ATMOSPHERIC WATER VAPOR: A NEMESIS FOR MILLIMETER WAVE PROPAGATION

Abstract : Millimeter waves offer an attractive way of solving unique system problems because of their ability to penetrate clouds, smog, dust, or fog. This makes them a logical choice over electrooptical devices for adverse weather applications. Spectral lines of oxygen and water vapor ultimately limit the atmospheric transparency; hence, most applications operate between the absorption lines in four window regions (that is, 24 to 48, 72 to 110, 128 to 160, and 200 to 260 GHz). Observations have established the existence of excess water vapor absorption (EWA), which is most evident in these windows. Excess implies that the effect is not related to the known spectral properties of the water molecule. EWA is found to increase in nontrivial manner with humidity and the discrepancies can be as large as a factor of 10. Several groups (most notably at the Appleton Laboratory, UK), have gathered evidence of EWA from laboratory and field observations and brought forward hypotheses to account for the data. Qualitative explanations are based on the assumption that water molecules in moist air form larger molecules with a dimer being the first step in a series of stable species. Hydrogen bonding, ion attraction and attachment of the polar H2O to foreign particles (aerosol growth) are the ordering forces considered in the clustering process. An assessment of the current EWA picture will be given and avenues of research attacks are discussed to solve the enigma in the quantitative description of the interaction between millimeter waves and moist air.

[1]  W. Fogarty Total atmospheric absorption at 22.2 GHz , 1975 .

[2]  W. G. Tam,et al.  The effects of relative humidity on the infrared aerosol extinction in the 3–5 and 8–15 μm spectral regions , 1979 .

[3]  P. Richards,et al.  A search for spectral features in the submillimeter background radiation. , 1971 .

[4]  A. Straiton,et al.  Attenuation of the Earth's atmosphere between the frequencies of 100 and 140 gigacycles per second , 1964 .

[5]  J. R. Perry,et al.  Measurements of index of refraction and signal loss due to an ice fog medium at 97 GHz using a Fabry , 1974 .

[6]  Hans J. Liebe,et al.  Accurate Foreign‐Gas‐Broadening Parameters of the 22‐GHz H2O Line from Refraction Spectroscopy , 1969 .

[7]  Y. Yamaguchi,et al.  Water cluster interpretation of IR absorption spectra in the 8-14-microm wavelength region. , 1979, Applied optics.

[8]  R. Nordstrom,et al.  Accuracy of the AFCRL atmospheric absorption line parameters compilation in the 10-microm atmospheric window. , 1976, Applied optics.

[9]  R. J. Knight,et al.  Millimetre wave spectroscopy of water vapour using harmonics from IMPATT diode oscillators , 1976 .

[10]  K. Bignell,et al.  The water‐vapour infra‐red continuum , 1970 .

[11]  J. T. Hall,et al.  Attenuation of millimeter wavelength radiation by gaseous water. , 1967, Applied Optics.

[12]  Larry A. Curtiss,et al.  Studies of molecular association in H2O and D2O vapors by measurement of thermal conductivity , 1979 .

[13]  K. O. White,et al.  Pressure dependence of the water vapor continuum absorption in the 3.5-4.0-microm region. , 1979, Applied optics.

[14]  H. Gerber A Saturation Hygrometer for the Measurement of Relative Humidity Between 95 and 105 , 1980 .

[15]  A. M. Cook,et al.  Calculations of Antenna Temperature, Horizontal Path Attenuation, and Zenith Attenuation Due to Water Vapor in the Frequency Band 150-700 GHz , 1977 .

[16]  E. I. Robson,et al.  Measurements of atmospheric attenuation by water vapour , 1979 .

[17]  G. Birnbaum Millimeter Wavelength Dispersion of Water Vapor , 1953 .

[18]  H. Liebe,et al.  Calculation of clear air EHF refractivity , 1978 .

[19]  J. R. Rusk Line‐Breadth Study of the 1.64‐mm Absorption in Water Vapor , 1965 .

[20]  Sidney Perkowitz,et al.  Far infrared optical constants of liquid water measured with an optically pumped laser , 1979 .

[21]  H. Gebbie,et al.  Atmospheric absorption between 4 and 30 cm−1 measured above Mauna Kea , 1977, Nature.

[22]  R. Plambeck Measurements of atmospheric attenuation near 225 GHz: Correlation with surface water vapor density , 1978 .

[23]  R E Roberts,et al.  Infrared continuum absorption by atmospheric water vapor in the 8-12-microm window. , 1976, Applied optics.

[24]  K. Froome The Refractive Indices of Water Vapour, Air, Oxygen, Nitrogen and Argon at 72 kMc/s , 1955 .

[25]  G. Wrixon,et al.  Measurements of Earth-Space Attenuation at 230 GHz , 1978 .

[26]  J. C. Peterson,et al.  Water vapor-nitrogen absorption at CO(2) laser frequencies. , 1979, Applied optics.

