Exploring Potential Methods for Anchoring Amine Groups on the Surface of Activated Carbon for CO2 Adsorption

Activated carbon can be effectively modified for CO2 adsorption with amine groups due to their high affinity for CO2. Using approaches such as impregnation, some modifiers containing amine groups are physically adsorbed on the surface of carbon, whereas other amine groups can be directly or indirectly chemically bound to the activated carbon matrix. In the context of exploring potential techniques for grafting amine groups onto activated carbon surfaces, we herein review the literature on modifications applied to different materials and supports for a variety of applications, limited to neither activated carbon nor CO2-adsorption applications. We focus on the processes of grafting amine groups and the parameters influencing these processes. Moreover, the mechanism of CO2 adsorption involving amine groups is discussed.

[1]  P. Taylor,et al.  Alkenes and aromatics , 2002 .

[2]  Covadonga Pevida,et al.  CO2 capture by adsorption with nitrogen enriched carbons , 2007 .

[3]  W. Daud,et al.  Adsorption capacities of carbon dioxide, oxygen, nitrogen and methane on carbon molecular basket derived from polyethyleneimine impregnation on microporous palm shell activated carbon , 2008 .

[4]  A. Ramos,et al.  OXYDEHYDROGENATION OF CYCLOHEXANOL OVER CARBON CATALYSTS , 1998 .

[5]  J. Choma,et al.  KOH activation of mesoporous carbons obtained by soft-templating , 2008 .

[6]  A. Walcarius,et al.  Electrochemical evaluation of polysiloxane-immobilized amine ligands for the accumulation of copper(II) species , 1999 .

[7]  Z. Li,et al.  Surface modification and functionalization through the self-assembled monolayer and graft polymerization. , 2005, Advances in colloid and interface science.

[8]  S. Biniak,et al.  The characterization of activated carbons with oxygen and nitrogen surface groups , 1997 .

[9]  C. Airoldi,et al.  New amino-inorganic hybrids from talc silylation and copper adsorption properties , 2001 .

[10]  J. J. Pis,et al.  Surface modification of activated carbons for CO2 capture , 2008 .

[11]  H. Tamai,et al.  Adsorption of methyl mercaptan on surface modified activated carbon. , 2006, Journal of colloid and interface science.

[12]  Park,et al.  A Hyperbranched Poly(ethyleneimine) Grown on Surfaces. , 2000, Journal of colloid and interface science.

[13]  Tae-Wan Kim,et al.  Functionalized mesoporous organic-inorganic hybrids through pore surface-restricted post-polymerization , 2007 .

[14]  T. Fukutsuka,et al.  Silylation of graphite oxide , 2004 .

[15]  T. Bandosz,et al.  Role of surface chemistry in adsorption of phenol on activated carbons. , 2003, Journal of colloid and interface science.

[16]  S. Biniak,et al.  Influence of the surface chemistry of modified activated carbon on its electrochemical behaviour in the presence of lead(II) ions , 2004 .

[17]  T. Yashima,et al.  Adsorption of carbon dioxide on modified mesoporous materials in the presence of water vapor , 2004 .

[18]  T. Bandosz,et al.  A Study of Acetaldehyde Adsorption on Activated Carbons , 2001 .

[19]  Zhong Tang,et al.  Sorbents for CO2 capture from high carbon fly ashes. , 2008, Waste management.

[20]  A. A. El-Hendawy Influence of HNO3 oxidation on the structure and adsorptive properties of corncob-based activated carbon , 2003 .

[21]  J. Clark,et al.  Organo-functionalized activated carbons as supports for the covalent attachment of a chiral manganese(III) salen complex , 2007 .

[22]  P. Samaras,et al.  Effect of activated carbons modification on porosity, surface structure and phenol adsorption. , 2008, Journal of hazardous materials.

[23]  C. Airoldi,et al.  Preparation of ethylenediamine-anchored cellulose and determination of thermochemical data for the interaction between cations and basic centers at the solid/liquid interface. , 2006, Carbohydrate research.

