Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts.

A series of bimetallic complexes have been synthesized that are supported by a 4-phosphino-substituted NHC ligand. The use of this stable ligand reduces the number of synthetic steps and allows for a wide range of metal combinations to be introduced into the complexes.

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