论文信息 - Nano-Golden Order

Nano-Golden Order

An experimental tour de force reveals the crystal structure of a gold-thiolate nanocrystal compound and the surprising nature of the gold-sulfur bonding.

R. Whetten | Ryan C. Price | R. Price

[1] Pablo D. Jadzinsky,et al. Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution , 2007, Science.

[2] L. F. Dahl,et al. Nanosized (μ12-Pt)Pd164-xPtx(CO)72(PPh3)20 (x ≈ 7) Containing Pt-Centered Four-Shell 165-Atom Pd−Pt Core with Unprecedented Intershell Bridging Carbonyl Ligands: Comparative Analysis of Icosahedral Shell-Growth Patterns with Geometrically Related Pd145(CO)x(PEt3)30 (x ≈ 60) Containing Capped Three-S , 2007 .

[3] Simon J L Billinge,et al. The Problem with Determining Atomic Structure at the Nanoscale , 2007, Science.

[4] Hannu Häkkinen,et al. Divide and protect: capping gold nanoclusters with molecular gold-thiolate rings. , 2006, The journal of physical chemistry. B.

[5] R. Whetten,et al. All-aromatic, nanometer-scale, gold-cluster thiolate complexes. , 2005, Journal of the American Chemical Society.

[6] Pekka Pyykkö,et al. Theoretical chemistry of gold. , 2004, Angewandte Chemie.

[7] R. Murray,et al. Monolayer-protected cluster molecules. , 2000, Accounts of chemical research.

[8] J. Strähle,et al. Thiolatokomplexe des einwertigen Golds. Synthese und Struktur von [(2,4,6‐iPr3C6H2S)Au]6 und (NH4)[(2,4,6‐iPr3C6H2S)2Au] , 1991 .

[9] B. Bagley. Five-fold Pseudosymmetry , 1970, Nature.

[10] H. Schmidbauer. Gold : progress in chemistry, biochemistry, and technology , 1999 .