Evaluation of Durability of Concrete with Mineral Additions with regard to Chloride-Induced Corrosion

This report presents the results from a study of modelling of chloride ingress and corrosion initiation in concrete with Portland cement and with fly ash and ground granulated blast-furnace slag as mineral additions. Durability of concrete with mineral additions and general models for chloride ingress in concrete are briefly reviewed. Chloride threshold values for corrosion initiation are discussed. The ClinConc model was employed to model the chloride ingress profiles after exposure under marine and road environments for 100 years. The model was validated using the field data after exposure in the Swedish seawater for about 20 years. The results show that the addition of mineral additions in general increases the resistance of concrete to chloride ingress. In consideration of both chloride resistance and alkalinity, the concrete with mineral additions still reveals sufficient margin to allow a significantly lower chloride threshold for initiation of corrosion of reinforcement steel in concrete. Based on the results from this study, some values of minimum cover thickness are suggested for different exposure environments depending on different types of binder used in concrete to achieve a service life of 100 years.

[1]  Velu Saraswathy,et al.  Studies on the corrosion resistance of reinforced steel in concrete with ground granulated blast-furnace slag--An overview. , 2006, Journal of hazardous materials.

[2]  T. Luping Chloride ingress in concrete exposed to marine environment - field data up to 10 years exposure , 2003 .

[3]  M Maage,et al.  Service Life Prediction of Marine Structures , 1997 .

[4]  C. Cremona,et al.  Corrosion initiation of reinforced concretes based on Portland or GGBS cements: Chloride contents and electrochemical characterizations versus time , 2012 .

[5]  M. Thiéry,et al.  Non-Saturated Ion Diffusion In Concrete–A New Approach To Evaluate Conductivity Measurements , 2013 .

[6]  Ueli Angst,et al.  Critical Chloride Content in Reinforced Concrete: A Review , 2009 .

[7]  B. Johannesson Transport and sorption phenomena in concrete and other porous media , 2000 .

[8]  C. L. Page,et al.  The influence of different cements on chloride-induced corrosion of reinforcing steel , 1986 .

[9]  R. Snellings,et al.  The pore solution of blended cements: a review , 2016 .

[10]  K. Tuutti Corrosion of steel in concrete , 1982 .

[11]  Patrick Dangla,et al.  Prediction of chloride ingress into saturated concrete on the basis of a multi-species model by numerical calculations , 2006 .

[12]  Tang Luping,et al.  Chloride Transport in Concrete - Measurement and Prediction , 1996 .

[13]  Arnon Bentur,et al.  Steel corrosion in concrete , 1997 .

[14]  Lars-Olof Nilsson,et al.  Resistance of Concrete to Chloride Ingress: Testing and modelling , 2011 .

[15]  J. Ollivier,et al.  Numerical simulation of multi-species diffusion , 2000 .

[16]  Leif Mejlbro,et al.  The Complete Solution of Fick's Second Law of Diffusion with Time-dependent Diffusion Coefficient and Surface Concentration , 1996 .

[17]  Anders Lindvall,et al.  Chloride ingress data from field and laboratory exposure – Influence of salinity and temperature , 2007 .

[19]  M. Collepardi,et al.  Penetration of Chloride Ions into Cement Pastes and Concretes , 1972 .

[20]  Luca Bertolini,et al.  Corrosion of Steel in Concrete , 2013 .

[21]  B. T. Molloy,et al.  Influence of PFA, slag and microsilica on chloride induced corrosion of reinforcement in concrete , 1991 .

[22]  L. Tang,et al.  A Numerical Method for Prediction of Chloride Penetration into Concrete Structures , 1996 .

[23]  E. Gruyaert Effect of blast-furnace slag as cement replacement on hydration, microstructure, strength and durability of concrete , 2011 .

[24]  S. Diamond,et al.  CHLORIDE CONCENTRATIONS IN CONCRETE PORE SOLUTIONS RESULTING FROM CALCIUM AND SODIUM CHLORIDE ADMIXTURES , 1986 .

[25]  Lars-Olof Nilsson,et al.  Chloride binding capacity and binding isotherms of OPC pastes and mortars , 1993 .

[26]  S.J.H. Meijers Computational Modelling of Chloride Ingress in Concrete , 2003 .

[27]  Tang Luping,et al.  Engineering Expression of the ClinConc Model for Prediction of Free and Total Chloride Ingress in Submerged Marine Concrete , 2008 .

[28]  Chloride ingress prediction: Part 1: Analytical model for time dependent diffusion coefficient and surface concentration , 2008 .

[29]  Luping Tang,et al.  Service-life prediction based on the rapid migration test and the ClinConc model , 2006 .

[30]  Dimitrios Boubitsas,et al.  Validation of models and test methods for assessment of durability of concrete structures in the road environment , 2012 .

[31]  M. C. Alonso,et al.  Analysis of the variability of chloride threshold values in the literature , 2009 .

[32]  N. Xie,et al.  Durability of steel reinforced concrete in chloride environments: An overview , 2012 .

[33]  G. Sergi,et al.  Diffusion of chloride and hydroxyl ions in cementitious materials exposed to a saline environment , 1992 .

[34]  Vincent Garcia,et al.  Potential measurement to determine the chloride threshold concentration that initiates corrosion of reinforcing steel bar in slag concretes , 2014 .