THE PROPERTIES OF ELECTRON AND HOLE TRAPS IN THERMAL SILICON DIOXIDE LAYERS GROWN ON SILICON

ABSTRACT Capture, optical and thermal discharge, and location of trapped electrons and holes in thermal silicon dioxide layers grown on silicon are reviewed. Charge trapping is discussed in oxides grown under various conditions (for instance, steam versus dry oxidation) and in oxides where impurites have been added by ion implantation or grown into the film at elevated temperatures. Characteristics of the trapping sites in terms of their spatial location, capture cross section, photoionization cross section, trap density, and energy depth in the forbidden gap are summarized for known traps. Techniques such as capacitance-voltage (C-V(l)) and photocurrent-voltage (photo I-V(2)) used in trap characterization are reviewed.

[1]  MOS Hardness Characterization and Its Dependence upon Some Process and Measurement Variables , 1976, IEEE Transactions on Nuclear Science.

[2]  R. Powell Hole photocurrents and electron tunnel injection induced by trapped holes in SiO2 films , 1975 .

[3]  R. C. Hughes Hole mobility and transport in thin SiO2 films , 1975 .

[4]  C. N. Berglund,et al.  AVALANCHE INJECTION CURRENTS AND CHARGING PHENOMENA IN THERMAL SiO2 , 1969 .

[5]  Richard Williams,et al.  Photoemission of Electrons from Silicon into Silicon Dioxide , 1965 .

[6]  Simon M. Sze,et al.  Carrier transport and storage effects in Au ion implanted SiO2 structures , 1972 .

[7]  K. W. Böer,et al.  Field‐Enhanced Ionization , 1970 .

[8]  A. F. Tasch,et al.  Recombination-Generation and Optical Properties of Gold Acceptor in Silicon , 1970 .

[9]  Carrier Injection into SiO2 from Si Surface Driven to Avalanche Breakdown by a Linear Ramp Pulse, and Trapping, Distribution and Thermal Annealing of Injected Holes in SiO2 , 1975 .

[10]  M. Lenzlinger,et al.  Fowler‐Nordheim Tunneling into Thermally Grown SiO2 , 1969 .

[11]  J. Aitken,et al.  Capture of electrons into Na+‐related trapping sites in the SiO2 layer of MOS structures at 77 °K , 1976 .

[12]  Donald R. Young Electron current injected into SiO2 from p‐type Si depletion regions , 1976 .

[13]  D. Dimaria,et al.  Capture and emission of electrons at 2.4-eV-deep trap level in SiO2films , 1975 .

[14]  D. Dimaria,et al.  Contact currents in silicon nitride , 1976 .

[15]  R. C. Hughes Charge-Carrier Transport Phenomena in Amorphous SiO 2 : Direct Measurement of the Drift Mobility and Lifetime , 1973 .

[16]  C. Henry Deep level spectroscopy, low temperature defect motion and nonradiative recombination in GaAs and GaP , 1975 .

[17]  J. Olivier,et al.  Energy losses of hot electrons in a thin layer of SiO2 on Si , 1972 .

[18]  J. R. Srour,et al.  Radiation-Induced Charge Transport and Charge Buildup in SiO2 Films at Low Temperatures , 1976, IEEE Transactions on Nuclear Science.

[19]  C. W. Gwyn,et al.  Model for Radiation‐Induced Charge Trapping and Annealing in the Oxide Layer of MOS Devices , 1969 .

[20]  Eiichi Suzuki,et al.  Avalanche Injection Effects in MIS Structures and Realization of N-Channel Enhancement Type MOS FETS , 1973 .

[21]  T. Ning,et al.  Optically induced injection of hot electrons into SiO2 , 1974 .

[22]  Carver A. Mead,et al.  Barrier energies in metal-silicon dioxide-silicon structures , 1966 .

[23]  B. L. Gregory,et al.  Process Optimization of Radiation-Hardened CMOS Integrated Circuits , 1975, IEEE Transactions on Nuclear Science.

[24]  H. R. Philipp,et al.  Optical transitions in crystalline and fused quartz , 1966 .

[25]  Tak H. Ning,et al.  Electron trapping at positively charged centers in SiO2 , 1975 .

