Micromorph thin-film silicon solar cells with transparent high-mobility hydrogenated indium oxide front electrodes

We investigate the performance of hydrogenated indium oxide as a transparent front electrode for micromorph thin-film silicon solar cells on glass. Light trapping is achieved by replicating the morphology of state-of-the-art zinc oxide electrodes, known for their outstanding light trapping properties, via ultraviolet nanoimprint lithography. As a result of the high electron mobility and excellent near-infrared transparency of hydrogenated indium oxide, the short-circuit current density of the cells is improved with respect to indium tin oxide and zinc oxide electrodes. We assess the potential for further current gains by identifying remaining sources of parasitic absorption and evaluate the light trapping capacity of each electrode. We further present a method, based on nonabsorbing insulating silicon nitride electrodes, allowing one to directly relate the optical reflectance to the external quantum efficiency. Our method provides a useful experimental tool to evaluate the light trapping potential of novel photonic nanostructures by a simple optical reflectance measurement, avoiding complications with electrical cell performance.

[1]  Christophe Ballif,et al.  UV‐nano‐imprint lithography technique for the replication of back reflectors for n‐i‐p thin film silicon solar cells , 2011 .

[2]  C. Ballif,et al.  Control of LPCVD ZnO growth modes for improved light trapping in thin film silicon solar cells , 2011 .

[3]  C. Battaglia,et al.  High fidelity transfer of nanometric random textures by UV embossing for thin film solar cells applications , 2011 .

[4]  C. Battaglia,et al.  Nanoimprint lithography for high-efficiency thin-film silicon solar cells. , 2011, Nano letters.

[5]  D. W. Sheel,et al.  Control of tin oxide film morphology by addition of hydrocarbons to the chemical vapour deposition process , 2010 .

[6]  C. Ballif,et al.  Mixed-phase p-type silicon oxide containing silicon nanocrystals and its role in thin-film silicon solar cells , 2010 .

[7]  C. Battaglia,et al.  Unlinking absorption and haze in thin film silicon solar cells front electrodes , 2010 .

[8]  F. Lederer,et al.  Comparison and optimization of randomly textured surfaces in thin-film solar cells. , 2010, Optics express.

[9]  Arvind Shah,et al.  Thin-Film Silicon Solar Cells , 2010 .

[10]  Sumei Huang,et al.  Influence of working pressure on ZnO:Al films from tube targets for silicon thin film solar cells , 2010 .

[11]  C. Battaglia,et al.  Efficient light management scheme for thin film silicon solar cells via transparent random nanostructures fabricated by nanoimprinting , 2010 .

[12]  Ihsanul Afdi Yunaz,et al.  ZnO Films with Very High Haze Value for Use as Front Transparent Conductive Oxide Films in Thin-Film Silicon Solar Cells , 2010 .

[13]  J. Hüpkes,et al.  Rough glass by 3d texture transfer for silicon thin film solar cells , 2010 .

[14]  M. Zeman,et al.  Light scattering properties of surface-textured substrates , 2010 .

[15]  M. Kondo,et al.  Application of hydrogen-doped In2O3 transparent conductive oxide to thin-film microcrystalline Si solar cells , 2010 .

[16]  C. Ballif,et al.  Resistive interlayer for improved performance of thin film silicon solar cells on highly textured substrate , 2010 .

[17]  C. Battaglia,et al.  Modeling of light scattering from micro- and nanotextured surfaces , 2010 .

[18]  H. Fujiwara,et al.  Hydrogen-doped In2O3 transparent conducting oxide films prepared by solid-phase crystallization method , 2010 .

[19]  Christophe Ballif,et al.  Influence of the substrate geometrical parameters on microcrystalline silicon growth for thin-film solar cells , 2009 .

[20]  A. Aberle Thin-film solar cells , 2009 .

[21]  Bernd Rech,et al.  Recent development on surface-textured ZnO:Al films prepared by sputtering for thin-film solar cell application , 2008 .

[22]  H. Fujiwara,et al.  Reduction of Optical Loss in Hydrogenated Amorphous Silicon/Crystalline Silicon Heterojunction Solar Cells by High-Mobility Hydrogen-Doped In2O3 Transparent Conductive Oxide , 2008 .

[23]  Christophe Ballif,et al.  Opto-electronic properties of rough LP-CVD ZnO:B for use as TCO in thin-film silicon solar cells , 2007 .

[24]  P. Buehlmann,et al.  In situ silicon oxide based intermediate reflector for thin-film silicon micromorph solar cells , 2007 .

[25]  H. Fujiwara,et al.  Hydrogen-doped In2O3 as High-mobility Transparent Conductive Oxide , 2007 .

[26]  Bernd Rech,et al.  The effect of front ZnO:Al surface texture and optical transparency on efficient light trapping in silicon thin-film solar cells , 2007 .

[27]  C. Ballif,et al.  Transition between grain boundary and intragrain scattering transport mechanisms in boron-doped zinc oxide thin films , 2007 .

[28]  H. Fujiwara,et al.  Interface-layer formation in microcrystalline Si:H growth on ZnO substrates studied by real-time spectroscopic ellipsometry and infrared spectroscopy , 2003 .

[29]  B. Drévillon,et al.  A real time ellipsometry study of the growth of amorphous silicon on transparent conducting oxides , 1989 .

[30]  S. Ishihara,et al.  Interaction of hydrogenated amorphous silicon films with transparent conductive films , 1983 .

[31]  J. J. Hanak Monolithic solar cell panel of amorphous silicon , 1979 .