Comparison of Classical and Fluctuation-Enhanced Gas Sensing with PdxWO3 Nanoparticle Films

Nanoparticle films of Pd xWO3, with x being 0.01 or 0.12, were made by dual-beam gas evaporation. The stochastic signal component (fluctuation-enhanced signal) originating from resistance fluctuations and the dc resistance (classical sensor signal) were measured during exposure to ethanol and hydrogen gas. For ethanol concentrations exceeding 50 ppm, changes in the resistance fluctuations gave 300 times larger detection sensitivity than changes in the dc resistance. © 2005 Elsevier B.V. All rights reserved.

[1]  T. Kleinpenning,et al.  1/f noise in thermo EMF of intrinsic and extrinsic semiconductors , 1974 .

[2]  Wu Xinghui,et al.  Electrical and gas-sensing properties of WO3 semiconductor material , 2001 .

[3]  F. Tang,et al.  Thermal stability of nanocrystalline gold prepared by gas deposition method , 1995 .

[4]  Yan Zhao,et al.  SnO2 gas sensor films deposited by pulsed laser ablation , 1999 .

[5]  Laszlo B. Kish,et al.  Gas Sensing Properties of Nanocrystalline WO3 Films Made by Advanced Reactive Gas Deposition , 2004 .

[6]  D. Briand,et al.  Pd-doped SnO2 thin films deposited by assisted ultrasonic spraying CVD for gas sensing: selectivity and effect of annealing , 1998 .

[7]  H. Maeta,et al.  Thermal Stability of Nanocrystalline Gold Studied by X-ray Diffraction Method , 1998 .

[8]  S. Rembeza,et al.  Electrical Resistivity and Gas Response Mechanisms of Nanocrystalline SnO2 Films in a Wide Temperature Range , 2000 .

[9]  Laszlo B. Kish,et al.  In situ electrical transport during isothermal annealing of nanocrystalline gold films , 2002 .

[10]  S. Santucci,et al.  Visualisation of the preferential adsorption sites of oxygen onto WO3 nano-particles , 2001 .

[11]  M. Weissman 1/f noise and other slow, nonexponential kinetics in condensed matter. , 1988 .

[12]  Laszlo B. Kish,et al.  Surface diffusion enhanced chemical sensing by surface acoustic waves , 2003 .

[13]  Laszlo B. Kish,et al.  Extracting information from noise spectra of chemical sensors: single sensor electronic noses and tongues , 2000 .

[14]  M. Madou,et al.  Chemical Sensing With Solid State Devices , 1989 .

[15]  S. Tsang,et al.  Ag doped WO3-based powder sensor for the detection of NO gas in air , 2003 .

[16]  J. Bendat,et al.  Random Data: Analysis and Measurement Procedures , 1987 .

[17]  S. Vassilev,et al.  Lanthanum doped SnO2 and ZnO thin films sensitive to ethanol and humidity , 2000 .

[18]  Norio Miura,et al.  Study of WO3-based sensing materials for NH3 and NO detection , 2000 .

[19]  L. B. Kish,et al.  High-Order Statistics for Fluctuation-Enhanced Gas Sensing , 2004 .

[20]  Francesco Tortorella,et al.  Gas recognition by activated WO3 thin-film sensors array , 2001 .