[24]  T. Bandosz,et al.  Surface Chemistry of Activated Carbons: Combining the Results of Temperature-Programmed Desorption, Boehm, and Potentiometric Titrations. , 2001, Journal of colloid and interface science.

[25]  T. Fukutsuka,et al.  Removal of formaldehyde from gas phase by silylated graphite oxide containing amino groups , 2008 .

[26]  P. Magri,et al.  Characterization of surface properties of nitrogen-enriched activated lignites by spectroscopic and chromatographic coupled with LSER modelling measurements , 2002 .

[27]  Michael Streat,et al.  Characterisation of the surface of oxidised carbon adsorbents , 2002 .

[28]  T. Bandosz,et al.  Adsorption of valeric acid from aqueous solution onto activated carbons: role of surface basic sites. , 2004, Journal of colloid and interface science.

[29]  S. Biniak,et al.  Effect of Activated Carbon Surface Oxygen- and/or Nitrogen-Containing Groups on Adsorption of Copper(II) Ions from Aqueous Solution† , 1999 .

[30]  Airoldi,et al.  Ethyleneimine Anchored on Thiol-Modified Silica Gel Surface-Adsorption of Divalent Cations and Calorimetric Data. , 2000, Journal of colloid and interface science.

[31]  H. Boehm.,et al.  Some aspects of the surface chemistry of carbon blacks and other carbons , 1994 .

[32]  H. V. Bekkum,et al.  Amination and ammoxidation of activated carbons , 1994 .

[33]  C. S. M. Lecea,et al.  Catalytic properties of a Rh–diamine complex anchored on activated carbon: Effect of different surface oxygen groups , 2007 .

[34]  T. Yashima,et al.  Reversible Adsorption of Carbon Dioxide on Amine-Modified SBA-15 from Flue Gas Containing Water Vapor , 2004 .

[35]  V. Zeleňák,et al.  Functionalised micro-/mesoporous silica for the adsorption of carbon dioxide , 2007 .

[36]  Colin E. Snape,et al.  CO2 capture using some fly ash-derived carbon materials , 2005 .

[37]  Rafael García,et al.  Catalytic wet air oxidation of aqueous ammonia with activated carbon , 2003 .

[38]  Zhong Tang,et al.  CO2 capture by activated and impregnated anthracites , 2005 .

[39]  T. Fukutsuka,et al.  Preparation and characterization of silylated graphite oxide , 2005 .

[40]  Kechang Xie,et al.  Adsorption of Carbon Dioxide on Activated Carbon , 2006 .

[41]  M. Takaoka,et al.  The effect of treatment of activated carbon by H2O2 or HNO3 on the decomposition of pentachlorobenzene , 2007 .

[42]  Christian L. Mangun,et al.  Surface chemistry, pore sizes and adsorption properties of activated carbon fibers and precursors treated with ammonia , 2001 .

[43]  F. Owens,et al.  Electrochemical nitration of single-wall carbon nanotubes , 2005 .

[44]  José L. Figueiredo,et al.  The effects of different activated carbon supports and support modifications on the properties of Pt/AC catalysts , 2001 .

[45]  J. Bimer Modified active carbons from precursors enriched with nitrogen functions: Sulfur removal capabilities , 1998 .

[46]  J. Figueiredo,et al.  Catalytic properties of carbon materials for wet oxidation of aniline. , 2008, Journal of hazardous materials.

[47]  Yuehe Lin,et al.  Selective Removal of Copper(II) from Aqueous Solutions Using Fine-Grained Activated Carbon Functionalized with Amine , 2004 .

[48]  T. Fukutsuka,et al.  Introduction of amino groups into the interlayer space of graphite oxide using 3-aminopropylethoxysilanes , 2007 .

[49]  M. Fonseca,et al.  Silylated calcium phosphates and their new behavior for copper retention from aqueous solution , 2007 .

[50]  Tao Zhang,et al.  CO2 adsorption on SBA-15 modified by aminosilane , 2007 .