[26]  E. Harari,et al.  Conduction and trapping of electrons in highly stressed ultrathin films of thermal SiO2 , 1977 .

[27]  The capture cross section of a dipole trap , 1975 .

[28]  R. C. Hughes Hot electron in SiO/sub 2/ , 1975 .

[29]  M. H. Woods,et al.  High electric fields in silicon dioxide produced by corona charging , 1973 .

[30]  D. Dimaria,et al.  Interface effects and high conductivity in oxides grown from polycrystalline silicon , 1975 .

[31]  S. R. Butler,et al.  Low-Temperature Photocurrent Spectroscopy on Localized States in SiO2Films , 1977 .

[32]  C. N. Berglund,et al.  Avalanche Injection of Electrons into Insulating SiO2 Using MOS Structures , 1970 .

[33]  Donald R. Young,et al.  Electron trapping by radiation‐induced charge in MOS devices , 1976 .

[34]  R. A. Gdula,et al.  The Effects of Processing on Hot Electron Trapping in SiO2 , 1976 .

[35]  Z. Weinberg,et al.  Use of photocurrent-voltage characteristics of MOS structures to determine insulator bulk trapped charge densities and centroids , 1977 .

[36]  E. P. EerNisse,et al.  Introduction rates and annealing of defects in ion‐implanted SiO2 layers on Si , 1974 .

[37]  A. Goodman,et al.  Photoemission of Electrons from Metals into Silicon Dioxide , 1966 .

[38]  M. Shatzkes,et al.  Impact ionization and positive charge in thin SiO2 films , 1976 .

[39]  J. H. Thomas,et al.  Electron trapping levels in silicon dioxide thermally grown on silicon , 1972 .

[40]  T. Ning Capture cross section and trap concentration of holes in silicon dioxide , 1976 .

[41]  C. Sah,et al.  Photoionization of Electrons at Sulfur Centers in Silicon , 1971 .

[42]  S. Wang,et al.  Low−temperature irradiation effects in SiO2−insulated MIS devices , 1975 .

[43]  C. N. Berglund,et al.  Photoinjection Studies of Charge Distributions in Oxides of MOS Structures , 1971 .

[44]  A. Goodman,et al.  Photoemission of Electrons from Silicon and Gold into Silicon Dioxide , 1966 .

[45]  Richard H. Bube,et al.  Electric Field Effects in Trapping Processes , 1966 .

[46]  J. F. Verwey,et al.  Nonavalanche injection of hot carriers into SiO2 , 1973 .

[47]  E. Loh Ultraviolet reflectance of Al2O3, SiO2 and BeO , 1964 .

[48]  D. M. Boulin,et al.  Interfacial dopants for dual-dielectric, charge-storage cells , 1974 .

[49]  K. Thornber,et al.  Electron‐electron effects in the writing and erasing of dual‐dielectric charge‐storage cells , 1978 .

[50]  J. S. Blakemore Radiative Capture by Impurities in Semiconductors , 1967 .

[51]  A. Goodman,et al.  Photoemission of Electrons fromn-Type Degenerate Silicon into Silicon Dioxide , 1966 .

[52]  E. P. EerNisse,et al.  Viscous Shear Flow Model for MOS Device Radiation Sensitivity , 1976, IEEE Transactions on Nuclear Science.

[53]  J. H. Thomas,et al.  Spectrally resolved photo depopulation of electron trapping defects in amorphous silica films , 1970 .

[54]  Z. Weinberg,et al.  Tunneling of electrons from Si into thermally grown SiO2 , 1977 .

[55]  D. Dimaria Room‐temperature conductivity and location of mobile sodium ions in the thermal silicon dioxide layer of a metal–silicon dioxide–silicon structure , 1977 .

[56]  W. C. Johnson,et al.  High‐field transport in SiO2 on silicon induced by corona charging of the unmetallized surface , 1976 .

[57]  R. Powell Photoinjection into SiO2: Use of Optical Interference to Determine Electron and Hole Contributions , 1969 .

[58]  D. Eastman,et al.  The band edge of amorphous SiO2 by photoinjection and photoconductivity measurements , 1971 .

[59]  C. N. Berglund,et al.  Photoinjection into SiO2: Electron Scattering in the Image Force Potential Well , 1971 .

