Practical modeling and optimization of ultrasound-assisted bleaching of olive oil using hybrid artificial neural network-genetic algorithm technique

Abstract Multi-objective modeling and optimization of ultrasound-assisted bleaching of olive oil were accomplished by a hybrid artificial neural network (ANN) and genetic algorithm (GA) method using an ultrasonic bath with a frequency of 25 kHz. The influence of process parameters including ultrasonic power, bleaching clay dosage, process temperature and time (inputs) on final Lovibond red (Lr) and peroxide value (PV) (outputs) was modeled by a multilayer feed-forward back propagation ANN. The accurate 2-hidden layer model with 20 neurons in each, high R 2 (up to 90%) and minimum mean square error (MSE) obtained by ANN was introduced to GA to find the best operation conditions to achieve minimum Lr and PV. The optimum treatment was found with ultrasonic power of 30%, bleaching clay of 1.2%, bleaching time of 13 min and temperature of 65 °C. Under optimal conditions, Lr and PV were 2.47 and 6.49 (meqO 2 /kg), respectively, that were consistent with predicted values. Optimally ultrasonic bleached olive oil and an industrially bleached olive oil were compared. In most cases, the results indicated no detrimental effects of ultrasound on oil structure. Thus, 40% reduction in bleaching clay dosage, 35% reduction in process temperature and 57% reduction in time over ultrasound-assisted bleaching which not only provided economic and environmental benefits, but also retained edible oil nutritional value in comparison to common bleaching procedure. The results of this study confirm the applicability of ultrasound-assisted bleaching by ultrasonic bath as an economic and feasible approach for bleaching of olive oil to reduce high bleaching costs.

[1]  M. Barzegar,et al.  Optimisation of soya bean oil bleaching by ultrasonic processing and investigate the physico‐chemical properties of bleached soya bean oil , 2015 .

[2]  F. Rehab,et al.  Physicochemical studies on sunflower oil blended with cold pressed tiger nut oil during deep frying process , 2012 .

[3]  A. Segers PRODUCTION AND REFINING OF OILS AND FATS , 2007 .

[4]  G. Jameson,et al.  Effect of ultrasound on surface cleaning of silica particles , 2000 .

[5]  S. Sayadi,et al.  Catalytic wet peroxide photo-oxidation of phenolic olive oil mill wastewater contaminants: Part I. Reactivity of tyrosol over (Al–Fe)PILC , 2007 .

[6]  Farid Chemat,et al.  Applications of ultrasound in food technology: Processing, preservation and extraction. , 2011, Ultrasonics sonochemistry.

[7]  F. Burke,et al.  Antimicrobial activity of ultrasonic cleaners. , 2005, Journal of Hospital Infection.

[8]  D. M. Chapman,et al.  Separation and characterization of pigments from bleached and deodorized canola oil , 1994 .

[9]  Tao Wu,et al.  Ultrasonic bleaching of rapeseed oil: Effects of bleaching conditions and underlying mechanisms , 2013 .

[10]  Rekha S. Singhal,et al.  Comparison of artificial neural network (ANN) and response surface methodology (RSM) in fermentation media optimization: Case study of fermentative production of scleroglucan , 2008 .

[11]  Lothar Thiele,et al.  Comparison of Multiobjective Evolutionary Algorithms: Empirical Results , 2000, Evolutionary Computation.

[12]  Jonas S Almeida,et al.  Predictive non-linear modeling of complex data by artificial neural networks. , 2002, Current opinion in biotechnology.

[13]  Ramón Aparicio,et al.  Comparative study of virgin olive oil sensory defects , 2005 .

[14]  M. Nakajima,et al.  Decolorization of vegetable oils by membrane processing , 2001 .

[15]  Stephen S. Chang,et al.  FORMATION OF CARBONYL COMPOUNDS FROM P‐CAROTENE DURING PALM OIL DEODORIZATION , 1980 .

[16]  Masoud Rahimi,et al.  Experimental study and genetic algorithm-based multi-objective optimization of thermal and flow characteristics in helically coiled tubes , 2013 .

[17]  Oualid Hamdaoui,et al.  Removal of cadmium from aqueous medium under ultrasound assistance using olive leaves as sorbent , 2009 .

[18]  S. Rizvi,et al.  Continuous supercritical carbon dioxide processing of palm oil , 1996 .

[19]  T. Lundstedt,et al.  Experimental design and optimization , 1998 .

[20]  I. Boyaci,et al.  Modeling and optimization II: Comparison of estimation capabilities of response surface methodology with artificial neural networks in a biochemical reaction , 2007 .

[21]  M. Barzegar,et al.  CHANGES IN OIL CONTENT, CHEMICAL PROPERTIES, FATTY ACID COMPOSITION AND TRIACYLGLYCEROL SPECIES OF TEA SEED OIL DURING MATURITY PERIOD , 2011 .

[22]  Jasenka Gajdoš Kljusurić,et al.  Optimization of Bleaching Parameters for Soybean Oil , 2011 .

[23]  M. R. Zakin,et al.  Cavitation thermometry using molecular and continuum sonoluminescence , 1996 .

[24]  F. Chemat,et al.  High power ultrasound effects on lipid oxidation of refined sunflower oil. , 2004, Ultrasonics sonochemistry.

[25]  David Wray,et al.  Teaching theory and practice , 2014 .

[26]  R. Verhé,et al.  Influence of bleaching by ultrasound on fatty acids and minor compounds of olive oil. Qualitative and quantitative analysis of volatile compounds (by SPME coupled to GC/MS). , 2008, Ultrasonics sonochemistry.

[27]  Ali Aminian,et al.  Accurate prediction of the dew points of acidic combustion gases by using an artificial neural network model , 2011 .

[28]  I. Hua,et al.  Sonochemical degradation of p-nitrophenol in a parallel-plate near-field acoustical processor. , 1995, Environmental science & technology.

[29]  L. H. Thompson,et al.  Sonochemistry: Science and Engineering , 1999 .

[30]  Werner Zschau,et al.  Bleaching of edible fats and oils , 2001 .

[31]  Sanjeev S. Tambe,et al.  Reaction Modeling and Optimization Using Neural Networks and Genetic Algorithms: Case Study Involving TS-1-Catalyzed Hydroxylation of Benzene , 2002 .

[32]  Beatriz P. P. Oliveira,et al.  Chemometric characterization of three varietal olive oils (Cvs. Cobrançosa, Madural and Verdeal Transmontana) extracted from olives with different maturation indices , 2007 .

[33]  Hanumantha Rao Garapati,et al.  Optimization of medium constituents for Cephalosporin C production using response surface methodology and artificial neural networks , 2009 .

[34]  D. Firestone,et al.  Official methods and recommended practices of the American Oil Chemists' Society , 1990 .

[35]  R. Verhé,et al.  Influence of the vegetable oil refining process on free and esterified sterols , 2002 .

[36]  M. Torrent,et al.  A laboratory study of the bleaching process in stigmasta-3,5-diene concentration in olive oils , 2001 .

[37]  Ali Zilouchian,et al.  Automation and process control of reverse osmosis plants using soft computing methodologies , 2001 .

[38]  H. Wendt Polyaromatische Kohlenwasserstoffe in rohen Ölen und Fetten und ihre Entfernung durch Behandlung mit aktivierter Kohle , 1981 .

[39]  F. Chemat,et al.  Deterioration of edible oils during food processing by ultrasound. , 2004, Ultrasonics sonochemistry.