Via-Shape-Control for Copper Dual-Damascene Interconnects With Low-k Organic Film

Copper dual-damascene (DD) interconnects are fabricated with low-k organic film (SiLKtrade) without any etch-stop layers by use of dual hard mask (dHM) process combined with sidewall-hardening etching step. It is a key point to reduce shoulder loss during trench etching at connecting regions of vias and trenches, so that hardening of the via-sidewall by fluorocarbon plasma during via etching is implemented. Careful designs of dual hard mask structures and their patterning sequence are carried out for the process without etch-stop layer under the trench. The two-layered interconnect with low-k structure has achieved low via-resistance of 0.65 Omega at 0.28 mumOslash with keeping large tolerance of misalignment up to 0.1 mum.

[1]  H. Bender,et al.  Effects of oxygen and fluorine on the dry etch characteristics of organic low-k dielectrics , 1999 .

[2]  Technical digest , 2007, 2007 IEEE 20th International Conference on Micro Electro Mechanical Systems (MEMS).

[3]  Oxygen ion beam etching for pattern transfer , 1984 .

[4]  Y. Hayashi,et al.  Layered Ta-nitrides (LTN) barrier film by power swing sputtering (PSS) technique for MOCVD-Cu damascene interconnects , 1999, International Electron Devices Meeting 1999. Technical Digest (Cat. No.99CH36318).

[5]  Marceline Bonvalot,et al.  High density plasma etching of low k dielectric polymers in oxygen-based chemistries , 2001 .

[6]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[7]  Y. Hayashi,et al.  A new pad-scanning, local-CMP (PASCAL-CMP) technique for reliable Cu-damascene interconnect formation , 1999, Proceedings of the IEEE 1999 International Interconnect Technology Conference (Cat. No.99EX247).

[8]  A. Krishnamoorthy,et al.  SiLKTM etch optimization and electrical characterization for 0.13 mum interconnects , 2005, Microelectron. Reliab..

[9]  H. Matsunaga,et al.  Novel Method of Estimating Dielectric Constant for Low-k Materials , 2002 .

[10]  Masaru Hori,et al.  Behavior of atomic radicals and their effects on organic low dielectric constant film etching in high density N2/H2 and N2/NH3 plasmas , 2002 .

[11]  Gottlieb S. Oehrlein,et al.  Study of sidewall passivation and microscopic silicon roughness phenomena in chlorine‐based reactive ion etching of silicon trenches , 1990 .

[12]  M. Hori,et al.  Etching organic low dielectric film in ultrahigh frequency plasma using N2/H2 and N2/NH3 gases , 2003 .

[13]  Realistic Etch Yield of Fluorocarbon Ions in SiO2 Etch Process , 1998 .