[27]  H. Liebe Calculated tropospheric dispersion and absorption due to the 22-GHz water vapor line , 1969 .

[28]  Darrell E. Burch,et al.  Absorption of Infrared Radiant Energy by CO 2 and H 2 O. III. Absorption by H 2 O between 0.5 and 36 cm −1 (278 μ−2 cm)* , 1968 .

[29]  G. E. Becker,et al.  Water Vapor Absorption of Electromagnetic Radiation in the Centimeter Wave-Length Range , 1946 .

[30]  B Nilsson,et al.  Meteorological influence on aerosol extinction in the 0.2-40-microm wavelength range. , 1979, Applied optics.

[31]  E. Altshuler,et al.  Atmospheric attenuation statistics at 15 and 35 GHz for very low elevation angles , 1978 .

[32]  H. R. Carlon,et al.  Mass spectrometry of ion-induced water clusters: an explanation of the infrared continuum absorption. , 1980, Applied optics.

[33]  D. Hogg,et al.  Microwave measurements of the absolute values of absorption by water vapour in the atmosphere , 1979, Nature.

[34]  R. J. Emery,et al.  Atmospheric propagation in the frequency range 100-1000 GHz , 1979 .

[35]  L. Frenkel,et al.  The microwave absorption by H 2 O vapor and its mixtures with other gases between 100 and 300 Gc/s , 1966 .

[36]  A. C. Gordon-Smith,et al.  Atmospheric emission measurements at 85 to 118 GHz , 1975 .

[37]  H. Gebbie,et al.  Measurements of anomalous atmospheric absorption in the wavenumber range 4 cm−1–15 cm−1 , 1975 .

[38]  G. Yue A quick method for estimating the equilibrium size and composition of aqueous sulfuric acid droplets , 1979 .

[39]  H. R. Carlon Do clusters contribute to the infrared absorption spectrum of water vapor , 1979 .

[40]  K. O. White,et al.  Water vapor continuum absorption in the 3.5-4.0-microm region. , 1978, Applied optics.

[41]  J. Hodges Aerosol extinction contribution to atmospheric attenuation in infrared wavelengths. , 1972, Applied optics.

[42]  G. T. Wrixon Measurements of atmospheric attenuation on an earth-space path at 90 GHz using a sun tracker , 1971 .

[43]  P. Ray,et al.  Broadband complex refractive indices of ice and water. , 1972, Applied optics.

[44]  P. Goldsmith,et al.  Measurement of Atmospheric Attenuation at 1.3 and 0.87 mm with an Harmonic Mixing Radiometer , 1974 .

[45]  E. I. Robson,et al.  Absolute measurements of atmospheric emission and absorption in the range 100–1000 GHz , 1978 .

[46]  S. Chang,et al.  Performance characteristics of a 300-GHz radiometer and some atmospheric attenuation measurements , 1968 .

[47]  G. Montgomery Temperature dependence of infrared absorption by the water vapor continuum near 1200 cm(-1). , 1978, Applied optics.

[48]  R. J. Knight,et al.  Absorption by water vapour at 7.1 cm−1 and its temperature dependence , 1978, Nature.

[49]  A. Newell,et al.  Absolute Determination of Refractive Indices of Gases at 47.7 Gigahertz , 1965 .

[50]  P. Ade,et al.  Absolute measurements of the atmospheric transparency at short millimetre wavelengths , 1979 .

[51]  M. N. Afsar,et al.  Submillimetre wave measurements of optical constants of water at various temperatures , 1978 .

[52]  M. N. Afsar,et al.  Measurements of the optical constants of liquid H 2 O and D 2 O between 6 and 450 cm −1 , 1977 .

[53]  R. A. Bohlander,et al.  Spectroscopy of water vapour , 1979 .

[54]  D. Hogg Effective Antenna Temperatures Due to Oxygen and Water Vapor in the Atmosphere , 1959 .

[55]  Van Vleck,et al.  The Absorption of Microwaves by Uncondensed Water Vapor , 1947 .

[56]  A. C. Gordon-Smith,et al.  Anomalous Absorption in the Atmosphere for 2.7 mm Radiation , 1973, Nature.

[57]  D. R. Cutten,et al.  Extension of water vapour continuum absorption to the 4.5 5.0 μm region , 1979 .

[58]  A. Straiton,et al.  Pressure Broadening of the 1.63‐mm Water‐Vapor Absorption Line , 1969 .

[59]  David C. Hogg,et al.  Measurement of atmospheric attenuation at millimeter wavelengths , 1956 .

[60]  John S. Muenter,et al.  THE STRUCTURE OF WATER DIMER FROM MOLECULAR BEAM ELECTRIC RESONANCE SPECTROSCOPY: PARTIALLY DEUTERATED DIMERS , 1977 .

[61]  P. Chylek,et al.  Verification of a Linear Relation between IR Extinction, Absorption and Liquid Water Content of Fogs , 1979 .

[62]  J. R. Birch,et al.  The refractive index of water vapour: A comparison of measurement and theory , 1978 .