Perspective of the preparation of agrichars using fossil hydrocarbon coke

The increasing demand of fossil fuels and decreasing light oil proven reserves lead to a future scenario of abundant coke production from the refinement of non-conventional fossil hydrocarbons. This paper highlights the possibility of using coke as an agrichar for preparing fertile soils resembling Amazonian terra preta. It is suggested that this alternative may contribute to both the capture of greenhouse gas by afforestation and the increase of rainfall by the albedo effect. It is proposed that the ideal agrichar must function as a store of nutrients in the form of graphene substituted NPK groups at the micropore molecular structure, providing habitat for plant friendly microorganism inside its macropores. The possibility of a sink effect connecting nutrient storage with microorganisms has also been proposed. A preliminary discussion on the possible coking procedures to improve the resulting agrichar efficacy, three options for large scale desert greening using agrichar as well as recommendations for further research are presented.

[1]  K. Laval,et al.  General circulation model experiments with surface albedo changes , 1986 .

[2]  A. Albornoz,et al.  Adding a micropore framework to a parent activated carbon by carbon deposition from methane or ethylene , 2003 .

[3]  John Gaunt,et al.  Bio-char Sequestration in Terrestrial Ecosystems – A Review , 2006 .

[4]  Anastasia Zabaniotou,et al.  Minimizing activated carbons production cost , 2009 .

[5]  H. Stoeckli Microporous carbons and their characterization: The present state of the art , 1990 .

[6]  Johannes Lehmann,et al.  A handful of carbon , 2007, Nature.

[7]  A. Plantinga,et al.  A Method for Estimating the Cost of CO2 Mitigation through Afforestation , 2001 .

[8]  Arnulf Grubler Doing More with Less: Improving the Environment through Green Engineering , 2006 .

[9]  M. Romero,et al.  Hydrogen production by steam-gasification of petroleum coke using concentrated solar power—II Reactor design, testing, and modeling , 2006 .

[10]  J. Laine,et al.  Sink Effect in Activated Carbon-Supported Hydrodesulfurization Catalysts , 1997 .

[11]  D. Fuller,et al.  Land Cover, Rainfall and Land-Surface Albedo in West Africa , 2002 .

[12]  L. Berkofsky Weather modification in arid regions: The Israeli experience , 1986 .

[13]  Aloys Hüttermann,et al.  Sustainable global energy supply based on lignocellulosic biomass from afforestation of degraded areas , 2009, Naturwissenschaften.

[14]  A. Albornoz,et al.  Evidence for the formation of slit mesopores in activated carbon , 1999 .

[15]  J. Skjemstad,et al.  Black Carbon Increases Cation Exchange Capacity in Soils , 2006 .

[16]  J. Lehmann,et al.  Stability of black carbon in soils across a climatic gradient , 2008 .

[17]  S. Riha,et al.  Maize yield and nutrition during 4 years after biochar application to a Colombian savanna oxisol , 2010, Plant and Soil.

[18]  Á. Calafat,et al.  Preparation and characterization of activated carbons from coconut shell impregnated with phosphoric acid , 1989 .

[19]  Mingbo Wu,et al.  Preparation of porous carbons from petroleum coke by different activation methods , 2005 .

[20]  C. Mann The Real Dirt on Rainforest Fertility , 2002, Science.

[21]  Georg Guggenberger,et al.  The 'Terra Preta' phenomenon: a model for sustainable agriculture in the humid tropics , 2001, Naturwissenschaften.

[22]  Ania C. Ulrich,et al.  Preparation and characterization of activated carbon from oil sands coke , 2012 .

[23]  Lawrence L. Kazmerski,et al.  Solar and wind opportunities for water desalination in the Arab regions , 2009 .

[24]  Bruce A. McCarl,et al.  Competitiveness of terrestrial greenhouse gas offsets: are they a bridge to the future? , 2007 .

[25]  Á. Calafat,et al.  Factors affecting the preparation of activated carbons from coconut shell catalized by potassium , 1991 .

[26]  J. Laine,et al.  Effect of the preparation method on the pore size distribution of activated carbon from coconut shell , 1992 .

[27]  A. Albornoz,et al.  Porosities and pore sizes in coralline calcium carbonate , 2008 .

[28]  P. Fedorak,et al.  Oil sands cokes affect microbial activities , 2005 .

[29]  A. Oberlin,et al.  Tem studies of coal tars: Crude tar and its insoluble fractions , 1990 .

[30]  Emma Marris,et al.  Putting the carbon back: Black is the new green , 2006, Nature.

[31]  J. Laine,et al.  PREPARATION OF ACTIVATED CARBON FROM COCONUT SHELL IN A SMALL SCALE COCURRENT FLOW ROTARY KILN , 1991 .

[32]  Franz Trieb,et al.  Concentrating Solar Power for Seawater Desalination , 2007 .

[33]  Lynnath E. Beckley,et al.  Physical and chemical signatures of a developing anticyclonic eddy in the Leeuwin Current, eastern Indian Ocean , 2008 .

[34]  H. Fritze,et al.  Charcoal as a habitat for microbes and its effect on the microbial community of the underlying humus , 2000 .