[60]  A. Goodman,et al.  Photoemission of Holes from Silicon into Silicon Dioxide , 1966 .

[61]  Z. Weinberg,et al.  Hole injection and transport in SiO2 films on Si , 1975 .

[62]  P. Solomon,et al.  Current and C-V Instabilities in Si02 at High Fields , 1977 .

[63]  P. Arnett,et al.  Silicon nitride trap properties as revealed by charge−centroid measurements on MNOS devices , 1975 .

[64]  G. F. Derbenwick,et al.  Vacuum Ultraviolet Radiation Effects in SiO2 , 1971 .

[65]  B. Yun,et al.  Measurements of charge propagation in Si3N4 films , 1974 .

[66]  D. Dimaria,et al.  Conduction studies in silicon nitride: dark currents and photocurrents , 1977 .

[67]  H. E. Boesch,et al.  Hole Transport and Recovery Characteristics of SiO2 Gate Insulators , 1976, IEEE Transactions on Nuclear Science.

[68]  J. R. Srour,et al.  The multiple‐trapping model and hole transport in SiO2 , 1977 .

[69]  A. Hartstein,et al.  Photon assisted tunneling from aluminum into silicon dioxide , 1976 .

[70]  H. E. Boesch,et al.  Application of stochastic hopping transport to hole conduction in amorphous SiO2 , 1976 .

[71]  D. Lang,et al.  Nonradiative capture and recombination by multiphonon emission in GaAs and GaP , 1977 .

[72]  N. Klein,et al.  Electroluminescence at high fields in silicon dioxide , 1976 .

[73]  D. Dimaria,et al.  Determination of insulator bulk trapped charge densities and centroids from photocurrent‐voltage charactersitcs of MOS structures , 1976 .

[74]  D. W. Ormond,et al.  Use of electron‐trapping region to reduce leakage currents and improve breakdown characteristics of MOS structures , 1977 .

[75]  J. F. Verwey,et al.  Hole Currents in Thermally Grown SiO2 , 1972 .

[76]  M. H. Woods,et al.  Hole traps in silicon dioxide , 1976 .

[77]  Chih-Tang Sah,et al.  Thermal emission and capture of electrons at sulfur centers in silicon , 1970 .

[78]  R. Poirier,et al.  Charge storage in SiO2 under low‐energy electron bombardment , 1974 .

[79]  G. Ascarelli,et al.  Recombination of Electrons and Donors in n-Type Germanium , 1960 .

[80]  R. C. Hughes Time-resolved hole transport in a-SiO/sub 2/ , 1977 .

[81]  D. R. Young,et al.  Avalanche Injection of Holes into SiO2 , 1977, IEEE Transactions on Nuclear Science.

[82]  Tak H. Ning,et al.  High‐field capture of electrons by Coulomb‐attractive centers in silicon dioxide , 1976 .

[83]  Carlton M. Osburn,et al.  Effect of electron trapping on IGFET characteristics , 1977 .

[84]  J. M. Aitken,et al.  Location of positive charges in SiO2 films on Si generated by vuv photons, x rays, and high‐field stressing , 1977 .

[85]  R. Powell On the determination of charge centroids in insulators by photoinjection or photodepopulation , 1977 .

[86]  J. M. Andrews,et al.  Electrochemical Charging of Thermal SiO2 Films by Injected Electron Currents , 1971 .

[87]  Melvin Lax,et al.  Cascade Capture of Electrons in Solids , 1960 .

[88]  Oxide thickness dependence of high‐energy‐electron‐, VUV‐, and corona‐induced charge in MOS capacitors , 1976 .

[89]  D. Dimaria,et al.  Trap ionization by electron impact in amorphous SiO2 films , 1974 .

[90]  D. Dimaria,et al.  Photocurent spectroscopy in thin-film insulators: Voltage dependence of the external-circuit current , 1974 .

[91]  D. R. Young,et al.  Electron Injection Studies of Radiation Induced Positive Charge in MOS Devices , 1976, IEEE Transactions on Nuclear Science.

[92]  S. R. Butler,et al.  Energy and spatial distribution of an electron trapping center in the MOS insulator , 1977 .