Forward osmosis: Novel desalination of produced water and fracturing flowback

Treatment and reuse of oil and gas (O&G) production wastewater in a cost-effective and environmentally sound manner is critical for sustainable industrial development and for meeting stringent regulations. High salinity, free and emulsified hydrocarbons, silts and clays released from producing formations, and process additives common in O&G drilling wastewater render many conventional treatment technologies ineffective. Forward osmosis (FO) has been established as a promising solution for treatment and desalination of complex industrial streams, and especially for O&G exploration and production wastewaters. FO has achieved up to 85% water recovery from O&G wastewaters and can concentrate feed streams to greater than 150,000 mg/L total dissolved solids. FO can be operated as a stand-alone technology with minimal pretreatment of the feed or can be coupled with other advanced processes such as reverse osmosis (RO). FO minimizes O&G wastewater disposal and can produce clean water for beneficial reuse. Recent developments in membrane fabrication, system configurations, and draw solutions are briefly reviewed. Expanded Summary

[1]  Tzahi Y. Cath,et al.  Selection of inorganic-based draw solutions for forward osmosis applications , 2010 .

[2]  S. Loeb,et al.  Effect of porous support fabric on osmosis through a Loeb-Sourirajan type asymmetric membrane , 1997 .

[3]  C. D. Lundin,et al.  Forward Osmosis-Reverse Osmosis Process Offers a Novel Hybrid Solution for Water Purification and Reuse , 2010 .

[4]  S. Riha,et al.  Toward strategic management of shale gas development: Regional, collective impacts on water resources , 2012 .

[5]  Dianne Rahm,et al.  Regulating hydraulic fracturing in shale gas plays: The case of Texas , 2011 .

[6]  K. S. Spiegler,et al.  Molecular (osmotic and electro-osmotic) backwash of cellulose acetate hyperfiltration membranes , 1981 .

[7]  Jack Gilron,et al.  Seawater desalination for agriculture by integrated forward and reverse osmosis: Improved product water quality for potentially less energy , 2012 .

[8]  Ann James,et al.  The potential of gas shale , 2010 .

[9]  Tzahi Y Cath,et al.  Effects of transmembrane hydraulic pressure on performance of forward osmosis membranes. , 2013, Environmental science & technology.

[10]  Aaron Dell Horn.  Breakthrough Mobile Water Treatment Converts 75% of Fracturing Flowback Fluid to Fresh Water and Lowers CO2 Emissions , 2009 .

[11]  Menachem Elimelech,et al.  Superhydrophilic thin-film composite forward osmosis membranes for organic fouling control: fouling behavior and antifouling mechanisms. , 2012, Environmental science & technology.

[12]  Ji-Hun Seo,et al.  Novel lower critical solution temperature phase transition materials effectively control osmosis by mild temperature changes. , 2012, Chemical communications.

[13]  Gary L. Amy,et al.  Well-constructed cellulose acetate membranes for forward osmosis: Minimized internal concentration polarization with an ultra-thin selective layer , 2010 .

[14]  Jincai Su,et al.  Enhanced double-skinned FO membranes with inner dense layer for wastewater treatment and macromolecule recycle using Sucrose as draw solute , 2012 .

[15]  Mark L. Stone,et al.  An initial study of hexavalent phosphazene salts as draw solutes in forward osmosis , 2013 .

[16]  Kai Yu Wang,et al.  Double-Skinned Forward Osmosis Membranes for Reducing Internal Concentration Polarization within the Porous Sublayer , 2010 .

[17]  Boqiang Lin,et al.  Forecasting natural gas supply in China: Production peak and import trends , 2012 .

[18]  Menachem Elimelech,et al.  Forward with osmosis: emerging applications for greater sustainability. , 2011, Environmental science & technology.

[19]  Xiaoxiao Song,et al.  Nano Gives the Answer: Breaking the Bottleneck of Internal Concentration Polarization with a Nanofiber Composite Forward Osmosis Membrane for a High Water Production Rate , 2011, Advanced materials.

[20]  In‐Chul Kim,et al.  Preparation of cellulose triacetate/cellulose acetate (CTA/CA)-based membranes for forward osmosis , 2013 .

[21]  Kai Yu Wang,et al.  Thin-Film Composite Membranes and Formation Mechanism of Thin-Film Layers on Hydrophilic Cellulose Acetate Propionate Substrates for Forward Osmosis Processes , 2012 .

[22]  A. Fakhru’l-Razi,et al.  Review of technologies for oil and gas produced water treatment. , 2009, Journal of hazardous materials.

[23]  Dan Li,et al.  Stimuli-responsive polymer hydrogels as a new class of draw agent for forward osmosis desalination. , 2011, Chemical communications.

[24]  Menachem Elimelech,et al.  Coupled reverse draw solute permeation and water flux in forward osmosis with neutral draw solutes , 2012 .

[25]  Iris Sutzkover-Gutman,et al.  Feed water pretreatment for desalination plants , 2010 .

[26]  Zhao Xin-gang,et al.  Focus on the development of shale gas in China—Based on SWOT analysis , 2013 .

[27]  Menachem Elimelech,et al.  Energy requirements of ammonia-carbon dioxide forward osmosis desalination , 2007 .

[28]  Nathan R. Hutchings,et al.  Making High Quality Frac Water out of Oilfield Waste , 2010 .

[29]  Tai-Shung Chung,et al.  Forward osmosis processes: Yesterday, today and tomorrow , 2012 .

[30]  Raphael Semiat,et al.  Backwash of RO spiral wound membranes , 2005 .

[31]  Rong Wang,et al.  High performance flat sheet forward osmosis membrane with an NF-like selective layer on a woven fabric embedded substrate , 2012 .

