Novel samarium/erbium and samarium/terbium codoped glass phosphor for application in warm white light-emitting-diode

Tunable polychromatic light emission within the low color correlated temperature range was produced using terbiumand/ or erbium-samarium co-doped PbGeO3:PbF2:CdF2 glass phosphor. The phosphors were synthesized, and their luminescence characteristics were examined under UV-blue light-emitting-diode laser excitation. Luminescence emission around 490, 545, 600, and 645 nm in Tb3+/Sm3+ and 525, 545, 600, and 645 nm in Er3+/Sm3+ co-doped phosphor was obtained and analyzed as a function of the active ions concentration, and excitation wavelength. Color tunability in the red-orange-yellow-green region was achieved combining of Tb3+, Er3+, and Sm3+ ions contents. Results suggest that the color-tunable polychromatic light emitter phosphor herein reported is a promising novel candidate for application in cold white-light LED-based illumination technology

[1]  Ping Huang,et al.  Bright upconversion white light emission in transparent glass ceramic embedding Tm3+/Er3+/Yb3+ : β-YF3 nanocrystals , 2007 .

[2]  J. Koenderink Q… , 2014, Les noms officiels des communes de Wallonie, de Bruxelles-Capitale et de la communaute germanophone.

[3]  Frank G. Shi,et al.  Efficient red phosphors Na5Ln(MoO4)4 : Eu3+ (Ln = La, Gd and Y) for white LEDs , 2009 .

[4]  R. Xie,et al.  Eu2+-doped Ca-α-SiAlON: A yellow phosphor for white light-emitting diodes , 2004 .

[5]  Hua Gong,et al.  Upconversion color tunability and white light generation in Tm3+/Ho3+/Yb3+ doped aluminum germanate glasses , 2010 .

[6]  Mamoru Mitomo,et al.  Oxynitride/nitride phosphors for white light-emitting diodes (LEDs) , 2008 .

[7]  D. Jeon,et al.  Yellow-emitting Sr3SiO5:Ce3+,Li+ phosphor for white-light-emitting diodes and yellow-light-emitting diodes , 2007 .

[8]  Masahiro Yoshimura,et al.  Synthesis and photoluminescence properties of color-tunable BaLa2WO7:Eu3+ phosphor , 2011 .

[9]  Hee Dong Park,et al.  White light-emitting diodes of GaN-based Sr 2 SiO 4 : Eu and the luminescent properties , 2013 .

[10]  Holger Winkler,et al.  Synthesis and optical properties of green to orange tunable garnet phosphors for pcLEDs , 2011 .

[11]  J. Steen,et al.  Luminescence properties of red-emitting M2Si5N8:Eu2+ (M = Ca, Sr, Ba) LED conversion phosphors , 2006 .

[12]  Young Rag Do,et al.  Optical properties of three-band white light emitting diodes , 2003 .

[13]  Ping Huang,et al.  Novel rare earth ions-doped oxyfluoride nano-composite with efficient upconversion white-light emission , 2008 .

[14]  Jung Hyun Jeong,et al.  Luminescence and energy transfer of Eu3+ or/and Dy3+ co-doped in Sr3AlO4F phosphors with NUV excitation for WLEDs , 2012 .

[15]  Hee Dong Park,et al.  White light-emitting diodes of GaN-based Sr2SiO4:Eu and the luminescent properties , 2003 .

[16]  L. A. Bueno,et al.  White light generation by frequency upconversion in Tm3+∕Ho3+∕Yb3+-codoped fluorolead germanate glass , 2007 .

[17]  Jong Kyu Kim,et al.  Solid-State Light Sources Getting Smart , 2005, Science.

[18]  Ping Huang,et al.  Novel Rare Earth Ions-Doped Oxyfluoride Nanocomposite with Efficient Upconversion White-Light Emission. , 2009 .

[19]  Chih-Hao Liang,et al.  Synthesis and photoluminescence characteristics of color-tunable BaY2ZnO5:Eu3+ phosphors , 2008 .

[20]  Naoto Kijima,et al.  Synthesis of High-Brightness Sub-micrometer Y2O2S Red Phosphor Powders by Complex Homogeneous Precipitation Method , 2006 .

[21]  S. Nakamura,et al.  Candela‐class high‐brightness InGaN/AlGaN double‐heterostructure blue‐light‐emitting diodes , 1994 .

[22]  Elias A. Silva,et al.  Generation of wide color gamut visible light in rare-earth triply doped tantalum oxide crystalline ceramic powders , 2010 .

[23]  A. S. Gouveia-Neto,et al.  Luminescent features of sol-gel derived rare-earth multi-doped oxyfluoride nano-structured phosphors for white LED application , 2012 .

[24]  S.J. Chang,et al.  White-light emission from near UV InGaN-GaN LED chip precoated with blue/green/red phosphors , 2003, IEEE Photonics Technology Letters.

[25]  Wellington S. Souza,et al.  Color tunable green–yellow–orange–red Er3+/Eu3+-codoped PbGeO3:PbF2:CdF2 glass phosphor for application in white-LED technology , 2013 .

[26]  林耿,et al.  Three primary colors emitting from Er3+–Eu3+ co-doped oxygen-deficient glasses , 2011 .

[27]  Htjm Bert Hintzen,et al.  Luminescence properties of Eu2+ - activated alkaline-earth silicon-oxynitride MSi2O2-deltaN2+2/3delta (M = Ca, Sr, Ba) : A promising class of novel LED conversion phosphors , 2005 .

[28]  P ? ? ? ? ? ? ? % ? ? ? ? , 1991 .

[29]  Hajime Yamamoto,et al.  White LED phosphors: the next step , 2010, OPTO.

[30]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[31]  Chang Hae Kim,et al.  Application of strontium silicate yellow phosphor for white light-emitting diodes , 2004 .

[32]  Elias A. Silva,et al.  Rare-earth doped solid-state phosphor with temperature induced variable chromaticity , 2009 .

[33]  Myung Sub Kim,et al.  White light emission characteristics of Tb3+ and Sm3+ co-doped CaYAlO4 nanocrystalline phosphors for solid-state lighting , 2013 .

[35]  Guangjun Zhou,et al.  Novel multiband luminescence of Y2Zr2O7:Eu3+, R3+ (R = Ce, Bi) orange–red phosphors via a sol–gel combustion approach , 2012 .

[36]  M. Vermelho,et al.  Color tunability with temperature and pump intensity in Yb3+/Tm3+ codoped aluminosilicate glass under anti-Stokes excitation. , 2010, The Journal of chemical physics.

[37]  Xiaoluan Liang,et al.  Luminescence properties of Tb doped and Tm/Tb/Sm co-doped glasses for LED applications , 2010 .

[38]  Arpad Bergh,et al.  The Promise and Challenge of Solid-State Lighting , 2001 .

[39]  Liping Yu,et al.  A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+, Tb3+, Eu2+ for LED-based near-UV chip: Preparation, characterization and luminescent mechanism , 2011 .