Imaging ferroelectric domains in multiferroics using a low‐energy electron microscope in the mirror operation mode

We report on low‐energy electron microscopy imaging of ferroelectric domains with submicron resolution. Periodic strips of ‘up’ and ‘down’‐polarized ferroelectric domains in bismuth ferrite – a room temperature multiferroic – serve as a model system to compare low‐energy electron microscopy with the established piezoresponse force microscopy. The results confirm the possibility of full‐field imaging of ferroelectric domains with short acquisition times by exploiting the sensitivity of ultraslow electrons to small variations of the electric potential near surfaces in the “mirror” operation mode.

[1]  S. Nepijko,et al.  Measurement of potential distribution function on object surface by using an electron microscope in the mirror operation mode , 2010, Journal of microscopy.

[2]  Shan X. Wang,et al.  Electric-field control of local ferromagnetism using a magnetoelectric multiferroic. , 2008, Nature materials.

[3]  T. Zhao,et al.  Electrical control of antiferromagnetic domains in multiferroic BiFeO3 films at room temperature , 2006, Nature materials.

[4]  Nicola A. Spaldin,et al.  The Renaissance of Magnetoelectric Multiferroics , 2005, Science.

[5]  M. Bibes,et al.  Influence of parasitic phases on the properties of BiFeO3 epitaxial thin films , 2005, cond-mat/0504631.

[6]  A. Gruverman,et al.  Polarization-dependent electron affinity of LiNbO3 surfaces , 2004 .

[7]  Sergei V. Kalinin,et al.  Imaging mechanism of piezoresponse force microscopy of ferroelectric surfaces , 2002 .

[8]  O. Bostanjoglo,et al.  Pulsed mirror electron microscope: A fast near-surface imaging probe , 2001 .

[9]  S. Nepijko,et al.  Peculiarities of imaging one‐ and two‐dimensional structures using an electron microscope in the mirror operation mode , 2001, Journal of microscopy.

[10]  Kevin C. Prince,et al.  SPELEEM: Combining LEEM and Spectroscopic Imaging , 1998 .

[11]  E. Bauer,et al.  Low energy electron microscopy , 1994 .

[12]  G. Rempfer,et al.  Emission microscopy and related techniques: resolution in photoelectron microscopy, low energy electron microscopy and mirror electron microscopy. , 1992, Ultramicroscopy.

[13]  K. N. Maffitt Interpretation of Electron‐Mirror Micrographs of Ferroelectric and Dielectric Surfaces , 1968 .

[14]  Ludwig A. Mayer On Electron Mirror Microscopy , 1955 .

[15]  R. L. Bihan,et al.  Measurement of surface potential between ferroelectric domains , 1976 .

[16]  F. English Electron‐Mirror‐Microscope Analysis of Surface Potentials on Ferroelectrics , 1968 .