A review of reverse osmosis membrane fouling and control strategies.

Reverse osmosis (RO) membrane technology is one of the most important technologies for water treatment. However, membrane fouling is an inevitable issue. Membrane fouling leads to higher operating pressure, flux decline, frequent chemical cleaning and shorter membrane life. This paper reviews membrane fouling types and fouling control strategies, with a focus on the latest developments. The fundamentals of fouling are discussed in detail, including biofouling, organic fouling, inorganic scaling and colloidal fouling. Furthermore, fouling mitigation technologies are also discussed comprehensively. Pretreatment is widely used in practice to reduce the burden for the following RO operation while real time monitoring of RO has the advantage and potential of providing support for effective and efficient cleaning. Surface modification could slow down membrane fouling by changing surface properties such as surface smoothness and hydrophilicity, while novel membrane materials and synthesis processes build a promising future for the next generation of RO membranes with big advancements in fouling resistance. Especially in this review paper, statistical analysis is conducted where appropriate to reveal the research interests in RO fouling and control.

[1]  F. Roddick,et al.  Pre-treatments for removing colour from secondary effluent: Effectiveness and influence on membrane fouling in subsequent microfiltration , 2013 .

[2]  Benny D. Freeman,et al.  Reverse osmosis desalination: water sources, technology, and today's challenges. , 2009, Water research.

[3]  Hans G.L. Coster,et al.  Detection of reverse osmosis membrane fouling with silica, bovine serum albumin and their mixture using in-situ electrical impedance spectroscopy , 2013 .

[4]  Toshiro Yamada,et al.  Chemical cleaning of reverse osmosis membranes used for treating wastewater from a rolling mill process , 2006 .

[5]  H. Ngo,et al.  In situ investigation of combined organic and colloidal fouling for nanofiltration membrane using ultrasonic time domain reflectometry , 2015 .

[6]  Seoktae Kang,et al.  Designing a biocidal reverse osmosis membrane coating: Synthesis and biofouling properties , 2016 .

[7]  V. Vatanpour,et al.  Investigation of raw and oxidized multiwalled carbon nanotubes in fabrication of reverse osmosis polyamide membranes for improvement in desalination and antifouling properties , 2017 .

[8]  Manh Hoang,et al.  An autopsy study of a fouled reverse osmosis membrane element used in a brackish water treatment plant. , 2007, Water research.

[9]  Sin Yin Lee,et al.  Comparing the growth and structure of flocs from electrocoagulation and chemical coagulation , 2016 .

[10]  B. Bruggen,et al.  The presence of ferric iron promotes calcium sulphate scaling in reverse osmosis processes , 2016 .

[11]  Shengfu Chen,et al.  A facile method for polyamide membrane modification by poly(sulfobetaine methacrylate) to improve fouling resistance , 2013 .

[12]  Jia Shin Ho,et al.  A threshold flux phenomenon for colloidal fouling in reverse osmosis characterized by transmembrane pressure and electrical impedance spectroscopy , 2016 .

[13]  G. Barton,et al.  Real time fouling monitoring with Electrical Impedance Spectroscopy , 2015 .

[14]  Anthony G Fane,et al.  Colloidal interactions and fouling of NF and RO membranes: a review. , 2011, Advances in colloid and interface science.

[15]  A. Marczewski,et al.  Adsorption of chlorophenoxy pesticides on activated carbon with gradually removed external particle layers , 2017 .

[16]  C. Saint,et al.  Assessing granular media filtration for the removal of chemical contaminants from wastewater. , 2011, Water research.

[17]  Jixiao Wang,et al.  Positively charged aromatic polyamide reverse osmosis membrane with high anti-fouling property prepared by polyethylenimine grafting , 2015 .

[18]  R. Lovitt,et al.  Fouling strategies and the cleaning system of NF membranes and factors affecting cleaning efficiency , 2007 .

[19]  John H. Lienhard,et al.  Scaling and fouling in membrane distillation for desalination applications: A review , 2015 .

[20]  Linhua Fan,et al.  Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures , 2012, Membranes.

[21]  Seungkwan Hong,et al.  Effect of solution chemistry on organic fouling of reverse osmosis membranes in seawater desalination , 2010 .

[22]  Hideto Matsuyama,et al.  Prevention of bacterial adhesion on polyamide reverse osmosis membranes via electrostatic interactions using a cationic phosphorylcholine polymer coating , 2014 .

[23]  S. Chellam,et al.  Reverse osmosis fouling during pilot-scale municipal water reuse: Evidence for aluminum coagulant carryover , 2016 .

[24]  N. Graham,et al.  Treatment of a secondary municipal effluent by ozone, UV and microfiltration: microbial reduction and effect on effluent quality , 2005 .