[51]  Araki,et al.  Removal of Formaldehyde by Activated Carbons Containing Amino Groups. , 1999, Journal of colloid and interface science.

[52]  C. Airoldi,et al.  Some features associated with organosilane groups grafted by the sol-gel process onto synthetic talc-like phyllosilicate. , 2006, Journal of colloid and interface science.

[53]  J. J. Pis,et al.  Surface modification of low cost carbons for their application in the environmental protection , 2005 .

[54]  Mohammadhosein Safari,et al.  Adsorption of carbon dioxide using impregnated activated carbon promoted by Zinc , 2009 .

[55]  Robert W. Stevens,et al.  CO2 capture by amine-enriched fly ash carbon sorbents , 2004 .

[56]  C. Ruiz,et al.  Functionalization of ordered mesoporous carbons synthesized with SBA-15 silica as template , 2007 .

[57]  Yao Shi,et al.  Thermal and hydrothermal stability of amino-functionalized SBA-16 and promotion of hydrophobicity by silylation , 2009 .

[58]  Covadonga Pevida,et al.  Preparation of carbon dioxide adsorbents from the chemical activation of urea–formaldehyde and melamine–formaldehyde resins , 2007 .

[59]  B. Deng,et al.  Enhanced mercury ion adsorption by amine-modified activated carbon. , 2009, Journal of hazardous materials.

[60]  E. Halliop,et al.  Acidic and basic sites on the surface of porous carbon , 1997 .

[61]  Sung Ju Cho,et al.  Hyperbranching polymerization of aziridine on silica solid substrates leading to a surface of highly dense reactive amine groups. , 2003, Journal of colloid and interface science.

[62]  F. Carrasco-Marín,et al.  Changes in surface chemistry of activated carbons by wet oxidation , 2000 .

[63]  J. Silvestre-Albero,et al.  Liquid phase removal of propanethiol by activated carbon: Effect of porosity and functionality , 2007 .

[64]  Amine grafted, pore-expanded MCM–41 for acid gas removal: Effect of grafting temperature, water, and amine type on performance , 2005 .

[65]  E. Sacher,et al.  The surface analytical characterization of carbon fibers functionalized by H2SO4/HNO3 treatment , 2008 .

[66]  J. Figueiredo,et al.  Immobilisation of amine-functionalised nickel(II) Schiff base complexes onto activated carbon treated with thionyl chloride , 2002 .

[67]  Satoshi Kodama,et al.  Surface modification of adsorbents by dielectric barrier discharge , 2002 .

[68]  Ke-wei Zhang,et al.  Amino functionalization and characteristics of multi-walled carbon nanotube/poly(methyl methacrylate) nanocomposite , 2009 .

[69]  A. Lua,et al.  Characterization of adsorbent prepared from oil-palm shell by CO2 activation for removal of gaseous pollutants , 2002 .

[70]  S. Ryu,et al.  Physical and chemical characteristics of multiwalled carbon nanotubes functionalized with aminosilane and its influence on the properties of natural rubber composites , 2007 .

[71]  J. A. Menéndez,et al.  On the nature of basic sites on carbon surfaces: an overview , 2004 .

[72]  Katsunori Yogo,et al.  Adsorption characteristics of carbon dioxide on organically functionalized SBA-15 , 2005 .

[73]  J. Figueiredo,et al.  Characterization of the surface chemistry of carbon materials by potentiometric titrations and temperature-programmed desorption , 2008 .

[74]  P. Zappelli,et al.  Solid Sorbents for the Reversible Capture of Carbon Dioxide , 2003 .

[75]  G. P. Knowles,et al.  Aminopropyl-functionalized mesoporous silicas as CO2 adsorbents , 2005 .

[76]  J. A. Menéndez,et al.  Bituminous coal-based activated carbons modified with nitrogen as adsorbents of hydrogen sulfide , 2004 .

[77]  Jun Zhang,et al.  CO2 capture by adsorption: Materials and process development , 2007 .

