Radiation-induced interface traps in hardened MOS transistors: an improved charge-pumping study

Different electrical characterization (subthreshold current-voltage measurements, 3-level and multi-frequency charge pumping) combined with isochronal anneals have been used to investigate the generation and the evolution of interface traps in radiation-hardened MOS transistors following exposure to 10 keV X-rays. The evolution of the interface state density (D/sub it/) during the anneal is found to be field-dependent and consistent with models involving a drift of positive species towards the Si-SiO/sub 2/ interface. The energy-resolved distributions of D/sub it/ in the silicon bandgap show the emergence of two broad structures located at /spl sim/E/sub V/+0.35 eV and /spl sim/E/sub V/+0.75 eV immediately after irradiation and during the first steps of the isochronal anneal (up to /spl sim/175/spl deg/C). At higher anneal temperatures, it is shown that the recovery of D/sub it/ is not uniform in the two halves of the silicon bandgap. In particular, the separation of the D/sub it/ distribution related to the lower part of the bandgap in two distinct peaks (at E/sub V/+0.30 eV and E/sub V/+0.45 eV) agrees well with the energy distributions of P/sub b0/ and P/sub b1/ centers. These results are consistent with Electron Spin Resonance (ESR) studies which have shown that P/sub b/ centers play a dominating role in the interface trap build-up and recovery mechanisms. Since ESR measurements are only accurate to /spl sim//spl plusmn/30% in absolute number, P/sub b/ centers do not probably account for all the electrically active interface trap defects, as also suggested by the evident asymmetry of the D/sub it/ distributions in the bandgap. Finally, we investigate the post-irradiation response of border traps by reducing the charge pumping frequency to low values. The implication of these results on the nature of border traps is discussed.

[1]  K. L. Brower Passivation of paramagnetic Si‐SiO2 interface states with molecular hydrogen , 1988 .

[2]  Orientation dependence of interface-trap transformation , 1989 .

[3]  Nelson S. Saks,et al.  The time-dependence of post-irradiation interface trap build-up in deuterium-annealed oxides (n-MOSFET) , 1992 .

[4]  R. K. Lawrence,et al.  Post-irradiation behavior of the interface state density and the trapped positive charge , 1990 .

[5]  Paul J. McWhorter,et al.  Modeling the anneal of radiation-induced trapped holes in a varying thermal environment , 1990 .

[6]  Daniel M. Fleetwood,et al.  Comparison of MOS capacitor and transistor postirradiation response , 1989 .

[7]  J. Autran,et al.  Characterization of Si–SiO2 interface states: Comparison between different charge pumping and capacitance techniques , 1993 .

[8]  B. Balland,et al.  A new third‐level charge pumping method for accurate determination of interface‐trap parameters in metal‐oxide‐semiconductor field‐effect‐transistors , 1994 .

[9]  Daniel M. Fleetwood,et al.  Field dependence of interface-trap buildup in polysilicon and metal gate MOS devices , 1990 .

[10]  D. Fleetwood,et al.  Effects of oxide traps, interface traps, and ‘‘border traps’’ on metal‐oxide‐semiconductor devices , 1993 .

[11]  David L. Griscom,et al.  Formation of interface traps in MOSFETs during annealing following low temperature irradiation , 1988 .

[12]  P. Dressendorfer,et al.  Paramagnetic trivalent silicon centers in gamma irradiated metal‐oxide‐silicon structures , 1984 .

[13]  H. L. Hughes,et al.  Annealing of total dose damage: redistribution of interface state density on [100], [110] and [111] orientation silicon , 1988 .

[14]  P. Balk,et al.  Charge exchange mechanisms of slow states in Si/SiO 2 , 1993 .

[15]  Daniel M. Fleetwood,et al.  Border traps: issues for MOS radiation response and long-term reliability , 1995 .

[16]  Patrick M. Lenahan,et al.  An electron spin resonance study of radiation‐induced electrically active paramagnetic centers at the Si/SiO2 interface , 1983 .

[17]  Patrick M. Lenahan,et al.  Electron‐spin‐resonance study of radiation‐induced paramagnetic defects in oxides grown on (100) silicon substrates , 1988 .

