Determination of manganese in seawater using flow injection analysis with on-line preconcentration and spectrophotometric detection

A highly sensitive method for the rapid determination of dissolved Mn(II) and total dissolvable Mn in seawater has been developed. The method uses on-line concentraion of Mn(II) onto 8-hydroxyquinoline immobilized onto a vinyl polymer gel. The Mn(II) is then eluted from the gel by acid and its concentration determined by spectrophotometric detection of the malachite green formed from the reaction of leucomalachite green and potassium periodate with Mn(II) acting as a catalyst

[1]  S. Willie,et al.  Determination of trace metals in seawater by inductively coupled plasma mass spectrometry with preconcentration on silica-immobilized 8-hydroxyquinoline , 1985 .

[2]  J. Ólafsson The semi-automated determination of manganese in sea water with leuco-malachite green , 1986 .

[3]  J. D. Burton,et al.  Dissolved manganese in the North Atlantic Ocean, 0–35°N , 1986 .

[4]  J. H. Martin,et al.  Lateral transport of Mn in the north-east Pacific Gyre oxygen minimum , 1985, Nature.

[5]  K. Hirayama,et al.  Spectrophotometric catalytic determination of an ultratrace amount of iron(III) in water based on the oxidation of N,N-dimethyl-p-phenylenediamine by hydrogen peroxide , 1988 .

[6]  Y. Sakai,et al.  Preconcentration of cobalt with N-(dithiocarboxy)sarcosine and amberlite xad-4 resin. , 1986, Talanta.

[7]  F. Cantwell,et al.  Determination of free magnesium ion concentration in aqueous solution using 8-hydroxyquinoline immobilized on a nonpolar adsorbent , 1992 .

[8]  R. Sturgeon,et al.  Preconcentration of trace elements from seawater with silica-immobilized 8-hydroxyquinoline , 1981 .

[9]  J. Lupton Water column hydrothermal plumes on the Juan de Fuca Ridge , 1990 .

[10]  V. Hodge,et al.  Influence of atmospherically transported aerosols on surface ocean water composition , 1978 .

[11]  M. Otto,et al.  Optimized spectrophotometric determination of trace cobalt and manganese by their catalysis of the tiron—hydrogen peroxide reaction , 1983 .

[12]  G. Topping Quality of data: With special reference to the measurement of trace metals in marine samples , 1986 .

[13]  Ray F. Weiss,et al.  Chemistry of submarine hydrothermal solutions at 21 °N, East Pacific Rise , 1985 .

[14]  J. E. Riley Contamination-free adjustment of pH during trace analysis , 1978 .