[25]  Seungkwan Hong,et al.  Nano-colloidal fouling mechanisms in seawater reverse osmosis process evaluated by cake resistance simulator-modified fouling index nanofiltration , 2014 .

[26]  John A. Bush,et al.  Membrane distillation for concentration of hypersaline brines from the Great Salt Lake: Effects of scaling and fouling on performance, efficiency, and salt rejection , 2016 .

[27]  Thomas L. Troyer,et al.  Chemical control of colloidal fouling of reverse osmosis systems , 2005 .

[28]  Menachem Elimelech,et al.  Colloidal Fouling of Reverse Osmosis Membranes: Measurements and Fouling Mechanisms , 1997 .

[29]  L. Zou,et al.  Synthesis and characterisation of superhydrophilic conductive heterogeneous PANI/PVDF anion-exchange membranes , 2015 .

[30]  B. Freeman,et al.  Fouling propensity of a poly(vinylidene fluoride) microfiltration membrane to several model oil/water emulsions , 2016 .

[31]  H. Budman,et al.  Assessing the role of feed water constituents in irreversible membrane fouling of pilot-scale ultrafiltration drinking water treatment systems. , 2013, Water research.

[32]  Daniel M. Kammen,et al.  Assessing the impacts of nuclear desalination and geoengineering to address China's water shortages , 2015 .

[33]  A. Ellis,et al.  Surface initiated polydopamine grafted poly([2-(methacryoyloxy)ethyl]trimethylammonium chloride) coatings to produce reverse osmosis desalination membranes with anti-biofouling properties , 2014 .

[34]  Walter Den,et al.  REMOVAL OF SILICA FROM BRACKISH WATER BY ELECTROCOAGULATION PRETREATMENT TO PREVENT FOULING OF REVERSE OSMOSIS MEMBRANES , 2008 .

[35]  Chuyang Y. Tang,et al.  Membrane fouling in osmotically driven membrane processes: A review , 2016 .

[36]  L. Xiaowei,et al.  Study on different ultrafiltration-based hybrid pretreatment systems for reverse osmosis desalination , 2015 .

[37]  S. Hong,et al.  Surface modification of a polyamide reverse osmosis membrane for chlorine resistance improvement , 2012 .

[38]  C. Visvanathan,et al.  Evaluation of virus removal efficiency of coagulation-sedimentation and rapid sand filtration processes in a drinking water treatment plant in Bangkok, Thailand. , 2016, Water research.

[39]  Devotha Nyambo,et al.  Applications: A Review , 2014 .

[40]  S. Azari,et al.  Fouling resistant zwitterionic surface modification of reverse osmosis membranes using amino acid l-cysteine , 2013 .

[41]  P. Bérubé,et al.  Ageing of membranes for water treatment: Linking changes to performance , 2016 .

[42]  Zafarullah Khan,et al.  Biofouling in reverse osmosis membranes for seawater desalination: Phenomena and prevention , 2011 .

[43]  Chuyang Y. Tang,et al.  Protein fouling of nanofiltration, reverse osmosis, and ultrafiltration membranes—The role of hydrodynamic conditions, solution chemistry, and membrane properties , 2011 .

[44]  Che-Jen Lin,et al.  Inorganic fouling of pressure-driven membrane processes — A critical review , 2010 .

[45]  H. Coster,et al.  Fouling of reverse osmosis membranes using electrical impedance spectroscopy: Measurements and simulations , 2009 .

[46]  Joseph G Jacangelo,et al.  Emerging desalination technologies for water treatment: a critical review. , 2015, Water research.

[47]  K. Gleason,et al.  Surface modification of reverse osmosis membranes with zwitterionic coating for improved resistance to fouling , 2015 .

[48]  Cong-jie Gao,et al.  Surface modification of thin-film composite polyamide reverse osmosis membranes with thermo-responsive polymer (TRP) for improved fouling resistance and cleaning efficiency , 2011 .

[49]  Ha‐Jin Lee,et al.  Cube sugar-like sponge/polymer brush composites for portable and user-friendly heavy metal ion adsorbents. , 2016, Journal of hazardous materials.

[50]  Shadi W. Hasan,et al.  A short review on reverse osmosis pretreatment technologies , 2014 .

[51]  Chen-yan Hu,et al.  A comparison of iodinated trihalomethane formation from chlorine, chlorine dioxide and potassium permanganate oxidation processes. , 2015, Water research.

[52]  Menachem Elimelech,et al.  Chemical cleaning of RO membranes fouled by wastewater effluent: Achieving higher efficiency with du , 2011 .

[53]  Alexander S. Gorzalski,et al.  Fouling of nanofiltration membranes in full- and bench-scale systems treating groundwater containing silica , 2014 .

[54]  S.T.V. Sim,et al.  Monitoring membrane biofouling via ultrasonic time-domain reflectometry enhanced by silica dosing , 2013 .