[78]  Enes Şayan Ultrasound-assisted preparation of activated carbon from alkaline impregnated hazelnut shell: An optimization study on removal of Cu2+ from aqueous solution , 2006 .

[79]  K. Xie,et al.  Study of the behavior of adsorbing CS2 by activated carbon , 2006 .

[80]  C. Pittman,et al.  Titration of tetraethylenepentamine (TEPA) and its phenyl isocyanate reaction products: A model correction factor for determination of TEPA grafted to carbon surfaces , 1997 .

[81]  Daniel Chinn,et al.  Amine-Grafted MCM-48 and Silica Xerogel as Superior Sorbents for Acidic Gas Removal from Natural Gas , 2003 .

[82]  K. Wilson,et al.  The influence of surface functionalization of activated carbon on palladium dispersion and catalytic activity in hydrogen oxidation , 2008 .

[83]  Yao Shi,et al.  Adsorption of carbon dioxide on organically functionalized SBA-16 , 2008 .

[84]  Zhihong Wu,et al.  Reactivities of amine functions grafted to carbon fiber surfaces by tetraethylenepentamine. Designing interfacial bonding , 1997 .

[85]  P. Burg,et al.  The characterization of nitrogen-enriched activated carbons by IR, XPS and LSER methods , 2002 .

[86]  T. Grzybek,et al.  Influence of nitrogen surface functionalities on the catalytic activity of activated carbon in low temperature SCR of NOx with NH3 , 2004 .

[87]  M. Shaffer,et al.  Silylation of multi-walled carbon nanotubes , 2003 .

[88]  J. Andresen,et al.  Preparation and characterization of novel CO2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41 , 2003 .

[89]  D. Wurster,et al.  Phenobarbital interactions with derivatized activated carbon surfaces. , 2006, Journal of colloid and interface science.

[90]  H. Tseng,et al.  Effects of acid treatments of activated carbon on its physiochemical structure as a support for copper oxide in DeSO(2) reaction catalysts. , 2006, Chemosphere.

[91]  C. Pittman,et al.  Chemical modification of carbon fiber surfaces by nitric acid oxidation followed by reaction with tetraethylenepentamine , 1997 .

[92]  Jiango Li,et al.  Surface functionalization and characterization of graphitic carbon nanofibers (GCNFs) , 2005 .

[93]  P. Dumas,et al.  Organosilane-modified maghemite nanoparticles and their use as co-initiator in the ring-opening polymerization of ɛ-caprolactone , 2005 .

[94]  S. Biniak,et al.  Effect of properties of chemically modified activated carbon and aromatic adsorbate molecule on adsorption from liquid phase , 2008 .

[95]  F. Kapteijn,et al.  The development of nitrogen functionality in model chars during gasification in CO2 and O2 , 1999 .

[96]  A. Cukierman,et al.  In situ modification of activated carbons developed from a native invasive wood on removal of trace toxic metals from wastewater. , 2009, Journal of hazardous materials.

[97]  B. Saha,et al.  Surface modification and characterisation of a coal-based activated carbon , 2005 .

[98]  Z. Iqbal,et al.  Functionalization of carbon nanotubes with amines and enzymes , 2005 .

[99]  C. Ania,et al.  Chapter 4 Surface chemistry of activated carbons and its characterization , 2006 .

[100]  A. G. Prado,et al.  Thermodynamic studies of the interaction at the solid/liquid interface between metal ions and cellulose modified with ethylenediamine. , 2006, Journal of hazardous materials.

[101]  Xiaobing Li,et al.  Functionalization of carbon nanofibers with diamine and polyimide oligmer , 2008 .

[102]  H. Tamai,et al.  Surface functionalization of mesoporous and microporous activated carbons by immobilization of diamine. , 2006, Journal of colloid and interface science.

[103]  R. Wakeman,et al.  Effect of surface modification of an engineered activated carbon on the sorption of 2,4-dichlorophenoxy acetic acid and benazolin from water. , 2006, Journal of colloid and interface science.