Influence of pyrolysis temperature on production and nutrient properties of wastewater sludge biochar.

The important challenge for effective management of wastewater sludge materials in an environmentally and economically acceptable way can be addressed through pyrolytic conversion of the sludge to biochar and agricultural applications of the biochar. The aim of this work is to investigate the influence of pyrolysis temperature on production of wastewater sludge biochar and evaluate the properties required for agronomic applications. Wastewater sludge collected from an urban wastewater treatment plant was pyrolysed in a laboratory scale reactor. It was found that by increasing the pyrolysis temperature (over the range from 300 °C to 700 °C) the yield of biochar decreased. Biochar produced at low temperature was acidic whereas at high temperature it was alkaline in nature. The concentration of nitrogen was found to decrease while micronutrients increased with increasing temperature. Concentrations of trace metals present in wastewater sludge varied with temperature and were found to primarily enriched in the biochar.

[1]  V. Strezov,et al.  Thermal processing of paper sludge and characterisation of its pyrolysis products. , 2009, Waste management.

[2]  F. Magdoff,et al.  Nitrogen mineralization from sewage sludge , 1977 .

[3]  Julia W. Gaskin,et al.  Effect of Low-Temperature Pyrolysis Conditions on Biochar for Agricultural Use , 2008 .

[4]  M. McBride Toxic metal accumulation from agricultural use of sludge: are USEPA regulations protective? , 1995 .

[5]  R. Singh,et al.  Potential benefits and risks of land application of sewage sludge. , 2008, Waste management.

[6]  M. D. Clark,et al.  The effect of temperature on decomposition at optimum and saturated soil water contents , 1983 .

[7]  J. Lehmann,et al.  Biochar for Environmental Management: Science and Technology , 2009 .

[8]  M. Sumner Beneficial use of effluents, wastes, and biosolids , 2000 .

[9]  Y. Zhai,et al.  The fate of Cu, Zn, Pb and Cd during the pyrolysis of sewage sludge at different temperatures , 2010, Environmental technology.

[10]  M. Overcash,et al.  Beneficial reuse and sustainability: the fate of organic compounds in land-applied waste. , 2005, Journal of environmental quality.

[11]  Zhihong Xu,et al.  Biochar: Nutrient Properties and Their Enhancement , 2012 .

[12]  M. Arrobas,et al.  Effect of composted sewage sludge amendment on soil nitrogen and phosphorus availability , 1997 .

[13]  M. Mclaughlin,et al.  SEWAGE SLUDGE AS A PHOSPHORUS AMENDMENT FOR SESQUIOXIC SOILS , 1987 .

[14]  Paul T. Williams,et al.  Influence of temperature on the products from the flash pyrolysis of biomass , 1996 .

[15]  L. Sommers,et al.  Mineralization of Nitrogen in Sewage Sludges , 1983 .

[16]  Yoshiyuki Shinogi,et al.  NUTRIENT LEACHING FROM CARBON PRODUCTS OF SLUDGE , 2004 .

[17]  Vladimir Strezov,et al.  Thermal Decomposition of Wheat Straw and Mallee Residue Under Pyrolysis Conditions , 2010 .

[18]  M. Mclaughlin Land application of sewage sludge: Phosphorus considerations , 1984 .

[19]  T R Bridle,et al.  Energy and nutrient recovery from sewage sludge via pyrolysis. , 2004, Water science and technology : a journal of the International Association on Water Pollution Research.

[20]  José A. Caballero,et al.  Characterization of sewage sludges by primary and secondary pyrolysis , 1997 .

[21]  G. E. Rayment,et al.  Australian laboratory handbook of soil and water chemical methods. , 1992 .

[22]  A. Barbarika,et al.  Factors affecting the mineralization of nitrogen in sewage sludge applied to soils , 1985 .

[23]  A. Hospido,et al.  Environmental Evaluation of Different Treatment Processes for Sludge from Urban Wastewater Treatments: Anaerobic Digestion versus Thermal Processes (10 pp) , 2005 .

[24]  T. Bandosz,et al.  Pore structure and surface chemistry of adsorbents obtained by pyrolysis of sewage sludge-derived fertilizer , 2001 .

[25]  W. Tsai,et al.  Fast pyrolysis of rice straw, sugarcane bagasse and coconut shell in an induction-heating reactor , 2006 .

[26]  John Gaunt,et al.  Bio-char Sequestration in Terrestrial Ecosystems – A Review , 2006 .

[27]  I. Hwang,et al.  Characteristics of leachate from pyrolysis residue of sewage sludge. , 2007, Chemosphere.

[28]  G. Neilsen,et al.  Biosolids recycling : Nitrogen management and soil ecology , 2006 .

[29]  L. Sommers Chemical Composition of Sewage Sludges and Analysis of Their Potential Use as Fertilizers , 1977 .