[55]  J. Grossman,et al.  Water desalination across nanoporous graphene. , 2012, Nano letters.

[56]  E. Casey,et al.  The role of cell-surface interactions in bacterial initial adhesion and consequent biofilm formation on nanofiltration/reverse osmosis membranes , 2014 .

[57]  Haiou Huang,et al.  The effects of organic fouling on the removal of radionuclides by reverse osmosis membranes. , 2016, Water research.

[58]  M. Khosravi,et al.  Chemical cleaning of reverse osmosis and nanofiltration membranes fouled by licorice aqueous solutions , 2011 .

[59]  Nalan Kabay,et al.  Pre-treatment with nanofiltration (NF) in seawater desalination—Preliminary integrated membrane tests in Urla, Turkey , 2015 .

[60]  G. Huang,et al.  Hardness, COD and turbidity removals from produced water by electrocoagulation pretreatment prior to Reverse Osmosis membranes , 2014 .

[61]  George M. Ayoub,et al.  Reverse osmosis technology for water treatment: State of the art review , 2011 .

[62]  Hans-Curt Flemming,et al.  Reverse osmosis membrane biofouling , 1997 .

[63]  Y. Cohen,et al.  Biofouling and cleaning effectiveness of surface nanostructured reverse osmosis membranes , 2013 .

[64]  M. Reinhard,et al.  Effects of polyether–polyamide block copolymer coating on performance and fouling of reverse osmosis membranes , 2006 .

[65]  N. Graham,et al.  Performance of an integrated granular media – Ultrafiltration membrane process for drinking water treatment , 2015 .

[66]  J. M. Thwala,et al.  Osmotic backwash of fouled FO membranes : cleaning mechanisms and membrane surface properties after cleaning , 2017 .

[67]  Vicki Chen,et al.  Natural organic matter (NOM) fouling in low pressure membrane filtration — effect of membranes and operation modes , 2008 .

[68]  Anja Drews,et al.  Membrane fouling in membrane bioreactors—Characterisation, contradictions, cause and cures , 2010 .

[69]  A. Martínez-Férez,et al.  On the cleaning procedure of a hydrophilic reverse osmosis membrane fouled by secondary-treated olive mill wastewater , 2015 .

[70]  B. Logan,et al.  Influence of Fluid Velocity and Cell Concentration on the Transport of Motile and Nonmotile Bacteria in Porous Media , 1998 .

[71]  Mingli Xu,et al.  Fouling resistance and cleaning efficiency of stimuli-responsive reverse osmosis (RO) membranes , 2016 .

[72]  Vicki Chen,et al.  Investigations of the coupled effect of cake-enhanced osmotic pressure and colloidal fouling in RO using crossflow sampler-modified fouling index ultrafiltration , 2011 .

[73]  In-Chul Kim,et al.  Interfacially synthesized chlorine-resistant polyimide thin film composite (TFC) reverse osmosis (RO) membranes , 2013 .

[74]  A. Schäfer,et al.  Factors affecting fluoride and natural organic matter (NOM) removal from natural waters in Tanzania by nanofiltration/reverse osmosis. , 2015, The Science of the total environment.

[75]  H. Matsuyama,et al.  Biofouling resistance of reverse osmosis membrane modified with polydopamine , 2014 .

[76]  C. Haas,et al.  Contribution of assimilable organic carbon to biological fouling in seawater reverse osmosis membrane treatment. , 2016, Water research.

[77]  Tien Vinh Nguyen,et al.  Effluent organic matter removal from reverse osmosis feed by granular activated carbon and purolite A502PS fluidized beds , 2014 .

[78]  Jeffrey C. Grossman,et al.  Nanoporous graphene as a reverse osmosis membrane: Recent insights from theory and simulation , 2015 .

[79]  E. Hoek,et al.  Effects of water chemistry on structure and performance of polyamide composite membranes , 2014 .

[80]  Debashis Chatterjee,et al.  Pilot study on arsenic removal from groundwater using a small-scale reverse osmosis system-Towards sustainable drinking water production. , 2016, Journal of hazardous materials.

[81]  K. Choo,et al.  Membrane photoreactor treatment of 1,4-dioxane-containing textile wastewater effluent: Performance, modeling, and fouling control. , 2015, Water research.

[82]  Menachem Elimelech,et al.  Fouling of reverse osmosis membranes by hydrophilic organic matter: implications for water reuse , 2006 .

[83]  Grace Adeniji-Oloukoi,et al.  Households' coping strategies for climate variability related water shortages in Oke-Ogun region, Nigeria , 2013 .

[84]  S. Ong,et al.  Fouling of RO membranes by effluent organic matter (EfOM): Relating major components of EfOM to their characteristic fouling behaviors , 2010 .

