RENEWABLE ENERGY AND ENVIRONMENTAL SUSTAINABILITY USING BIOMASS FROM DAIRY AND BEEF ANIMAL PRODUCTION

The Texas Panhandle is regarded as the 'Cattle Feeding Capital of the World', producing 42% of the fed beef cattle in the United States within a 200-mile radius of Amarillo generating more than 5 million tons of feedlot manure/year. Apart from feedlots, the Bosque River Region in Erath County, just north of Waco, Texas with about 110,000 dairy cattle in over 250 dairies, produces 1.8 million tons of manure biomass (excreted plus bedding) per year. While the feedlot manure has been used extensively for irrigated and dry land crop production, most dairies, as well as other concentrated animal feeding operations (CAFO's), the dairy farms utilize large lagoon areas to store wet animal biomass. Water runoff from these lagoons has been held responsible for the increased concentration of phosphorus and other contaminates in the Bosque River which drains into Lake Waco - the primary source of potable water for Waco's 108,500 people. The concentrated animal feeding operations may lead to land, water, and air pollution if waste handling systems and storage and treatment structures are not properly managed. Manure-based biomass (MBB) has the potential to be a source of green energy at large coal-fired power plants and on smaller-scale combustion systemsmore » at or near confined animal feeding operations. Although MBB particularly cattle biomass (CB) is a low quality fuel with an inferior heat value compared to coal and other fossil fuels, the concentration of it at large animal feeding operations can make it a viable source of fuel. The overall objective of this interdisciplinary proposal is to develop environmentally benign technologies to convert low-value inventories of dairy and beef cattle biomass into renewable energy. Current research expands the suite of technologies by which cattle biomass (CB: manure, and premature mortalities) could serve as a renewable alternative to fossil fuel. The work falls into two broad categories of research and development. Category 1 - Renewable Energy Conversion. This category addressed mostly in volume I involves developing. Thermo-chemical conversion technologies including cofiring with coal, reburn to reduce nitrogen oxide (NO, N2O, NOx, etc.) and Hg emissions and gasification to produce low-BTU gas for on-site power production in order to extract energy from waste streams or renewable resources. Category 2 - Biomass Resource Technology. This category, addressed mostly in Volume II, deals with the efficient and cost-effective use of CB as a renewable energy source (e.g. through and via aqueous-phase, anaerobic digestion or biological gasification). The investigators formed an industrial advisory panel consisting fuel producers (feedlots and dairy farms) and fuel users (utilities), periodically met with them, and presented the research results; apart from serving as dissemination forum, the PIs used their critique to red-direct the research within the scope of the tasks. The final report for the 5 to 7 year project performed by an interdisciplinary team of 9 professors is arranged in three volumes: Vol. I (edited by Kalyan Annamalai) addressing thermo-chemical conversion and direct combustion under Category 1 and Vol. II and Vol. III ( edited by J M Sweeten) addressing biomass resource Technology under Category 2. Various tasks and sub-tasks addressed in Volume I were performed by the Department of Mechanical Engineering (a part of TEES; see Volume I), while other tasks and sub-tasks addressed in Volume II and IIII were conducted by Texas AgriLife Research at Amarillo; the TAMU Biological and Agricultural Engineering Department (BAEN) College Station; and West Texas A and M University (WTAMU) (Volumes II and III). The three volume report covers the following results: fuel properties of low ash and high ash CB (particularly DB) and MB (mortality biomass) and coals, non-intrusive visible infrared (NVIR) spectroscopy techniques for ash determination, dairy energy use surveys at 14 dairies in Texas and California, cofiring of low quality CB with high quality coal, emission results and ash fouling behavior, using CB as reburn fuel for NOx and Hg reduction, gasification of fuels to produce low quality gases, modeling of reburn, pilot scale test results, synthesis of engineering characterization, geographical mapping, a transportation cost study to determine potential handling and transportation systems for co-firing with coal at regional coal-fired power plants, software analyses for the design of off-site manure, pre-processing and storage systems for a typical dairy farm or beef cattle feedlot, recursive production functions/systems models for both cattle feedlots, systems modeling, stocks and flows of energy involved in the CAFO system, feedback from an Industry Advisory Committee (IAC) to the investigators on project direction and task emphasis and economics of using CB as cofiring and reburn fuel.« less

[1]  L. T. Fan,et al.  Gasification of Feedlot Manure in a Fluidized Bed Reactor. The Effect of Temperature , 1980 .

[2]  Hartmut Spliethoff,et al.  Effect of air-staging on mercury speciation in pulverized fuel co-combustion: part 2 , 2007 .

[3]  Yufeng Duan,et al.  Impact of Coal Chlorine on Mercury Speciation and Emission from a 100-MW Utility Boiler with Cold-Side Electrostatic Precipitators and Low-NOx Burners , 2005 .

[4]  Ronald W. Thring,et al.  Production of H2 and medium heating value gas via steam gasification of lignins in fixed‐bed reactors , 2010 .

[5]  Harvey G. Stenger,et al.  Effects of H2O, SO2, and NO on Homogeneous Hg Oxidation by Cl2 , 2006 .

[6]  Margaret S. Wooldridge,et al.  Co-firing of coal and biomass fuel blends , 2001 .

[7]  C. Di Blasi,et al.  Countercurrent fixed-bed gasification of biomass at laboratory scale , 1999 .

[8]  A. Bridgwater,et al.  The influence of feedstock drying on the performance and economics of a biomass gasifier–engine CHP system , 2002 .

[9]  John M. Sweeten,et al.  Thermo-Chemical Energy Conversion Using Supplementary Animal Wastes With Coal , 2007 .

