Highly sustainable electroactive artificial muscle with graphene

Electroactive artificial muscles driven by electrical stimuli have been widely developed for practical applications including bio-mimetic robots and active biomedical devices. However, conventional ionic type artificial muscles have a critical drawback of poor sustainability under long-time excitations, mainly because the inner electrolyte and hydrated cations can leak out through cracks in the metallic electrodes. Here, we developed a highly sustainable electro-active artificial muscle by using hydrophobic reduced graphene oxide papers. The highly conductive, flexible and cost-effective carbon electrodes have smooth outer surface and rough inner surface, for mechanical adhesion between electrodes and an ionic membrane and water floating functions. More importantly, the carbon electrode has a unique functionality of the vaporized or liquid electrolyte impermeability, greatly benefits for a highly sustainable electro-active artificial muscle.

[1]  Sung-Weon Yeom,et al.  A biomimetic jellyfish robot based on ionic polymer metal composite actuators , 2009 .

[2]  I. Oh,et al.  Dry‐Type Artificial Muscles Based on Pendent Sulfonated Chitosan and Functionalized Graphene Oxide for Greatly Enhanced Ionic Interactions and Mechanical Stiffness , 2013 .

[3]  I. Oh,et al.  Defect-engineered three-dimensional graphene-nanotube-palladium nanostructures with ultrahigh capacitance. , 2012, ACS nano.

[4]  Kwang J. Kim,et al.  Visualization of the cation migration in ionic polymer-metal composite under an electric field , 2010 .

[5]  E. Smela Conjugated Polymer Actuators for Biomedical Applications , 2003 .

[6]  J. Kysar,et al.  Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene , 2008, Science.

[7]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.

[8]  Franz R. Aussenegg,et al.  The use of metal-island-coated pH-sensitive swelling polymers for biosensor applications , 1995 .

[9]  S. Stankovich,et al.  Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide , 2007 .

[10]  G. Wallace,et al.  Processable aqueous dispersions of graphene nanosheets. , 2008, Nature nanotechnology.

[11]  I. Oh,et al.  Fullerenol-based electroactive artificial muscles utilizing biocompatible polyetherimide. , 2011, ACS nano.

[12]  I. Oh,et al.  A Biomimetic Actuator Based on an Ionic Networking Membrane of Poly(styrene‐alt‐maleimide)‐Incorporated Poly(vinylidene fluoride) , 2008 .

[13]  N. Koratkar,et al.  Graphene--nanotube--iron hierarchical nanostructure as lithium ion battery anode. , 2013, ACS nano.

[14]  K. Kim,et al.  Ionic polymer–metal composites: II. Manufacturing techniques , 2003 .

[15]  Yong Wang,et al.  A compact electroactive polymer actuator suitable for refreshable Braille display , 2008 .

[16]  C. N. Lau,et al.  Superior thermal conductivity of single-layer graphene. , 2008, Nano letters.

[17]  K. Kim,et al.  Ionic polymer-metal composites: I. Fundamentals , 2001 .

[18]  I. Oh,et al.  Novel biomimetic actuator based on SPEEK and PVDF , 2009 .

[19]  Jinzhu Li,et al.  Superfast-response and ultrahigh-power-density electromechanical actuators based on hierarchal carbon nanotube electrodes and chitosan. , 2011, Nano letters.