[85]  S. S. Madaeni,et al.  CHEMICAL CLEANING OF REVERSE OSMOSIS MEMBRANE FOULED BY WASTEWATER , 2010 .

[87]  Ahmed S. Al-Amoudi,et al.  Factors affecting natural organic matter (NOM) and scaling fouling in NF membranes: A review , 2010 .

[88]  Menachem Elimelech,et al.  Salt cleaning of organic-fouled reverse osmosis membranes. , 2007, Water research.

[89]  Jun Huang,et al.  Mechanisms of enhanced total organic carbon elimination from oxalic acid solutions by electro-peroxone process. , 2015, Water research.

[90]  Cong-jie Gao,et al.  Surface modification of a commercial thin-film composite polyamide reverse osmosis membrane through graft polymerization of N-isopropylacrylamide followed by acrylic acid , 2013 .

[91]  Mohammad Nurul Alam Hawlader,et al.  An experiment with different pretreatment methods , 2003 .

[92]  Cong-jie Gao,et al.  High-flux and fouling-resistant reverse osmosis membrane prepared with incorporating zwitterionic amine monomers via interfacial polymerization , 2016 .

[93]  B. Chaplin,et al.  Electrochemical impedance spectroscopy study of membrane fouling and electrochemical regeneration at a sub-stoichiometric TiO 2 reactive electrochemical membrane , 2016 .

[94]  S. Zubair,et al.  Organic fouling in surface modified reverse osmosis membranes: Filtration studies and subsequent morphological and compositional characterization , 2017 .

[95]  Zhenfa Liu,et al.  Antiscaling effect of polyaspartic acid and its derivative for RO membranes used for saline wastewater and brackish water desalination , 2017 .

[96]  Bruce Jefferson,et al.  Chlorine disinfection of grey water for reuse: effect of organics and particles. , 2008, Water research.

[97]  S. Couperthwaite,et al.  Evaluation of electrocoagulation for the pre-treatment of coal seam water , 2014 .

[98]  Esther Karunakaran,et al.  Physicochemical analysis of initial adhesion and biofilm formation of Methanosarcina barkeri on polymer support material. , 2016, Colloids and surfaces. B, Biointerfaces.

[99]  Jianrong Chen,et al.  A critical review of extracellular polymeric substances (EPSs) in membrane bioreactors: Characteristics, roles in membrane fouling and control strategies , 2014 .

[100]  V. Bright,et al.  Use of capacitive microsensors and ultrasonic time-domain reflectometry for in-situ quantification of concentration polarization and membrane fouling in pressure-driven membrane filtration☆ , 2006 .

[101]  Yong Taek Lee,et al.  Surface modification of polyamide RO membrane for improved fouling resistance , 2016 .

[102]  Ludovic F. Dumée,et al.  Towards integrated anti-microbial capabilities: Novel bio-fouling resistant membranes by high velocity embedment of silver particles , 2015 .

[103]  Cong-jie Gao,et al.  Improving fouling resistance and chlorine stability of aromatic polyamide thin-film composite RO membrane by surface grafting of polyvinyl alcohol (PVA) , 2015 .

[104]  Panagiotis D. Christofides,et al.  Self-adaptive feed flow reversal operation of reverse osmosis desalination , 2013 .

[105]  Menachem Elimelech,et al.  Colloidal fouling in forward osmosis: Role of reverse salt diffusion , 2012 .

[106]  Menachem Elimelech,et al.  Influence of membrane surface properties on initial rate of colloidal fouling of reverse osmosis and nanofiltration membranes , 2001 .

[107]  M. Elimelech,et al.  Fatty acid fouling of reverse osmosis membranes: implications for wastewater reclamation. , 2008, Water research.

[108]  J. Fuhrman,et al.  Bacterial community structure and its patterns. , 2008 .

[109]  Yoram Cohen,et al.  A novel RO ex situ scale observation detector (EXSOD) for mineral scale characterization and early detection , 2007 .

[110]  Majid Bagheri,et al.  Evaluation and prediction of membrane fouling in a submerged membrane bioreactor with simultaneous upward and downward aeration using artificial neural network-genetic algorithm , 2015 .

[111]  Jae-Hong Kim,et al.  Analysis of CaSO4 scale formation mechanism in various nanofiltration modules , 1999 .

[112]  Guo-Rong Xu,et al.  Strategies for improving the performance of the polyamide thin film composite (PA-TFC) reverse osmosis (RO) membranes: Surface modifications and nanoparticles incorporations , 2013 .

[113]  M. Hosseini,et al.  The Separation Method for Removing of Colloidal Particles from Raw Water , 2008 .

[114]  A. Adin,et al.  Electrocoagulation versus chemical coagulation: coagulation/flocculation mechanisms and resulting floc characteristics. , 2012, Water research.