[32]  Andrea Achilli,et al.  Organic ionic salt draw solutions for osmotic membrane bioreactors. , 2012, Bioresource technology.

[33]  Amy E. Childress,et al.  Forward osmosis: Principles, applications, and recent developments , 2006 .

[34]  Giulio C. Sarti,et al.  Water, salt, and ethanol diffusion through membranes for water recovery by forward (direct) osmosis processes , 2008 .

[35]  Qi-feng Liu,et al.  Pre-treatment strategies for seawater desalination by reverse osmosis system. , 2009 .

[36]  Mark L. Stone,et al.  SWITCHABLE POLARITY SOLVENTS AS DRAW SOLUTES FOR FORWARD OSMOSIS , 2013 .

[37]  C. D. Moody,et al.  Drinking water from sea water by forward osmosis , 1976 .

[38]  Roberto Aguilera,et al.  Technological progress and the availability of European oil and gas resources , 2012 .

[39]  Sui Zhang,et al.  Thin film composite forward osmosis membranes based on polydopamine modified polysulfone substrates with enhancements in both water flux and salt rejection , 2012 .

[40]  Raphael Semiat,et al.  Osmotic backwash process in RO membranes , 2006 .

[41]  Liwei Huang,et al.  FORWARD OSMOSIS , 2013 .

[42]  Kai Yu Wang,et al.  Developing thin‐film‐composite forward osmosis membranes on the PES/SPSf substrate through interfacial polymerization , 2012 .

[43]  Linda Zou,et al.  Recent developments in forward osmosis : opportunities and challenges. , 2012 .

[44]  Xuejun Liu,et al.  Emerging shale gas revolution in China. , 2012, Environmental science & technology.

[45]  Mohsen Jahanshahi,et al.  Synthesis of novel thin film nanocomposite (TFN) forward osmosis membranes using functionalized multi-walled carbon nanotubes , 2013 .

[46]  Tao He,et al.  Cellulose triacetate forward osmosis membranes: preparation and characterization , 2013 .

[47]  Rong Wang,et al.  Composite forward osmosis hollow fiber membranes: Integration of RO- and NF-like selective layers to enhance membrane properties of anti-scaling and anti-internal concentration polarization , 2012 .

[48]  Yang Liu,et al.  The effects of pretreatment on nanofiltration and reverse osmosis membrane filtration for desalination of oil sands process-affected water , 2011 .

[49]  Ming Ming Ling,et al.  Desalination process using super hydrophilic nanoparticles via forward osmosis integrated with ultrafiltration regeneration , 2011 .

[50]  Gary L. Amy,et al.  Hydrophilic Superparamagnetic Nanoparticles: Synthesis, Characterization, and Performance in Forward Osmosis Processes , 2011 .

[51]  Robert L McGinnis,et al.  Desalination by ammonia–carbon dioxide forward osmosis: Influence of draw and feed solution concentrations on process performance , 2006 .

[52]  Ruud Weijermars,et al.  Economic appraisal of shale gas plays in Continental Europe , 2013 .

[53]  Jincai Su,et al.  Exploration of polyelectrolytes as draw solutes in forward osmosis processes. , 2012, Water research.

[54]  J. McCutcheon,et al.  Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis , 2006 .

[55]  Kai Yu Wang,et al.  Highly Water-Soluble Magnetic Nanoparticles as Novel Draw Solutes in Forward Osmosis for Water Reuse , 2010 .

[56]  Bart Van der Bruggen,et al.  Distillation vs. membrane filtration: overview of process evolutions in seawater desalination , 2002 .

[57]  Richard E. Kravath,et al.  Desalination of sea water by direct osmosis , 1975 .

[58]  Raphael Semiat,et al.  Osmotic backwash mechanism of reverse osmosis membranes , 2008 .

[59]  Necati Kayaalp,et al.  Desalination of produced water from oil production fields by membrane processes , 2008 .

[60]  Menachem Elimelech,et al.  Desalination and reuse of high-salinity shale gas produced water: drivers, technologies, and future directions. , 2013, Environmental science & technology.

[61]  Menachem Elimelech,et al.  A novel ammonia-carbon dioxide forward (direct) osmosis desalination process , 2005 .

[62]  Tai‐Shung Chung,et al.  Draw solutions for forward osmosis processes: Developments, challenges, and prospects for the future , 2013 .

[63]  Tom Depuydt,et al.  Forward and pressure retarded osmosis: potential solutions for global challenges in energy and water supply. , 2013, Chemical Society reviews.

[64]  Kerri L. Hickenbottom,et al.  Forward osmosis treatment of drilling mud and fracturing wastewater from oil and gas operations , 2013 .

[65]  Samer Adham,et al.  Dewatering Reverse Osmosis Concentrate from Water Reuse Applications Using Forward Osmosis WateReuse Foundation , 2007 .

[66]  Xue Li,et al.  Emerging forward osmosis (FO) technologies and challenges ahead for clean water and clean energy applications , 2012 .

[67]  Peter Czermak,et al.  Characterization and application of different ceramic membranes for the oil-field produced water treatment , 2009 .

[68]  Kai Yu Wang,et al.  Study of draw solutes using 2-methylimidazole-based compounds in forward osmosis , 2010 .

[69]  Jörg E. Drewes,et al.  Beneficial use of co-produced water through membrane treatment: technical-economic assessment , 2008 .

[70]  Sherub Phuntsho,et al.  A novel low energy fertilizer driven forward osmosis desalination for direct fertigation: Evaluating , 2011 .

[71]  Nathan T. Hancock,et al.  Pilot demonstration of the NH3/CO2 forward osmosis desalination process on high salinity brines , 2013 .