Optical portable instrument for the determination of CO2 in indoor environments.

A portable device based on a colorimetric sensor to determine the atmospheric level of CO2 gas is presented in this work. The system is based on a low-cost, low-power System on a Chip (SoC) microcontroller with integrated Wi-Fi. A user-friendly application was developed to monitor and log the CO2 measurements when the system is connected to a Wi-Fi network. The sensing membrane is directly deposited on the surface of the colour detector, thus reducing the complexity of the system. This sensing membrane is formed by a pH indicator α-naphtholphthalein, tetramethylammonium hydroxide pentahydrate, 1-ethyl-3-methylimidazolium tetrafluoroborate, Tween 20 and hydroxypropyl methylcellulose as the hydrophilic polymer. The system has been fully characterized, obtaining response and recovery times of 1.3 and 2.5 s, respectively, a limit of detection of 51 ppm, and an average resolution of 6.3 ppm. This portable device was applied for the in-situ determination of CO2 gas in the atmosphere inside classrooms in several secondary schools. The measurements were taken during complete workdays and the results were statistically compared with the same measurements taken using a commercially available non-dispersive infra-red (NDIR) device. No significant statistical differences were found between the results obtained using both devices. A complete statistical treatment of the measurements made with the proposed portable device was carried out. The obtained results show that the concentration of CO2 gas in some schools was higher than the desired concentration, with regard to influencing the student's health, safety, productivity and comfort. This demonstrates the need to control this parameter to ensure appropriate indoor environmental quality (IEQ).

[1]  Andrew Mills,et al.  Equilibrium studies on colorimetric plastic film sensors for carbon dioxide , 1992 .

[2]  Gerhard P. Hancke,et al.  Air Quality Monitoring System Based on ISO/IEC/IEEE 21451 Standards , 2016, IEEE Sensors Journal.

[3]  Itziar G. Alonso-González,et al.  A Low Cost Wireless Acoustic Sensor for Ambient Assisted Living Systems , 2017 .

[4]  Gerhard P. Hancke,et al.  Energy Efficient Environment Monitoring System Based on the IEEE 802.15.4 Standard for Low Cost Requirements , 2014, IEEE Sensors Journal.

[5]  William W. Nazaroff,et al.  Real-time monitoring of personal exposures to carbon dioxide , 2016 .

[6]  Gonçalo Marques,et al.  An Indoor Monitoring System for Ambient Assisted Living Based on Internet of Things Architecture , 2016, International journal of environmental research and public health.

[7]  Grant R. McKercher,et al.  Characteristics and applications of small, portable gaseous air pollution monitors. , 2017, Environmental pollution.

[8]  Marek Tobiszewski,et al.  Current air quality analytics and monitoring: a review. , 2015, Analytica chimica acta.

[9]  Jacek Namieśnik,et al.  Moving your laboratories to the field--Advantages and limitations of the use of field portable instruments in environmental sample analysis. , 2015, Environmental research.

[10]  Alberto J. Palma,et al.  Hand-held optical instrument for CO2 in gas phase based on sensing film coating optoelectronic elements , 2010 .

[11]  Xinrong Li,et al.  A Cost-effective Wireless Sensor Network System for Indoor Air Quality Monitoring Applications , 2014, FNC/MobiSPC.

[12]  L. Capitán-Vallvey,et al.  Ionic liquids on optical sensors for gaseous carbon dioxide , 2018, Analytical and Bioanalytical Chemistry.

[13]  Optical sensor for carbon dioxide gas determination, characterization and improvements. , 2014, Talanta.

[14]  I. Annesi-Maesano,et al.  Indoor Air Quality and Sources in Schools and Related Health Effects , 2013, Journal of toxicology and environmental health. Part B, Critical reviews.

[15]  Jian Zhou,et al.  Measurement of air exchange rates in different indoor environments using continuous CO2 sensors. , 2012, Journal of environmental sciences.

[16]  L. Capitán-Vallvey,et al.  A new light emitting diode-light emitting diode portable carbon dioxide gas sensor based on an interchangeable membrane system for industrial applications. , 2011, Analytica chimica acta.

[17]  Liping Wang,et al.  Continuous monitoring of indoor environmental quality using an Arduino-based data acquisition system , 2018, Journal of Building Engineering.

[18]  Guillermo Orellana,et al.  Enhanced performance of a fibre-optic luminescence CO2 sensor using carbonic anhydrase , 1995 .

[19]  Francis Tsow,et al.  A Novel Real-time Carbon Dioxide Analyzer for Health and Environmental Applications. , 2014, Sensors and actuators. B, Chemical.

[20]  Hui Zhang,et al.  Partial- and whole-body thermal sensation and comfort— Part I: Uniform environmental conditions , 2006 .

[21]  L. Al-Awadi,et al.  Comparison of indoor air quality in schools: Urban vs. Industrial 'oil & gas' zones in Kuwait , 2017 .

[22]  Yuriy Vagapov,et al.  Comparative analysis and practical implementation of the ESP32 microcontroller module for the internet of things , 2017, 2017 Internet Technologies and Applications (ITA).

[23]  Jung-Yoon Kim,et al.  ISSAQ: An Integrated Sensing Systems for Real-Time Indoor Air Quality Monitoring , 2014, IEEE Sensors Journal.

[24]  Brent Stephens,et al.  Open Source Building Science Sensors (OSBSS): A low-cost Arduino-based platform for long-term indoor environmental data collection , 2016 .

[25]  J. Namieśnik,et al.  The State of the Art in the Field of Non-Stationary Instruments for the Determination and Monitoring of Atmospheric Pollutants , 2008 .

[26]  Ralph P. Tatam,et al.  Non-dispersive infra-red (NDIR) measurement of carbon dioxide at 4.2μm in a compact and optically efficient sensor , 2013 .

[27]  San-Shan Hung,et al.  A Portable Array-Type Optical Fiber Sensing Instrument for Real-Time Gas Detection , 2016, Sensors.