[115]  N. K. Saha,et al.  Low fouling and improved chlorine resistant thin film composite reverse osmosis membranes by cerium(IV)/polyvinyl alcohol mediated surface modification , 2015 .

[116]  Menachem Elimelech,et al.  Chemical and physical aspects of cleaning of organic-fouled reverse osmosis membranes , 2006 .

[117]  C. Aneziris,et al.  Removal of colloidal particles in ceramic depth filters based on diatomaceous earth , 2011 .

[118]  Yiliang Zhao,et al.  Essential factors of an integrated moving bed biofilm reactor-membrane bioreactor: Adhesion characteristics and microbial community of the biofilm. , 2016, Bioresource technology.

[119]  W. Krantz,et al.  Effect of humic-acid fouling on membrane distillation , 2016 .

[120]  The-Vinh Nguyen,et al.  Osmosis-assisted cleaning of organic-fouled seawater RO membranes , 2013 .

[121]  Qian-Yuan Wu,et al.  Fouling of reverse osmosis membrane for municipal wastewater reclamation: Autopsy results from a full-scale plant , 2014 .

[122]  In S. Kim,et al.  Foulant characterization and distribution in spiral wound reverse osmosis membranes from different pressure vessels , 2015 .

[123]  Eric M.V. Hoek,et al.  Modeling the effects of fouling on full-scale reverse osmosis processes , 2008 .

[124]  Cong-jie Gao,et al.  Intensified cleaning of organic-fouled reverse osmosis membranes by thermo-responsive polymer (TRP) , 2012 .

[125]  A. Sathasivan,et al.  A review: Potential and challenges of biologically activated carbon to remove natural organic matter in drinking water purification process. , 2017, Chemosphere.

[126]  In S. Kim,et al.  Organic fouling behavior in direct contact membrane distillation , 2014 .

[127]  S. Agarwal,et al.  Removal of As(III) and As(V) using rubber tire derived activated carbon modified with alumina composite , 2016 .

[128]  T. Bergan [Chlorine disinfection]. , 1974, Tidsskrift for Den Norske Laegeforening.

[129]  J. J. Sadhwani,et al.  Cleaning tests for seawater reverse osmosis membranes , 2001 .

[130]  ChangKyoo Yoo,et al.  Proposed new fouling monitoring indices for seawater reverse osmosis to determine the membrane cleaning interval , 2013 .

[131]  Hideto Matsuyama,et al.  Important fractions of organic matter causing fouling of seawater reverse osmosis (SWRO) membranes , 2016 .

[132]  Zhe Zhang,et al.  Enhancing chlorine resistances and anti-biofouling properties of commercial aromatic polyamide reverse osmosis membranes by grafting 3-allyl-5,5-dimethylhydantoin and N,N′-Methylenebis(acrylamide) , 2013 .

[133]  Lisa Henthorne,et al.  State-of-the-art of reverse osmosis desalination pretreatment , 2015 .

[134]  Jaeweon Cho,et al.  Membrane filtration of natural organic matter: factors and mechanisms affecting rejection and flux decline with charged ultrafiltration (UF) membrane , 2000 .

[135]  M. Monnot,et al.  Granular activated carbon filtration plus ultrafiltration as a pretreatment to seawater desalination lines: Impact on water quality and UF fouling , 2016 .

[136]  Stephen P. Chesters,et al.  Innovations in the inhibition and cleaning of reverse osmosis membrane scaling and fouling. , 2009 .

[137]  J. Kavanagh,et al.  In situ characterization of compaction, ionic barrier and hydrodynamics of polyamide reverse osmosis membranes using electrical impedance spectroscopy , 2015 .

[138]  Manuel Fariñas,et al.  New and innovative sea water intake system for the desalination plant at San Pedro del Pinatar , 2007 .

[139]  M. Teixeira,et al.  Fouling of nanofiltration membrane: Effects of NOM molecular weight and microcystins , 2013 .

[140]  M. Pérez,et al.  Comparison of MF/UF pretreatment with conventional filtration prior to RO membranes for surface seawater desalination , 2002 .

[141]  Liu Yang,et al.  Pilot testing of outside-in UF pretreatment prior to RO for high turbidity seawater desalination , 2006 .

[142]  Jaeweon Cho,et al.  Biodegradability, DBP formation, and membrane fouling potential of natural organic matter: characterization and controllability. , 2005, Environmental science & technology.

[143]  Laura García-Cuerva,et al.  Public perceptions of water shortages, conservation behaviors, and support for water reuse in the U.S. , 2016 .

[144]  S. Sharifnia,et al.  CHEMICAL CLEANING OF ULTRAFILTRATION MEMBRANES FOULED BY WHEY , 2001 .

[145]  Markus Busch,et al.  How different is the composition of the fouling layer of wastewater reuse and seawater desalination RO membranes? , 2014, Water research.

