22]  Lucia Toniolo,et al.  Setup of a sustainable indoor cleaning methodology for the sculpted stone surfaces of the Duomo of Milan , 2014, Heritage Science.

[23]  Wolfgang Schwarz,et al.  The Hydration of Modern Roman Cements Used for Current Architectural Conservation , 2012 .

[24]  John Hughes,et al.  Science and Art: A Future for Stone: Proceedings of the 13th International Congress on the Deterioration and Conservation of Stone, Volume 2 , 2016 .

[25]  Chandra L. Reedy Thin-section Petrography in Studies of Cultural Materials , 1994 .

[26]  Ioanna Papayianni,et al.  Investigative methods for the characterisation of historic mortars—Part 1: Mineralogical characterisation , 2005 .

[28]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[29]  J. Lindqvist,et al.  Historic Mortars with Burned Alum Shale as an Artificial Pozzolan , 2012 .

[30]  H. Viles,et al.  COMPARABILITY OF NON-DESTRUCTIVE MOISTURE MEASUREMENT TECHNIQUES ON MASONRY DURING SIMULATED WETTING , 2019 .

[31]  Salvador Muñoz Viñas Contemporary theory of conservation , 2002 .

[32]  Jan Elsen,et al.  Microscopy of historic mortars—a review , 2006 .

[33]  Ran Wang,et al.  Tridimensional Reconstruction Applied to Cultural Heritage with the Use of Camera-Equipped UAV and Terrestrial Laser Scanner , 2014, Remote. Sens..

[34]  Rosário Veiga,et al.  Understanding the transport of nanolime consolidants within Maastricht limestone , 2016 .

[35]  S. Caro,et al.  An investigation of Roman mortar technology through the petrographic analysis of archaeological material , 2008 .

[36]  R. J. Schaffer,et al.  The Weathering of Natural Building Stones , 2013 .

[37]  Marie D. Jackson,et al.  Unlocking the secrets of Al-tobermorite in Roman seawater concrete , 2013 .