Electroreduction of nitrite based on Ag/PPy nanowires modified electrodes

Polypyrrole(PPy) nanowires modified electrodes were developed by template-free electrochemical method based on graphite electrode. The Ag/PPy nanowires composited modofied electrodes were prepared by method of electrochemical deposition Ag with the condition of constant current density. The electrocatalytic reduction of nitrite based on Ag/PPy nanowires composited modified electrodes was developed. The effect of solution pH, electrolytic potentials and electrolytic current density on electrolysis of nitrite and the electrolysis products were also examined. Through the above experiment, the suitable conditions of electrocatalytic reduction nitrite on the Ag/PPy composited nanowires modified grapite electrodes can be established. And the Ag/PPy composited nanowires modified grapite electrodes should have promising application in environmental remediation.

[1]  T. Kang,et al.  Determination of nitrite using sensors based on nickel phthalocyanine polymer modified electrodes. , 2004, Talanta.

[2]  Xinming Li,et al.  Electrochemical oxidation behavior of nitrite on a chitosan-carboxylated multiwall carbon nanotube modified electrode , 2005 .

[3]  M. Gatta,et al.  Electrochemical reduction of NO3− and NO2− on a composite copper thallium electrode in alkaline solutions , 2004 .

[4]  C. Ewen,et al.  Evaluation of a multifunctional indicator for the electroanalytical determination of nitrite , 2005 .

[5]  T. Nyokong,et al.  Comparative electrooxidation of nitrite by electrodeposited Co(II), Fe(II) and Mn(III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines on gold electrodes. , 2007, Analytica chimica acta.

[6]  Tebello Nyokong,et al.  Electrocatalytic activity of arylthio tetra-substituted oxotitanium(IV) phthalocyanines towards the oxidation of nitrite , 2007 .

[7]  Jixiao Wang,et al.  Solid-phase extraction and amperometric determination of nitrite with polypyrrole nanowire modified electrodes , 2005 .

[8]  M. H. Pournaghi-Azar,et al.  ELECTROCATALYTIC OXIDATION OF NITRITE AT AN ALUMINUM ELECTRODE MODIFIED BY A CHEMICALLY DEPOSITED PALLADIUM PENTACYANONITROSYLFERRATE FILM , 2004 .

[9]  K. Bouzek,et al.  Platinum distribution and electrocatalytic properties of modified polypyrrole films , 2001 .

[10]  T. Nyokong,et al.  Metallophthalocyanine catalysed electroreduction of nitrate and nitrite ions in alkaline media , 1997 .

[11]  G. Milczarek Selective and sensitive detection of nitrite based on NO sensing on a polymer-coated rotating disc electrode , 2007 .

[12]  M. Kamyabi,et al.  Electrocatalytic oxidation and determination of nitrite on carbon paste electrode modified with oxovanadium(IV)-4-methyl salophen , 2008 .

[13]  I. Becerik,et al.  Electrocatalytic properties of platinum particles incorporated with polypyrrole films in d-glucose oxidation in phosphate media , 1997 .

[14]  Ebrahim Zarei,et al.  Electrocatalytic reduction of nitrite using ferricyanide; Application for its simple and selective determination , 2006 .