[146]  V. Bright,et al.  Comprehensive experimental studies of early-stage membrane scaling during nanofiltration , 2011 .

[147]  Jaeweon Cho,et al.  MEMBRANE FILTRATION OF NATURAL ORGANIC MATTER: INITIAL COMPARISON OF REJECTION AND FLUX DECLINE CHARACTERISTICS WITH ULTRAFILTRATION AND NANOFILTRATION MEMBRANES , 1999 .

[148]  A. Ellis,et al.  The impact of diatoms on the biofouling of seawater reverse osmosis membranes in a model cross-flow system , 2016 .

[149]  L. Kong,et al.  Promoted water transport across graphene oxide-poly(amide) thin film composite membranes and their antibacterial activity , 2015 .

[150]  F. Clarens,et al.  Life cycle and human health risk assessments as tools for decision making in the design and implementation of nanofiltration in drinking water treatment plants. , 2014, The Science of the total environment.

[151]  M. Loosdrecht,et al.  Magnetic resonance imaging and 3D simulation studies of biofilm accumulation and cleaning on reverse osmosis membranes , 2010 .

[152]  Ludovic F. Dumée,et al.  Hybrid thin film nano-composite membrane reactors for simultaneous separation and degradation of pesticides , 2017 .

[153]  H. F. Shaalan,et al.  Development of fouling control strategies pertinent to nanofiltration membranes , 2003 .

[154]  M. Khayet Fouling and Scaling in Desalination , 2016 .

[155]  I. Aljundi,et al.  Membrane fouling and modification using surface treatment and layer-by-layer assembly of polyelectrolytes: State-of-the-art review , 2016 .

[156]  G. Pearce The case for UF/MF pretreatment to RO in seawater applications , 2007 .

[157]  Cong-jie Gao,et al.  Fabrication and characterization of a novel poly(amide-urethane@imide) TFC reverse osmosis membrane with chlorine-tolerant property , 2014 .

[158]  A. Varesano,et al.  Chitosan coated cotton gauze for antibacterial water filtration. , 2014, Carbohydrate polymers.

[159]  Menachem Elimelech,et al.  Protein (BSA) fouling of reverse osmosis membranes : Implications for wastewater reclamation , 2007 .

[160]  Pierre Lucien Cote,et al.  A method for assessing membrane fouling in pilot-and full-scale systems , 2001 .

[161]  Pierre Le-Clech,et al.  Analysis of UF membrane fouling mechanisms caused by organic interactions in seawater. , 2013, Water research.

[162]  Talal Yusaf,et al.  Biofouling in RO system: Mechanisms, monitoring and controlling , 2012 .

[163]  Rong Wang,et al.  Effects of scaling and cleaning on the performance of forward osmosis hollow fiber membranes , 2012 .

[164]  C. Liu Advances in Membrane Technologies for Drinking Water Purification , 2014 .

[165]  Menachem Elimelech,et al.  Fouling and cleaning of RO membranes fouled by mixtures of organic foulants simulating wastewater ef , 2011 .

[166]  Y. Cohen,et al.  An Integrated approach for characterization of polyamide reverse osmosis membrane degradation due to exposure to free chlorine , 2016 .

[167]  S. Zaidi,et al.  Surface modification of reverse osmosis desalination membranes by thin-film coatings deposited by initiated chemical vapor deposition , 2013 .

[168]  Boris Liberman,et al.  Development of novel backwash cleaning technique for reverse osmosis in reclamation of secondary effluent , 2010 .

[169]  Yong-Sheng Li,et al.  Research on refurbishing of the used RO membrane through chemical cleaning and repairing with a new system , 2013 .

[170]  Panagiotis D. Christofides,et al.  Mineral scale monitoring for reverse osmosis desalination via real-time membrane surface image analysis , 2011 .

[171]  Gary L. Amy,et al.  Seawater reverse osmosis desalination and (harmful) algal blooms , 2015 .

[172]  Membrane fouling insight during reverse osmosis purification of pretreated olive mill wastewater , 2016 .

[173]  Hyun-Chul Kim,et al.  Membrane fouling due to alginate, SMP, EfOM, humic acid, and NOM , 2013 .

[174]  C. Morlay,et al.  The removal of endocrine disrupting compounds, pharmaceutically activated compounds and cyanobacterial toxins during drinking water preparation using activated carbon--a review. , 2012, The Science of the total environment.

[175]  Jing Wang,et al.  Improving the water flux and bio-fouling resistance of reverse osmosis (RO) membrane through surface modification by zwitterionic polymer , 2015 .

[176]  Ngai Yin Yip,et al.  hemical cleaning of RO membranes fouled by wastewater effluent : Achieving igher efficiency with dual-step cleaning ui , 2011 .

