Formulation, rheology and thermal aging of polymer greases—Part II: Influence of the co-thickener content

Abstract In the first part of this work, the effect of the thickener content on the rheological behavior of polymer greases was investigated. The aim of this part II is to show the correlation between these greases’ rheology and its formulation, regarding the co-thickener content. Even though the greases were formulated with the same base oil, the co-thickener content and nature clearly influence the bleed-oil viscosity and the greases’ mechanical stability, allowing us to control the oil bleeding rate. Therefore, analyzing the rheology of these polymer greases, this study aims to bring some light on the base oil vs bleed-oil viscosity approach at high shear rate and the effect on the properties of the active lubricant in the EHD contact.

[1]  Jorge H.O. Seabra,et al.  Friction torque in grease lubricated thrust ball bearings , 2011 .

[2]  P. D. Fleischauer,et al.  Chemical Analysis of Hydrocarbon Grease from Spin Bearing Tests , 1983 .

[3]  C. Gallegos,et al.  Relationship among microstructure, rheology and processing of a lithium lubricating grease , 2005 .

[4]  P. Lugt,et al.  Oil-Bleeding Model for Lubricating Grease Based on Viscous Flow Through a Porous Microstructure , 2010 .

[5]  P. Jiang,et al.  Thermal Degradation Behavior of Poly(propylene) with a Novel Silicon‐Containing Intumescent Flame Retardant , 2005 .

[6]  P. Vergne,et al.  Rheological Behavior of Greases: Part I—Effects of Composition and Structure , 2000 .

[7]  Hugh Spikes,et al.  The behaviour of greases in elastohydrodynamic contacts , 1992 .

[8]  Rheological properties of greases in ehd contacts , 1984 .

[9]  Pieter Martin Lugt,et al.  Grease Lubrication in Rolling Bearings , 2013 .

[10]  Marcus Björling,et al.  Film thickness in a ball-on-disc contact lubricated with greases, bleed oils and base oils , 2012 .

[11]  Farrukh Qureshi,et al.  The high pressure rheology of polymer-oil solutions , 2003 .

[12]  H. Spikes,et al.  Thermal Degradation of Greases and the Effect on Lubrication Performance , 1998 .

[13]  P. Cann Grease degradation in a bearing simulation device , 2006 .

[14]  D. Mazuyer,et al.  Effects of Grease Composition and Structure on Film Thickness in Rolling Contact , 2003 .

[15]  Jorge H.O. Seabra,et al.  Friction and wear in thrust ball bearings lubricated with biodegradable greases , 2011 .

[16]  P. Lugt,et al.  Prediction of film thickness decay in starved elasto-hydrodynamically lubricated contacts using a thin layer flow model , 2009 .

[17]  E. Klaus,et al.  Oxidative Degradation of Phosphate Esters , 1981 .

[18]  T. Tadros,et al.  Steady flow and viscoelastic properties of lubricating grease containing various thickener concentrations. , 2004, Journal of colloid and interface science.

[19]  J. E. Martín-Alfonso,et al.  Evaluation of different polyolefins as rheology modifier additives in lubricating grease formulations , 2011 .

[20]  G. Fredrickson The theory of polymer dynamics , 1996 .

[21]  P. Cann Grease Degradation in R 0 F Bearing Tests , 2012 .

[22]  P. M. Cann,et al.  Grease Degradation in Rolling Element Bearings , 2001 .

[23]  John P. Coates,et al.  Infrared Spectroscopic Methods for the Study of Lubricant Oxidation Products , 1986 .

[24]  John Dixon,et al.  The Utilization of FT-IR for Army Oil Condition Monitoring , 1998 .

[25]  D. Dong,et al.  A theory of elastohydrodynamic grease-lubricated line contact based on a refined rheological model , 1988 .

[26]  P. Lugt,et al.  Grease Degradation in R0F Bearing Tests , 2007 .