Assessment of elemental pollution in soil of Islamabad city using instrumental neutron activation analysis and atomic absorption spectrometry techniques

Abstract The soil samples of nine different sites in Islamabad were studied for their elemental composition. Instrumental neutron activation analysis and atomic absorption spectrometry were employed and 33 elements were determined. The acquired data were analyzed using descriptive statistics, principal component analysis, cluster analysis, pollution level index and enrichment factor. A perusal of results shows a distribution of elemental concentration in two major groups, one along the highway and the other in industrial area of Islamabad. The soil along the highway sites was found to be relatively less polluted than at the sites in the industrial area. The enrichment factor indicates the presence of As, Pb, Sb, Se and Sn at higher levels. The method validation was done by analyzing IAEA reference materials SL-1 (lake sediment) and S7 (soil).

[1]  Paul Geladi,et al.  Principal Component Analysis , 1987, Comprehensive Chemometrics.

[2]  N. Khalid,et al.  Potential of Broussonetia papyrifera leaves as biomonitors for atmospheric pollution: use of INAA and AAS techniques , 2006 .

[3]  C. Micó,et al.  Assessing heavy metal sources in agricultural soils of an European Mediterranean area by multivariate analysis. , 2006, Chemosphere.

[4]  P. Madejón,et al.  Biomonitoring of trace elements in the leaves and fruits of wild olive and holm oak trees. , 2006, The Science of the total environment.

[5]  Paola Gramatica,et al.  Analysis of Mosses and Soils for Quantifying Heavy Metal Concentrations in Sicily: A Multivariate and Spatial Analytical Approach , 2006, Environmental science and pollution research international.

[6]  H. Poggi‐Varaldo,et al.  A multivariate analysis of the accumulation and fractionation of major and trace elements in agricultural soils in Hidalgo State, Mexico irrigated with raw wastewater. , 2005, Environment international.

[7]  David E. Booth,et al.  Chemometrics: Data Analysis for the Laboratory and Chemical Plant , 2004, Technometrics.

[8]  M. Wasim,et al.  INAA for the characterization of airborne particulate matter from the industrial area of Islamabad city , 2003 .

[9]  Domy C. Adriano,et al.  Trace Elements in Terrestrial Environments: Biogeochemistry, Bioavailability, and Risks of Metals , 2001 .

[10]  Eric R. Ziegel,et al.  Handbook of Chemometrics and Qualimetrics, Part B , 2000, Technometrics.

[11]  J. Einax,et al.  GEOSTATISTICAL AND MULTIVARIATE STATISTICAL METHODS FOR THE ASSESSMENT OF POLLUTED SOILS : MERITS AND LIMITATIONS , 1999 .

[12]  E. Miguel,et al.  Origin and patterns of distribution of trace elements in street dust: Unleaded petrol and urban lead , 1997 .

[13]  I. Maiz,et al.  Heavy metal contamination analysis of roadsoils and grasses from gipuzkoa (Spain) , 1996 .

[14]  B. Mason Principles of geochemistry , 1958 .