[177]  K. Jacob,et al.  Novel reverse osmosis membranes composed of modified PVA/Gum Arabic conjugates: Biofouling mitigation and chlorine resistance enhancement. , 2017, Carbohydrate polymers.

[178]  Jianxin Li,et al.  In situ investigation of fouling behavior in submerged hollow fiber membrane module under sub-critical flux operation via ultrasonic time domain reflectometry , 2012 .

[179]  N. Hilal,et al.  Polymeric membranes: surface modification for minimizing (bio)colloidal fouling. , 2014, Advances in colloid and interface science.

[180]  Weimin Gao,et al.  Understanding water and ion transport behaviour and permeability through poly(amide) thin film composite membrane , 2015 .

[181]  Menachem Elimelech,et al.  Combined organic and colloidal fouling in forward osmosis: Fouling reversibility and the role of applied pressure , 2014 .

[182]  M. Herzberg,et al.  Biofilm formation on RO membranes: the impact of seawater pretreatment , 2016 .

[183]  M. Kennedy,et al.  Effect of coagulation on fouling potential and removal of algal organic matter in ultrafiltration pretreatment to seawater reverse osmosis. , 2014, Water research.

[184]  Fariborz Taghipour,et al.  Application of ultraviolet light-emitting diodes (UV-LEDs) for water disinfection: A review. , 2016, Water research.

[185]  R. Field,et al.  Synergetic cleaning procedure for a ceramic membrane fouled by beer microfiltration , 1999 .

[186]  Lingyun Shi,et al.  Cleaning effects of oxalic acid under ultrasound to the used reverse osmosis membranes with an online cleaning and monitoring system , 2016 .

[187]  Muhammad Tariq Khan,et al.  Source water quality shaping different fouling scenarios in a full-scale desalination plant at the Red Sea. , 2013, Water research.

[188]  Application of Ultraviolet Light Emitting Diodes for the Advanced Oxidation of Guar Gum , 2018 .

[189]  M. Monnot,et al.  Seawater reverse osmosis desalination plant at community-scale: Role of an innovative pretreatment on process performances and intensification , 2017 .

[190]  S. Yuu,et al.  Removal of colloidal particles in electroflotation , 1985 .

[191]  H. Coster,et al.  In situ structural and functional characterization of reverse osmosis membranes using electrical impedance spectroscopy , 2013 .

[192]  Hong-Ying Hu,et al.  Fouling characteristics of reverse osmosis membranes at different positions of a full-scale plant for municipal wastewater reclamation. , 2016, Water research.

[193]  S. Zinadini,et al.  Fabrication and characterization of novel antifouling nanofiltration membrane prepared from oxidized multiwalled carbon nanotube/polyethersulfone nanocomposite , 2011 .

[194]  Hong Wang,et al.  Direct monitoring of sub-critical flux fouling in a horizontal double-end submerged hollow fiber membrane module using ultrasonic time domain reflectometry , 2014 .

[195]  L. Fan,et al.  Effect of biological activated carbon pre-treatment to control organic fouling in the microfiltration of biologically treated secondary effluent. , 2014, Water research.

[196]  Alnaif Naser,et al.  Removal of turbidity and suspended solids by electro-coagulation to improve feed water quality of reverse osmosis plant , 2011 .

[197]  N. Graham,et al.  Evaluation of ferrate as a coagulant aid/oxidant pretreatment for mitigating submerged ultrafiltration membrane fouling in drinking water treatment , 2016 .

[198]  B. García-Fayos,et al.  Static cleaning tests as the first step to optimize RO membranes cleaning procedure , 2015 .

[199]  Changjoo Yeom,et al.  Purification of oily seawater/wastewater using superhydrophobic nano-silica coated mesh and sponge , 2016 .

[200]  C. Vial,et al.  Assessment of hardness, microorganism and organic matter removal from seawater by electrocoagulation as a pretreatment of desalination by reverse osmosis , 2016 .

[201]  Marc Pidou,et al.  Biofouling and scaling control of reverse osmosis membrane using one-step cleaning - potential of acidified nitrite solution as an agent , 2015 .

[202]  P. Kabat,et al.  Analysing monthly sectorial water use and its influence on salt intrusion induced water shortage in urbanized deltas , 2016 .

[203]  V. Vatanpour,et al.  Surface modification of commercial seawater reverse osmosis membranes by grafting of hydrophilic monomer blended with carboxylated multiwalled carbon nanotubes , 2017 .

[204]  Ludovic F. Dumée,et al.  Amine Enrichment of Thin-Film Composite Membranes via Low Pressure Plasma Polymerization for Antimicrobial Adhesion. , 2015, ACS applied materials & interfaces.

[205]  Sungsoo Han,et al.  Surface modification of SWRO membranes using hydroxyl poly(oxyethylene) methacrylate and zwitterionic carboxylated polyethyleneimine , 2015 .

