Super-Resolution Scanning Near-Field Optical Microscopy

Scanning near-field optical microscopy (SNOM) is a method to obtain information about the optical properties of a sample at a lateral resolution below the diffraction limit of far-field microscopy. In SNOM, a light source of a dimension which is small compared to the wavelength of light and which is held at a small distance from the sample is scanned across the surface of the sample. The modulation by the sample of the light emitted from the source is recorded as a signal. As a general rule one may say that the size of the source and the distance to the sample limit the resolution of SNOM. A radiating self-emitting point dipole may be regarded as an idealized SNOM source. With such a source the resolution of SNOM imaging is expected to be limited by the distance of this dipole to the surface of the object [1]. It is difficult to design a light-emitting SNOM probe corresponding to a dipole at a distance of less than 10 nm from the object and it is therefore difficult to conceive SNOM imaging beyond a resolution of 10 nm. There have been, however, occasional reports of near-field optical imaging at a resolution in the range of 1-10 nm [2, 3]. In SNOM-images recorded with the tetrahedral tip (T-tip) a resolution in the range of 1-10 nm was obtained reproducibly on samples consisting of small grains of silver of a size of the order of 2-10 nm embedded in a flat surface of gold [3, 4]. An example of an image is shown in Fig. 1. In a different experiment we investigated a surface-embedded latex bead projection pattern [5] consisting of a flat surface of a polymer into which gold patches of a triangular shape of a size of about 50 nm and a thickness of 20 nm were embedded [6].

[1]  K. L. Chopra,et al.  Thin Film Phenomena , 1969 .

[2]  P. K. Aravind,et al.  The effects of the interaction between resonances in the electromagnetic response of a sphere-plane structure; applications to surface enhanced spectroscopy , 1983 .

[3]  John E. Wessel,et al.  Surface-enhanced optical microscopy , 1985 .

[4]  U. Fischer,et al.  Submicrometer aperture in a thin metal film as a probe of its microenvironment through enhanced light scattering and fluorescence , 1986 .

[5]  Fischer Uc,et al.  Observation of single-particle plasmons by near-field optical microscopy. , 1989 .

[6]  Christian Girard,et al.  Superresolution of near-field optical microscopy defined from properties of confined electromagnetic waves. , 1992, Applied optics.

[7]  Y. Martin,et al.  Scanning Interferometric Apertureless Microscopy: Optical Imaging at 10 Angstrom Resolution , 1995, Science.

[8]  Alain Dereux,et al.  Near-field optics theories , 1996 .

[9]  Harald Fuchs,et al.  Material contrast in scanning near-field optical microscopy at 1–10 nm resolution , 1997 .

[10]  Eric Bourillot,et al.  Squeezing the Optical Near-Field Zone by Plasmon Coupling of Metallic Nanoparticles , 1999 .

[11]  Coherent near field optical microscopy , 2000 .

[12]  Gerhard Ertl,et al.  Surface Enhanced Raman Spectroscopy: Towards Single Molecule Spectroscopy , 2000 .

[13]  J. Pendry,et al.  Negative refraction makes a perfect lens , 2000, Physical review letters.

[14]  SNOM/STM using a tetrahedral tip and a sensitive current‐to‐voltage converter , 2001, Journal of microscopy.

[15]  U. Fischer,et al.  Elastic Scattering by a Metal Sphere with an Adsorbed Molecule as a Model for the Detection of Single Molecules by Scanning Probe Enhanced Elastic Resonant Scattering (SPEERS) , 2001 .

[16]  Harald Fuchs,et al.  Latex bead projection nanopatterns , 2002 .

[17]  A. Dereux,et al.  Imaging of photonic nanopatterns by scanning near-field optical microscopy , 2002 .