[18]  D. Babot,et al.  Etude par pompage de, charge des défauts induits à l'interface Si-SiO2 par rayonnements ionisants , 1994 .

[19]  A. Stesmans Revision of H2 passivation of Pb interface defects in standard (111)Si/SiO2 , 1996 .

[20]  Michael J. Uren,et al.  Separation of two distinct fast interface state contributions at the (100)Si/SiO2 interface using the conductance technique , 1992 .

[21]  P. Winokur,et al.  Simple technique for separating the effects of interface traps and trapped‐oxide charge in metal‐oxide‐semiconductor transistors , 1986 .

[22]  James H. Stathis,et al.  Passivation and depassivation of silicon dangling bonds at the Si/SiO2 interface by atomic hydrogen , 1993 .

[23]  M. Uren,et al.  Fast and slow interface state distributions on (100) and (111) Si:SiO 2 surfaces following negative bias stress , 1995 .

[24]  M. White,et al.  Observation of near-interface oxide traps with the charge-pumping technique , 1992, IEEE Electron Device Letters.

[25]  D. Fleetwood Fast and slow border traps in MOS devices , 1995 .

[26]  F. V. Thome,et al.  High-temperature silicon-on-insulator electronics for space nuclear power systems: requirements and feasibility , 1988 .

[27]  G. Groeseneken,et al.  A reliable approach to charge-pumping measurements in MOS transistors , 1984, IEEE Transactions on Electron Devices.

[28]  M. Ancona,et al.  Determination of interface trap capture cross sections using three-level charge pumping , 1990, IEEE Electron Device Letters.

[29]  D. Fleetwood,et al.  Microscopic nature of border traps in MOS oxides , 1994 .

[30]  N. Johnson,et al.  Interface traps and Pb centers in oxidized (100) silicon wafers , 1986 .

[31]  Bruce E. Deal,et al.  Interface states and electron spin resonance centers in thermally oxidized (111) and (100) silicon wafers , 1981 .

[32]  Daniel Babot,et al.  Three-level charge pumping study of radiation-induced defects at SiSiO2 interface in submicrometer MOS transistors , 1995 .

[33]  Marvin H. White,et al.  Theory and application of charge pumping for the characterization of Si-SiO/sub 2/ interface and near-interface oxide traps , 1994 .

[34]  P. Dressendorfer,et al.  Effect of bias on radiation‐induced paramagnetic defects at the silicon‐silicon dioxide interface , 1982 .

[35]  P. S. Winokur,et al.  Predicting CMOS Inverter Response in Nuclear and Space Environments , 1983, IEEE Transactions on Nuclear Science.

[36]  C. Barnes,et al.  The application of deep level transient spectroscopy to the measurement of radiation-induced interface state spectra , 1988 .

[37]  W. C. Johnson,et al.  Radiation-Induced Trivalent Silicon Defect Buildup at the Si-SiO2 Interface in MOS Structures , 1981, IEEE Transactions on Nuclear Science.

[39]  Daniel M. Fleetwood,et al.  Effects of interface traps and border traps on MOS postirradiation annealing response , 1995 .

[40]  T. Ma,et al.  Possible observation of Pb0 and Pb1 centers at irradiated (100)Si/SiO2 interface from electrical measurements , 1991 .

[41]  Martin Kerber Energy distribution of slow trapping states in metal‐oxide‐semiconductor devices after Fowler–Nordheim injection , 1993 .

[42]  D. Biegelsen,et al.  Characteristic electronic defects at the Si‐SiO2 interface , 1983 .

[43]  E. H. Nicollian,et al.  Mos (Metal Oxide Semiconductor) Physics and Technology , 1982 .

[44]  Dominique Vuillaume The nature of interface states generated by high field injection , 1993 .

[45]  N. Johnson Electronic and Optical Properties of Silicon Dangling-Bond Defects at the Si-Sio2 Interface , 1988 .

[46]  Gerard Ghibaudo,et al.  Analytical study of the contribution of fast and slow oxide traps to the charge pumping current in MOS structures , 1996 .

[47]  T. R. Oldham,et al.  Response of interface traps during high-temperature anneals (MOSFETs) , 1991 .

[48]  Mario G. Ancona,et al.  Numerical simulation of 3‐level charge pumping , 1992 .