论文信息 - Refined Procedure for Analysis of Electron Diffraction Data and Its Application to CCl4

Refined Procedure for Analysis of Electron Diffraction Data and Its Application to CCl4

A refined procedure for obtaining the structure of free molecules from electron diffraction data is described which compensates for the interference arising from non‐nuclear scattering. The procedure is applied to CCl4 using somewhat more extensive rotating sector data than has hitherto been published for this molecule. Estimates are made for the first time in electron diffraction results of the effect of anharmonicity of vibration on the measurement of internuclear distance and of the effect of the failure of the Born approximation on the measurement of amplitudes of vibration. A method of estimating the reliability of the results is described.

L. Bartell | R. Schwendeman | L. Brockway

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