Superconductivity in compressed lithium at 20 K

Superconductivity at high temperatures is expected in elements with low atomic numbers, based in part on conventional BCS (Bardeen–Cooper–Schrieffer) theory. For example, it has been predicted that when hydrogen is compressed to its dense metallic phase (at pressures exceeding 400 GPa), it will become superconducting with a transition temperature above room temperature. Such pressures are difficult to produce in a laboratory setting, so the predictions are not easily confirmed. Under normal conditions lithium is the lightest metal of all the elements, and may become superconducting at lower pressures; a tentative observation of a superconducting transition in Li has been previously reported. Here we show that Li becomes superconducting at pressures greater than 30 GPa, with a pressure-dependent transition temperature (Tc) of 20 K at 48 GPa. This is the highest observed Tc of any element; it confirms the expectation that elements with low atomic numbers will have high transition temperatures, and suggests that metallic hydrogen will have a very high Tc. Our results confirm that the earlier tentative claim of superconductivity in Li was correct.

[1]  J. B. Neaton,et al.  Pairing in dense lithium , 1999, Nature.

[2]  Alfred Forchel,et al.  Temperature dependence of the exciton homogeneous linewidth in In 0.60 Ga 0.40 As/GaAs self-assembled quantum dots , 2002 .

[3]  N. Ashcroft,et al.  EFFECTIVE ELECTRON-ELECTRON INTERACTIONS AND THE THEORY OF SUPERCONDUCTIVITY , 1997 .

[4]  J. Cunningham,et al.  Pure dephasing induced by exciton-phonon interactions in narrow GaAs quantum wells , 1998 .

[5]  Charles Santori,et al.  Triggered single photons from a quantum dot , 2001, QELS 2001.

[6]  Axel Kuhn,et al.  Deterministic single-photon source for distributed quantum networking. , 2002, Physical review letters.

[7]  Rosa Weigand,et al.  Fine Structure of Biexciton Emission in Symmetric and Asymmetric CdSe/ZnSe Single Quantum Dots , 1999 .

[8]  N. Christensen,et al.  Predicted superconductive properties of lithium under pressure. , 2001, Physical review letters.

[9]  L. Marsal,et al.  Acoustic phonon broadening mechanism in single quantum dot emission , 2001 .

[10]  E. Knill,et al.  A scheme for efficient quantum computation with linear optics , 2001, Nature.

[11]  K. Syassen,et al.  Equation of state of lithium to 21 GPa , 1999 .

[12]  N. Ashcroft,et al.  High Temperature Superconductivity in Metallic Hydrogen:Electron-Electron Enhancements , 1997 .

[13]  Marvin L. Cohen,et al.  Pseudopotential calculation of the mass enhancement and superconducting transition temperature of simple metals , 1969 .

[14]  K. Syassen,et al.  New high-pressure phases of lithium , 2000, Nature.

[15]  Y. Yamamoto,et al.  Single-mode spontaneous emission from a single quantum dot in a three-dimensional microcavity. , 2001, Physical review letters.

[16]  B. V. Shanabrook,et al.  Homogeneous Linewidths in the Optical Spectrum of a Single Gallium Arsenide Quantum Dot , 1996, Science.

[17]  J. Schrieffer Theory of superconductivity , 1958 .

[18]  Hong,et al.  Measurement of subpicosecond time intervals between two photons by interference. , 1987, Physical review letters.

[19]  Shih,et al.  New type of Einstein-Podolsky-Rosen-Bohm experiment using pairs of light quanta produced by optical parametric down conversion. , 1988, Physical review letters.

[20]  Lin,et al.  High-pressure and low-temperature study of electrical resistance of lithium. , 1986, Physical review. B, Condensed matter.