Corrosion Processes, Nature and Composition of Corrosion Products on Iron Artefacts of Weaponry

The paper outlines the corrosion processes occurring in different types of iron artefacts of weaponry and military equipment while buried and after excavation. Special attention was given to the description of the nature and the composition of corrosion products on the surface of iron artefacts, which provided their protection over thousands of years. The corrosion processes occurring after the excavation can cause a rapid deterioration of these objects in relatively mild conditions. Being particularly dangerous for archaeological iron weapons and military equipment, these processes are dealt with here in detail.

[1]  V. Argyropoulos,et al.  The corrosion of excavated archaeological iron with details on weeping and akaganéite , 1999 .

[2]  H. Tamura The role of rusts in corrosion and corrosion protection of iron and steel , 2008 .

[3]  Koji Hashimoto,et al.  The Mechanism of Atmospheric Rusting and the Protective Amorphous Rust on Low Alloy Steel(Chemistry) , 1974 .

[4]  R. Balasubramaniam,et al.  On the corrosion resistance of the Delhi iron pillar , 2000 .

[5]  Masato Yamashita,et al.  Composition and protective ability of rust layer formed on weathering steel exposed to various environments , 2006 .

[6]  Zoran Radakovic,et al.  From fracture mechanics to structural integrity assessment : this monograph contains the lectures presented at the eighth international fracture mechanics summer school held in Belgrade, Serbia and Montenegro, 23-27 June 2003. , 2004 .

[7]  S. Turgoose THE CORROSION OF ARCHAEOLOGICAL IRON DURING BURIAL AND TREATMENT , 1985 .

[8]  Lyndsie S. Selwyn,et al.  Overview of archaeological iron: the corrosion problem, key factors affecting treatment, and gaps in current knowledge , 2004 .

[9]  S. Turgoose,et al.  POST-EXCAVATION CHANGES IN IRON ANTIQUITIES , 1982 .

[10]  D. Watkinson,et al.  Desiccated Storage of Chloride-Contaminated Archaeological Iron Objects , 2005 .

[11]  Joseph R. Davis Corrosion: Understanding The Basics , 2000 .

[12]  P. Dillmann,et al.  Buried iron archaeological artefacts: Corrosion mechanisms related to the presence of Cl-containing phases , 2007 .

[13]  Mark Gilberg,et al.  THE IDENTITY OF COMPOUNDS CONTAINING CHLORIDE IONS IN MARINE IRON CORROSION PRODUCTS: A CRITICAL REVIEW , 1981 .

[14]  P. Lagarde,et al.  Structural evidence for the desalination of akaganeite in the preservation of iron archaeological objects, using synchrotron X-ray powder diffraction and absorption spectroscopy , 2009 .

[15]  P. Dillmann,et al.  Advances in understanding atmospheric corrosion of iron. II. Mechanistic modelling of wet–dry cycles , 2004 .

[16]  R. Wei The Fracture Mechanics Approach to Stress Corrosion Cracking , 1979 .

[17]  R. Balasubramaniam,et al.  Characterization of Delhi iron pillar rust by X-ray diffraction, Fourier transform infrared spectroscopy and Mössbauer spectroscopy , 2000 .

[18]  Ludovic Legrand,et al.  A corrosion study of the ferrous medieval reinforcement of the Amiens cathedral. Phase characterisation and localisation by various microprobes techniques , 2010 .

[19]  G. C. Wood,et al.  The corrosion of iron and zinc by atmospheric hydrogen chloride , 1993 .

[20]  Lyndsie Selwyn,et al.  Metals and Corrosion: A Handbook for the Conservation Professional , 2004 .

[21]  P. Dillmann,et al.  Study of lepidocrocite γ-FeOOH electrochemical reduction in neutral and slightly alkaline solutions at 25 °C , 2005 .

[22]  David Watkinson,et al.  Degree of mineralization: its significance for the stability and treatment of excavated ironwork , 1983 .

[23]  R. P. Frankenthal,et al.  Corrosion Mechanisms for Iron and Low Alloy Steels Exposed to the Atmosphere , 1990 .

[24]  T. Misawa,et al.  The mechanism of atmospheric rusting and the effect of Cu and P on the rust formation of low alloy steels , 1971 .

[25]  D. Landolt,et al.  Corrosion and surface chemistry of metals , 2007 .

[26]  F. Hui,et al.  Infrared spectrometry for solid phase analysis: Corrosion rusts , 2008 .

[27]  P. Dillmann,et al.  Advances in understanding atmospheric corrosion of iron. I. Rust characterisation of ancient ferrous artefacts exposed to indoor atmospheric corrosion , 2004 .

[28]  Kurt Nielsen,et al.  On the akaganéite crystal structure, phase transformations and possible role in post-excavational corrosion of iron artifacts , 2003 .