[206]  Serge Stoll,et al.  A Generalized Description of Aquatic Colloidal Interactions: The Three-colloidal Component Approach , 1998 .

[207]  S. Vigneswaran,et al.  In-depth analyses of organic matters in a full-scale seawater desalination plant and an autopsy of reverse osmosis membrane , 2016 .

[208]  Seungho Yu,et al.  A comparative study of disinfection efficiency and regrowth control of microorganism in secondary wastewater effluent using UV, ozone, and ionizing irradiation process. , 2015, Journal of hazardous materials.

[209]  Menachem Elimelech,et al.  Role of Cell Surface Lipopolysaccharides in Escherichia coli K12 adhesion and transport. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[210]  M. Drikas,et al.  Comparison of NOM character in selected Australian and Norwegian drinking waters. , 2008, Water research.

[211]  Marc A. Deshusses,et al.  Direct observation of biofouling in cross-flow microfiltration: mechanisms of deposition and release , 2004 .

[212]  Chuyang Y. Tang,et al.  Surface modification of thin film composite RO membrane for enhanced anti-biofouling performance , 2013 .

[213]  R. Schneider,et al.  Analysis of foulant layer in all elements of an RO train , 2005 .

[214]  In S. Kim,et al.  Foulant analysis of a reverse osmosis membrane used pretreated seawater , 2013 .

[215]  Veronique Bonnelye,et al.  UF/MF as RO pre-treatment: the real benefit , 2008 .

[216]  Sudhakar M. Rao Reverse osmosis , 2007 .

[217]  Seockheon Lee,et al.  Changes in the relative abundance of biofilm-forming bacteria by conventional sand-filtration and microfiltration as pretreatments for seawater reverse osmosis desalination , 2011 .

[218]  Menachem Elimelech,et al.  Fouling of Reverse Osmosis Membranes by Aluminum Oxide Colloids , 1995 .

[219]  Hong-Ying Hu,et al.  Characterization of trihalomethane, haloacetic acid, and haloacetonitrile precursors in a seawater reverse osmosis system. , 2017, The Science of the total environment.

[220]  R. Sheikholeslami,et al.  Silica fouling and cleaning of reverse osmosis membranes , 2001 .

[221]  Yufeng Zhang,et al.  Surface coating on the polyamide TFC RO membrane for chlorine resistance and antifouling performance improvement , 2014 .

[222]  N. Hilal,et al.  A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion , 2015 .

[223]  Carla Denis,et al.  Study of biofilms on PVDF membranes after chemical cleaning by sodium hypochlorite , 2015 .

[224]  Jixiao Wang,et al.  A novel reverse osmosis membrane with regenerable anti-biofouling and chlorine resistant properties , 2013 .

[225]  A. Fane,et al.  Quantitative determination of the electrical properties of RO membranes during fouling and cleaning processes using electrical impedance spectroscopy , 2016 .

[226]  M. Loosdrecht,et al.  Chemical cleaning of biofouling in reverse osmosis membranes evaluated using magnetic resonance imaging , 2010 .

[227]  G. Leslie,et al.  Real-time monitoring of scale formation in reverse osmosis using electrical impedance spectroscopy , 2014 .

[228]  T. Arnot,et al.  A review of reverse osmosis membrane materials for desalinationDevelopment to date and future poten , 2011 .

[229]  M. V. van Loosdrecht,et al.  Bacterial community structure and variation in a full-scale seawater desalination plant for drinking water production. , 2016, Water research.

[230]  Cong-jie Gao,et al.  Novel composite nanofiltration membranes containing zwitterions with high permeate flux and improved anti-fouling performance , 2012 .

[231]  Yong‐Seok Choi,et al.  Reverse osmosis nanocomposite membranes containing graphene oxides coated by tannic acid with chlorine-tolerant and antimicrobial properties , 2016 .

[232]  CHEMICAL CLEANING OF REVERSE OSMOSIS MEMBRANE FOULED BY APPLE JUICE , 2011 .

[233]  Christopher Bellona,et al.  Fouling of nanofiltration and reverse osmosis membranes during municipal wastewater reclamation: Membrane autopsy results from pilot-scale investigations , 2010 .

[234]  P. Scales,et al.  Influence of pre-treatment combinations on RO membrane fouling , 2016 .

[235]  J. A. López-Ramírez,et al.  Comparative studies of reverse osmosis membranes for wastewater reclamation , 2006 .

[236]  Xia Huang,et al.  A novel ZnO nanoparticle blended polyvinylidene fluoride membrane for anti-irreversible fouling , 2012 .

[237]  O. Coronell,et al.  Identifying facile and accurate methods to measure the thickness of the active layers of thin-film composite membranes – A comparison of seven characterization techniques , 2016 .