[10]  Saqib Mukhtar,et al.  Utilization of Latent Heat Derived From Vaporized Wastewater in High Moisture Dairy Manure Combustion Schemes , 2007 .

[11]  Ravi K Srivastava,et al.  Nitrogen Oxides Emission Control Options for Coal-Fired Electric Utility Boilers , 2005, Journal of the Air & Waste Management Association.

[12]  Saqib Mukhtar,et al.  Fixed-bed gasification of feedlot manure and poultry litter biomass. , 2004 .

[13]  R. R. Rhinehart,et al.  Coal gasification in a pilot-scale fluidized bed reactor. 3. Gasification of a Texas lignite , 1987 .

[14]  Bruce Biewald,et al.  Use of Selective Catalytic Reduction For Control of NOx Emissions From Power Plants in the U . S . 1 , 2000 .

[15]  Lincoln Clark Young,et al.  High-temperature, air-blown gasification of dairy-farm wastes for energy production , 2003 .

[16]  Robert B. Finkelman,et al.  U.S. Geological Survey coal quality (COALQUAL) database; version 2.0 , 1997 .

[17]  L. D. Smoot,et al.  Release and reaction of fuel-nitrogen in a high-pressure entrained-coal gasifier , 1987 .

[18]  Helena Lopes,et al.  Effect of catalysts in the quality of syngas and by-products obtained by co-gasification of coal and wastes. 1. Tars and nitrogen compounds abatement , 2007 .

[19]  Saqib Mukhtar,et al.  Thermo-Chemical Conversion Analysis on Dairy Manure-Based Biomass Through Direct Combustion , 2007 .

[20]  A. Demirbas,et al.  Potential applications of renewable energy sources, biomass combustion problems in boiler power systems and combustion related environmental issues , 2005 .

[21]  M. Aznar,et al.  Biomass gasification in atmospheric and bubbling fluidized bed: effect of the type of gasifying agent on the product distribution , 1999 .

[22]  Udayasarathy Arcot Vijayasarathy Mercury emission control for coal fired power plants using coal and biomass , 2009 .

[23]  Atul K. Jain,et al.  Energy implications of future stabilization of atmospheric CO2 content , 1998, Nature.

[24]  John M. Sweeten,et al.  The economics of reburning with cattle manure-based biomass in existing coal-fired power plants for NOx and CO2 emissions control , 2009 .

[25]  Soyuz Priyadarsan Fixed bed gasification studies on coal-feedlot biomass and coal-chicken litter biomass under batch mode operation , 2002 .

[26]  Gerardo Gordillo Ariza Fixed bed countercurrent low temperature gasification of dairy biomass and coal -dairy biomass blends using air-steam as oxidizer , 2009 .

[27]  Adam Klimanek,et al.  Enhanced Yield of Hydrogen From Wastes Using High Temperature Steam Gasification , 2006 .

[28]  Nicholas Thomas Carlin Thermo-chemical conversion of dairy waste based biomass through direct firing , 2007 .

[29]  Saqib Mukhtar,et al.  Co-gasification of blended coal with feedlot and chicken litter biomass , 2005 .

[30]  Ishwar K. Puri,et al.  Combustion Science and Engineering , 2006 .

[31]  John M. Sweeten,et al.  Combustion-Fuel Properties of Manure or Compost from Paved vs. Un-paved Cattle Feedlots , 2006 .

[32]  Kalyan Annamalai,et al.  Dairy Biomass-Wyoming Coal Blends Fixed Gasification Using Air-Steam for Partial Oxidation , 2012 .

[33]  Colomba Di Blasi,et al.  Modeling wood gasification in a countercurrent fixed‐bed reactor , 2004 .

[34]  S. Thanapal,et al.  Fixed bed gasification of dairy biomass with enriched air mixture , 2012 .

[35]  John M. Sweeten,et al.  Assessment of Chemical and Physical Characteristics of Bottom, Cyclone, and Baghouse Ashes from the Combustion of Manure , 2006 .

[36]  Hyukjin Oh,et al.  Reburning renewable biomass for emissions control and ash deposition effects in power generation , 2009 .

[37]  Madhu Babu Puchakayala Mercury emission behavior during isolated coal particle combustion , 2009 .

[38]  John M. Sweeten,et al.  Co-combustion and Gasification of Coal and Cattle Biomass: a Review of Research and Experimentation , 2011 .

[39]  Kalyan Annamalai,et al.  Adiabatic fixed bed gasification of dairy biomass with air and steam , 2010 .

[40]  Kalyan Annamalai,et al.  Air-Steam Gasification of Dairy Biomass Using Small Scale Fixed Bed Gasifier , 2009 .

[41]  S. Mark Wilhelm,et al.  Generation and disposal of petroleum processing waste that contains mercury , 1999 .

[42]  John M. Sweeten,et al.  Energy Conversion: Coal, Animal Waste, and Biomass Fuel , 2012 .

[43]  K. C. Midkiff,et al.  Fuelnitrogen transformations in one-dimensional coal-dust flames , 1984 .

[44]  Sue Terpackaro,et al.  Twenty-Seventh Symposium (International) on Combustion. Volume 1 , 1998 .

[45]  Vladimir M. Zamansky,et al.  Second Generation Advanced Reburning for High Efficiency NOx Control , 1997 .

[46]  John M. Sweeten,et al.  Co-firing of coal and cattle feedlot biomass (FB) Fuels, Part III: fouling results from a 500,000 BTU/h pilot plant scale boiler burner☆ , 2003 .

[47]  Oliver Lindqvist,et al.  Chemical reactions of mercury in combustion flue gases , 1991 .

[48]  S. S. Penner,et al.  Combustion and Flames , 1960 .