A self-healing cementitious composite with mineral admixtures and built-in carbonate

Abstract In this study, experimental investigations were conducted on the self-healing potential of concrete. Sulfoaluminate based expansive agents (CSA), crystalline admixture (CA), and calcium hydrogen phosphate were used as part of cementitious materials, and porous ceramsites served as the carrier for sodium carbonate solution. The quantification of the widths/areas of the cracks was performed to examine the feasibility of the approach and optimize mix proportions. A gas permeability test was conducted on two preferred mixes to investigate the change in the gas permeability of pre-cracked samples. After curing in still water for 28 d, the pre-cracked specimens with ceramsites containing sodium carbonate, and appropriate dosages of additives exhibited considerable efficiency in surface crack closure and healing in gas permeability. The SEM results indicated the deeper formation of healing products (CaCO3) in the cracks of the suggested mix when compared to that in the control mix. A healing mechanism was discussed based on the experimental results.

[1]  Guang Ye,et al.  Self-healing of cracks in cement paste affected by additional Ca2+ ions in the healing agent , 2015 .

[2]  J. J. Kollek The determination of the permeability of concrete to oxygen by the Cembureau method—a recommendation , 1989 .

[3]  Tao Ji,et al.  Effect of prewetting degree of ceramsite on the early-age autogenous shrinkage of lightweight aggregate concrete , 2015 .

[4]  Takeshi Ogino,et al.  The formation and transformation mechanism of calcium carbonate in water , 1987 .

[5]  W. Verstraete,et al.  Microbial carbonate precipitation in construction materials: A review , 2010 .

[6]  G. Assche,et al.  Selection of healing agents for a vascular self-healing application , 2017 .

[7]  Feng Xing,et al.  Experimental Study on Mechanical Properties and Porosity of Organic Microcapsules Based Self-Healing Cementitious Composite , 2017, Materials.

[8]  Zhengwu Jiang,et al.  Influence of mineral additives and environmental conditions on the self-healing capabilities of cementitious materials , 2015 .

[9]  L. N. Plummer,et al.  The solubilities of calcite, aragonite and vaterite in CO2-H2O solutions between 0 and 90°C, and an evaluation of the aqueous model for the system CaCO3-CO2-H2O , 1982 .

[10]  F. Xing,et al.  Experimental investigation on the compressive strength and shrinkage of concrete with pre-wetted lightweight aggregates , 2017 .

[11]  T. Ahn,et al.  Mechanical behavior of a capsule embedded in cementitious matrix-macro model and numerical simulation , 2016 .

[12]  O. Jin-ping Experiment and research on permeable crystallization self-repairing performance of concrete , 2008 .

[13]  Qingbin Li,et al.  Behavior of concrete beam with embedded shape memory alloy wires , 2006 .

[14]  Hubert Rahier,et al.  Influence of mix composition on the extent of autogenous crack healing by continued hydration or calcium carbonate formation , 2012 .

[15]  Fang Cheng,et al.  Experimental study on early cracking sensitivity of lightweight aggregate concrete , 2017 .

[16]  Feng Xing,et al.  Experimental Study on Cementitious Composites Embedded with Organic Microcapsules , 2013, Materials.

[17]  Carolyn M. Dry,et al.  Three designs for the internal release of sealants, adhesives, and waterproofing chemicals into concrete to reduce permeability , 2000 .

[18]  Eduardus A. B. Koenders,et al.  Self-healing of surface cracks in mortars with expansive additive and crystalline additive , 2012 .

[19]  Liberato Ferrara,et al.  Self-healing capability of concrete with crystalline admixtures in different environments , 2015 .

[20]  En-Hua Yang,et al.  Self Healing in Concrete Materials , 2007 .

[21]  Nele De Belie,et al.  Self-healing phenomena in cement-based materials , 2013 .

[22]  Luboš Taranza,et al.  Fly-Ash Usage in New Cement-Based Material for Concrete Waterproofing , 2012 .

[23]  Mohamed Lachemi,et al.  Development and recovery of mechanical properties of self-healing cementitious composites with MgO expansive agent , 2017 .

[24]  Björn Johannesson,et al.  A review : Self-healing in cementitious materials and engineered cementitious composite as a self-healing material , 2012 .

[25]  Chunxiang Qian,et al.  Self-healing in cementitious materials: Materials, methods and service conditions , 2016 .

[26]  Toshiharu Kishi,et al.  Crack Self-healing Behavior of Cementitious Composites Incorporating Various Mineral Admixtures , 2010 .

[27]  Carolyn M. Dry,et al.  Procedures developed for self-repair of polymer matrix composite materials , 1996 .

[28]  Carola Edvardsen,et al.  Water Permeability and Autogenous Healing of Cracks in Concrete , 1999 .